Ans :-
Let solubility of Ag2SO4 = S mol/L = 0.0155 M (Given)
Partial dissociation of sparingly soluble salt Ag2SO4 is :
Ag2SO4 (s) <------------------------> 2Ag+ (aq) ..................+.....................SO42- (aq)
.........................................................2S mol/L..............................................S mol/L
Expression of Solubility product (Ksp) which is equal to the product of the molar concentration of products raise to the power of stoichiometric coefficient at equilibrium stage of the reaction.
Ksp = [Ag+]2.[SO42-]
= (2S)2.(S)
= (2 x 0.0155 M)2.(0.0155 M)
= 1.49 x 10-5 M3
Therefore, Ksp of Ag2SO4 = 1.49 x 10-5 M3
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