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6. (8) A 50.0 mL sample of hard water containing Ca2 was titrated with 0.0500 M...
4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point (i.e. 50.0 mL EDTA has been added), what is the equilibrium concentration of Ca2, [Ca2], and what is the pCa? The formation constant of CaY, Kaa 5.0 x 1010, and α4 of EDTA at pH 10.0 is 0.35 4. 50.0 mL of 0.00200 M Ca2 solution buffer at pH 10.0 is titrated with 0.00200 M EDTA. At equivalence point...
Problem 4: EDTA titration with 16.55 ml of o.0114 M EDTA at pH-10. A 50.0 mL sample of water containing both Ca? and Mg is titrated in another 50.0 mL sample, the Mg* was precipitated as Mg(OH)2 and then, Ca2* was titrated at pH 13 with 9.25 ml of the same EDTA solution. Calculate ppm CaCo, (FW-100.09) and MgCO, (FW-84.31) in the sample. FWca: 40.08; FWm: 24.30 Problem 4: EDTA titration with 16.55 ml of o.0114 M EDTA at pH-10....
A 50.0 mL sample containing Cd2+ and Mn2+ was treated with 51.7 mL of 0.0500M EDTA. Titration of the excess unreacted EDTA required 15.8 mL of 0.0190 M Ca2+. The Cd2+ was displaced from EDTA by the addition of an excess of CN−. Titration of the newly freed EDTA required 13.7 mL of 0.0190 M Ca2+. What are the concentrations of Cd2+ and Mn2+ in the original solution? A 50.0 mL sample containing Cd2+ and Mn2+ was treated with 51.7...
Please help! Will rate. A 50.0 mL sample containing Cd2+ and Mn2+ was treated with 56.5 mL of 0.0600 M EDTA. Titration of the excess unreacted EDTA required 13.3 mL of 0.0100 M Ca. The Cd2t was displaced from EDTA by the addition of an excess of CN. Titration of the newly freed EDTA required 11.2 mL of 0.0100 M Ca2+. What are the concentrations of Cd2+ and Mn2+ in the original solution? M Mn2+ concentration: M Cd2 concentration: A...
A 150.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log Kr for the Ca2+-EDTA complex is 10.65 and the fraction of free EDTA in the Y- form, ay, is 0.041 at pH 9.00. What is K/, the conditional formation constant for Ca²+ at pH 9.00? What is the equivalence point volume, Ve, in milliliters? ml V = Ve= Calculate the concentration of Ca²+ at V = { v. [Ca2+1...
1. A 10.00 mL aliquot of 0.010 M CaCO3 is titrated with 18.22 mL of EDTA solution. What is the EDTA molarity? 2. A 250.0 mL water sample requires 30.85 mL of the EDTA solution from question 1 to reach the calmagite endpoint. What was the molarity of the hard metal ions in the water sample? 3. If the metal ions in the water sample of question 2 are assumed to be Ca2+ from CaCO3, express the concentration in ppm...
Hardness in groundwater is due to the presence of metal ions, primarily Mg2+ and Ca2+. Hardness is generally reported as ppm CaCO3. To measure water hardness, a sample of groundwater is titrated with EDTA, a chelating agent, in the presence of the indicator Eriochrome Black T, symbolized as In. Eriochrome Black T, a weaker chelating agent than EDTA, is red in the presence of Ca2+ and turns blue when Ca2+ is removed. red blue Ca(In)2+ +EDTACa(EDTA) 2+ In A 50.00...
A 50.0 mL sample containing Cd2+ and Mn2+ was treated with 57.2 mL of 0.0700 M EDTA. Titration of the excess unreacted EDTA required 14.6 mL of 0.0150 M Ca2+. The Cd2+ was displaced from EDTA by the addition of an excess of CN“. Titration of the newly freed EDTA required 11.3 mL of 0.0150 M Ca2+. What are the concentrations of Cd2+ and Mn2+ in the original solution? concentration: M Mn2+ concentration: M Cd2+
A 120.0 mL sample of 0.040 M Ca2+ is titrated with 0.040 M EDTA at pH 9.00. The value of logKf for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, αY4−, is 0.041 at pH 9.00. What is Kf′, the conditional formation constant, for Ca2+ at pH 9.00? Kf′= What is the equivalence point volume, Ve, in milliliters? Ve= mL Calculate the concentration of Ca2+ at V=12Ve. [Ca2+]= M Calculate the concentration...
A 140.0 mL sample of 0.080 M Ca2+ is titrated with 0.080 M EDTA at pH 9.00. The value of log?f for the Ca2+−EDTA complex is 10.65 and the fraction of free EDTA in the Y4− form, ?Y4− , is 0.041 at pH 9.00. What is ?′f , the conditional formation constant, for Ca2+ at pH 9.00? ?′f= What is the equivalence point volume, ?e , in milliliters? ?e= mL Calculate the concentration of Ca2+ at ?=12?e . [Ca2+]= M...