3. A 25.00 mL 0.0250 M calcium carbonate sample is titrated with 14.3 mM EDTA solution. Both sample and titrant are buffered at pH = 10.0 a. What is the titration reaction and what is the value of the conditional formation constant? b. What is the calcium ion concentration when 12.35 mL of titrant has been added? c. What is pCa2+ at the equivalence volume?
3. A 25.00 mL 0.0250 M calcium carbonate sample is titrated with 14.3 mM EDTA solution....
The metal ion Mn+ was titrated with 0.0500 M EDTA. The initial solution contained 100.0 mL of 0.0500 M metal ion (Mn+) buffered at a pH of 9.00. a) Calculate the equivalence volume (Veq). b) What is the concentration of the free metal ion at volume V = Veq/2. c) If the conditional formation constant, K’f = 5.4 X 1010, calculate the concentration of free metal ion at volume V = Veq.
(10) (3) 4. The metal ion Mnt was titrated with 0.0500 M EDTA. The initial solution contained 100.0 mL of 0.0500 M metal ion (M9+) buffered at a pH of 9.00. a) Calculate the equivalence volume (Veg). b) What is the concentration of the free metal ion at volume V = Veg/2. c) If the conditional formation constant, K'r = 5.4 X 1010, calculate the concentration of free metal ion at volume V = Veq. (4)
A 140.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log?f for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, ?Y4− , is 0.041 at pH 9.00. What is ?′f , the conditional formation constant, for Ca2+ at pH 9.00? ?′f= What is the equivalence point volume, ?e , in milliliters? ?e= mL Calculate the concentration of Ca2+ at ?=12?e . [Ca2+]= M...
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of logKf for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, αY4−, is 0.041 at pH 9.00. What is Kf′, the conditional formation constant, for Ca2+ at pH 9.00? Kf′= What is the equivalence point volume, Ve, in milliliters? Ve= mL Calculate the concentration of Ca2+ at V=12Ve. [Ca2+]= M Calculate the concentration...
4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point (i.e. 50.0 mL EDTA has been added), what is the equilibrium concentration of Ca2, [Ca2], and what is the pCa? The formation constant of CaY, Kaa 5.0 x 1010, and α4 of EDTA at pH 10.0 is 0.35 4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point...
A 100 mL sample of 0.060 M is titrated with 0.060 M EDTA at pH 9.00. The value of Kf for the Ca^2+ -EDTA complex is 10.65 and the fraction of free EDTA in the Y^4- form, ay+ , is at pH 9.00. The Y4- was not given how am i suppose to solve this. What is Kf' , the conditional formation constant, for CA^2+ at pH 9.00? What is the equivalence point volume, Ve, in milliliters? Calculate the concentration...
A 150.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log Kr for the Ca2+-EDTA complex is 10.65 and the fraction of free EDTA in the Y- form, ay, is 0.041 at pH 9.00. What is K/, the conditional formation constant for Ca²+ at pH 9.00? What is the equivalence point volume, Ve, in milliliters? ml V = Ve= Calculate the concentration of Ca²+ at V = { v. [Ca2+1...
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of log Kr for the Ca2-EDTA complex is 10.65 and the fraction of free EDTA in the Y4 form, a, is 0.041 at pH 9.00 What is K, the conditional formation constant, for Ca2+ at pH 9.00? K What is the equivalence point volume, V, in milliliters? C Ve= mL Calculate the concentration of Ca2t at V Ca2+ М Calculate the...
23. A 25.00 mL water sample is titrated with a 0.0120 M EDTA solution. The equivalence point is reached when 17.0 mL of the EDTA is added. The hardness in the sample was ppm CаCОз. a) 817 b) 219 c) 120 d) 346 e) none of the above
Ex. 13.4 The analysis of 10.00 mL 0.0100 M Ca²+ solution in water at pH 10.00 that was titrated using 0.0050 M EDTA. The conditional formation constant for this reaction under these conditions is 1.75X1010. What values of pCa would be expected (a) at the beginning of the titration; (b) 50% of the way through this titration; (c) at the equivalence point; (d) after an excess of 10.00 mL titrant has been added to this sample?