4. The complexes (Mn(H2O).], [Fe(H2O))", [MnCl] and [FeCl.] all have magnetic moments near 5.92 BM. Explain...
10) The complexes [Mn(H20%)". [Fe(H20%)". [MnClar-and [FeC14]-all have magnetic moments of nearly 5.92 BM. What does this tell you about the geometric and electronic structures of these complexes? Why is the spin-only formula so precise in these cases?
10) The complexes [Mn(H20%)". [Fe(H20%)". [MnClar-and [FeC14]-all have magnetic moments of nearly 5.92 BM. What does this tell you about the geometric and electronic structures of these complexes? Why is the spin-only formula so precise in these cases?
4. For each of the Mn complexes in the table below, give electronic configurations (within the t2g and eg sets of 3d orbitals) that are consistent with the observed magnetic moments. u (BM) 1.8 Compound [Mn(CN)6]4 [Mn(CN)6]3- [Mn(NCS)6]4- [Mn(acac)3] 3.2 6.1 5.0
5 The values of the spin only magnetic moments (uso)of several complexes are given below. Show how these values of uso are consistent with the structure of each complex. (a) uso = 2.83 for [Ni(OH2)]2+ (b) uso = 0 for [Ni(CO)4] (c) uso = 1.73 for [Cu(NH3)6]2+ (d) uso = 3.88 for [Co(OH2).]2+ (e) uso = 5.92 for [Fe(OH2)6]3+ and [Mn(Br)4]?-
5 The values of the spin only magnetic moments (uso)of several complexes are given below. Show how these values of uso are consistent with the structure of each complex (a) uso 2.83 for [Ni(OH2)6]2 (b) uso 0 for [Ni(CO)4 1.73 for [Cu(NH3)6]2 (d)uso 3.88 for [Co(OH2)6]2 (c) uso (e) so 5.92 for [Fe(OH2)e]* and [Mn(Br)4]2
The values of the spin only magnetic moments (uso)of several complexes are given below. Show how these values of uso are consistent with the structure of each complex (a) so 2.83 for [Ni(OH2)e]2 (b) uso 0 for [Ni(CO)4] (d) uso 3.88 for [Co(OH2)6]2* (c) Hso 1.73 for [Cu(NH3)e]2* and [Mn(Br)4]2 (e) so 5.92 for [Fe(OH2)e]
5 The values of the spin only magnetic moments (uso)of several complexes are given below. Show how these values of uso are consistent with the structure of each complex. (a) uso = 2.83 for [Ni(OH2).]2+ (b) uso = 0 for [Ni(CO)4] (c) Mso = 1.73 for [Cu(NH3)6]2+ (d) uso = 3.88 for (Co(OH2)6]2 (e) uso = 5.92 for [Fe(OHz)o]** and [Mn(Br)]2
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
For each of the transition metal ions : (a) [Fe(H2O)4 ]3+ (b) [Mn(H2O)4 Cl2 ]+ (c) [Re(H2O)4 Cl2 ]+ (d) [Co(NH3)2 (en)2]2+ (i) Draw the structure of each transition metal complex. (ii) Determine the number of d electrons (iii) Draw the arrangement of d electrons in the ground state (iv) Calculate the LFSE (in units of deltao or deltaT ) for each complex
4. Consider the following complexes. Na, [Fe(ox),] [Cr(H2O) (NHJ) SO, [Pt(en)(ONO)CI] Write the coordination sphere for the complexes I, II and III. [3 marks] in each of the Determine the oxidation state of the central atom coordination complex [3 marks] Determine the coordination number in each of the complexes. [3 marks) Name each of the complex using IUPAC system [6 marks) Draw the molecular geometry of complex II. [2 marks] Using Crystal Field Theory, draw the energy diagram of the...
please do answer all the questions below. thank you
For each of the following complexes, draw the molecular structure and determine the effective atomic numbers. (i) Na[Fe(CN)s(NH3)3l (i) [Cr(H2O)2(NH3)2(en)]Cl (ii) [Co(o-phen)2(NHs)(NCS))CI (iv) (n3-C3Hs)Co(CO)2] (v) [Fe(diphos)(CO)sl in which diphos Ph2PCH2CH2PPh2 and Ph CsHs (10 marks) (i)/ The K for Fe(OH)4]2-is found to be higher than that found in (5 marks) Zn(OH)4]2-and [Cr(OHM. Explain . Cho and coworkers used the following ligand to react with cobalt. Predict how this ligand would bind...