4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point (i.e. 50.0 mL EDTA has been added), what is the equilibrium concentration of Ca2, [Ca2...
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of logKf for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, αY4−, is 0.041 at pH 9.00. What is Kf′, the conditional formation constant, for Ca2+ at pH 9.00? Kf′= What is the equivalence point volume, Ve, in milliliters? Ve= mL Calculate the concentration of Ca2+ at V=12Ve. [Ca2+]= M Calculate the concentration...
A 140.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log?f for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, ?Y4− , is 0.041 at pH 9.00. What is ?′f , the conditional formation constant, for Ca2+ at pH 9.00? ?′f= What is the equivalence point volume, ?e , in milliliters? ?e= mL Calculate the concentration of Ca2+ at ?=12?e . [Ca2+]= M...
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of log Kr for the Ca2-EDTA complex is 10.65 and the fraction of free EDTA in the Y4 form, a, is 0.041 at pH 9.00 What is K, the conditional formation constant, for Ca2+ at pH 9.00? K What is the equivalence point volume, V, in milliliters? C Ve= mL Calculate the concentration of Ca2t at V Ca2+ М Calculate the...
A 150.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log Kr for the Ca2+-EDTA complex is 10.65 and the fraction of free EDTA in the Y- form, ay, is 0.041 at pH 9.00. What is K/, the conditional formation constant for Ca²+ at pH 9.00? What is the equivalence point volume, Ve, in milliliters? ml V = Ve= Calculate the concentration of Ca²+ at V = { v. [Ca2+1...
6. (8) A 50.0 mL sample of hard water containing Ca2 was titrated with 0.0500 M EDTA standard solution at pH 10 and with Eriochrome Black T indicator. The endpoint was reached when 11.35 mL of EDTA was added a) (6) Calculate the concentration of Ca* in the unknown sample in moles per liter (M). b) (2) What is the pCa of the solution?
A 100 mL sample of 0.060 M is titrated with 0.060 M EDTA at pH 9.00. The value of Kf for the Ca^2+ -EDTA complex is 10.65 and the fraction of free EDTA in the Y^4- form, ay+ , is at pH 9.00. The Y4- was not given how am i suppose to solve this. What is Kf' , the conditional formation constant, for CA^2+ at pH 9.00? What is the equivalence point volume, Ve, in milliliters? Calculate the concentration...
Complex-Formation Titrations +2 10. Calculate the Ca concentration and pCa logCa D of a solution that results from the mixing of each of the following solutions (buffered at a pH of 10.0): +2 +2 +2 EDTA +10 The complexation reaction: Ca CaEDTA atapH of 10.0, has an Kefr r 5.0 s 10 +2 +10 Kerr-lCaEDTAI/(1 Ca.-11 EDTA I) = 5.0 x 10 a) Calculate the pCa of a solution of 50.0 ml of 0.0102 MCa with 50.0 ml of 0.0100...
You are titrating 130.0 mL of 0.050 M Ca2 with 0.050 M EDTA at pH 9.00. Log K for the Ca2 EDTA complex is 10.65, and the fraction of free EDTA in the Y4-form, *. is 0.041 at pH 9.00. (a) What is Kt, the conditional formation constant, for Ca2 at pH 9.00? Number K: (pH 9.00) = 110 (b) What is the equivalence volume, Ve, in milliliters? Number mL (c) Calculate the concentration of Ca+ at V- 1/2 Ve...
16. (a) Determine the concentration of free Ca* at equilibrium in a solution that initially starts with 0.10 M CaY at a pH of 6.00. Note that the formation constant (Kr) for Ca2+ is 4.47x1010 and the fraction of EDTA in the deprotonated form (av4) at a pH of 6.00 is 1.8x10. (b) Would you expect there to be more or less free Ca2 at a higher pH? (8 pts) Ca2+ + EDTA CaY2 16. (a) Determine the concentration of...
3. A 25.00 mL 0.0250 M calcium carbonate sample is titrated with 14.3 mM EDTA solution. Both sample and titrant are buffered at pH = 10.0 a. What is the titration reaction and what is the value of the conditional formation constant? b. What is the calcium ion concentration when 12.35 mL of titrant has been added? c. What is pCa2+ at the equivalence volume?