EDTA is a Hexaprotic system. EDTA with Ca+2 form complex in 1:1. All steps are in equilibrium so Consider backward reaction for the concentration calculation.
A 150.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log Kr for the Ca2+-EDTA c...
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of log Kr for the Ca2-EDTA complex is 10.65 and the fraction of free EDTA in the Y4 form, a, is 0.041 at pH 9.00 What is K, the conditional formation constant, for Ca2+ at pH 9.00? K What is the equivalence point volume, V, in milliliters? C Ve= mL Calculate the concentration of Ca2t at V Ca2+ М Calculate the...
A 140.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log?f for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, ?Y4− , is 0.041 at pH 9.00. What is ?′f , the conditional formation constant, for Ca2+ at pH 9.00? ?′f= What is the equivalence point volume, ?e , in milliliters? ?e= mL Calculate the concentration of Ca2+ at ?=12?e . [Ca2+]= M...
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of logKf for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, αY4−, is 0.041 at pH 9.00. What is Kf′, the conditional formation constant, for Ca2+ at pH 9.00? Kf′= What is the equivalence point volume, Ve, in milliliters? Ve= mL Calculate the concentration of Ca2+ at V=12Ve. [Ca2+]= M Calculate the concentration...
You are titrating 130.0 mL of 0.050 M Ca2 with 0.050 M EDTA at pH 9.00. Log K for the Ca2 EDTA complex is 10.65, and the fraction of free EDTA in the Y4-form, *. is 0.041 at pH 9.00. (a) What is Kt, the conditional formation constant, for Ca2 at pH 9.00? Number K: (pH 9.00) = 110 (b) What is the equivalence volume, Ve, in milliliters? Number mL (c) Calculate the concentration of Ca+ at V- 1/2 Ve...
A 100 mL sample of 0.060 M is titrated with 0.060 M EDTA at pH 9.00. The value of Kf for the Ca^2+ -EDTA complex is 10.65 and the fraction of free EDTA in the Y^4- form, ay+ , is at pH 9.00. The Y4- was not given how am i suppose to solve this. What is Kf' , the conditional formation constant, for CA^2+ at pH 9.00? What is the equivalence point volume, Ve, in milliliters? Calculate the concentration...
A 30.0 mL sample of 0.0200M Cu2t buffered at pH 9.00 is titrated with 0.0300 M EDTA. Calculate pCut at each of the added volumes of EDTA. For the Cu2+-EDTA complex, log Kr is 18.78. The fraction of free EDTA in the Y form, ay can be found in this table. O mL pCu2+ 6.67 mL pCu2+ 20.0 mL pCu2 Values of ay for EDTA a PH ay4- 0 1.3 x 10-23 1 1.4 x 10-18 2 2.6 x 10-14...
4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point (i.e. 50.0 mL EDTA has been added), what is the equilibrium concentration of Ca2, [Ca2], and what is the pCa? The formation constant of CaY, Kaa 5.0 x 1010, and α4 of EDTA at pH 10.0 is 0.35 4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point...
Find the conditional formation constant for Ba(EDTA)2- at pH 9.00, where log Kf is 7.88 and Qyt is 0.041. K = 3.11 <106 Find the concentration of free Ba²+ in 0.060 M Na, [Ba(EDTA)] at pH 9.00. [Ba2+] = 1.93 x10-8
The metal ion Mn+ was titrated with 0.0500 M EDTA. The initial solution contained 100.0 mL of 0.0500 M metal ion (Mn+) buffered at a pH of 9.00. a) Calculate the equivalence volume (Veq). b) What is the concentration of the free metal ion at volume V = Veq/2. c) If the conditional formation constant, K’f = 5.4 X 1010, calculate the concentration of free metal ion at volume V = Veq.