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VIII. (9 pts.) Each of the following carbocations will rearrange to form a different carbocation. Draw...
Draw the structures of the two carbocation intermediates that might form during the reaction of the...
Draw the structures of the two carbocation intermediates that might form during the reaction of the alkene (below) with HCI. • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • If the two carbocations differ in stability, select the reaction arrow from the dropdown menu, and draw the less stable carb • If two carbocations are energetically equivalent, separate the two structures with...
Name_ 08 (4 pts total) Explain why the formation of the carbocation that leads to the...
Name_ 08 (4 pts total) Explain why the formation of the carbocation that leads to the way product of this reaction is both thermodynamically and kinetically favorable con the formation of the other possible carbocation. (Hint: there are some key terms that I am looking for and none of them are "Marko Rule" -I am asking you to explain why/how Markovnikov's Rule works) нас H.SO H30 C H, H,0 Q8a (2 pts) It is thermodynamically favorable because... Q8b (2 pts)...
1. (4 pts) Rank each of the following carbocations in order of stability (1 most stable...
1. (4 pts) Rank each of the following carbocations in order of stability (1 most stable and 4 least stable). н н сH н Н,с Н,с" H сH; CH3 Hас- H 2. (6 pts total; 2 pts each) Complete the following transformations by indicating the reactant structure or the major organic product(s). Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable. Cl2 Он cat. H2SO H-о Br Br conc. HBra) сн сна 3. (10 pts...
For each of the following pairs of organic molecules, circle the one that would react with...
For each of the following pairs of organic molecules, circle the one that would react with a given nucleophile at a faster rate in the Sw1 reaction, and briefly explain your choice. нссн, vs. H₂C CH₂ CH Hoc tots vs. Ho C^ots 6. Each of the following carbocations can undergo a rearrangement to give a more stable carbocation. In each case, draw the structure of the rearranged carbocation, and show the mechanism of the 1,2 hydride shift or 1,2-alkyl shift...
I. name the following compounds II. write structures for each of the followong structires III.Arrange alkenes from most...
I.
name the following compounds
II. write structures for each of the followong
structires
III.Arrange alkenes from most to least stable
IV. if rearrangement is expected, draw rearranged structure
for wach carbocation
V.
PLEASE HELP, ive been struggling in organic and this is the
review for our 3rd exam. if i can get help (and explanations) for
1-4 it would be a big help
CHM 2210 Examination 3 11/02/18 Directions: Please supply all answers in the spaces provided on both...
For each of the following reactions, draw the structure of the major organic product in the...
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in...
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in methanol (Na* OCH, CH,OH). CH NaOme MeOH CH Compound A Problem 2c Draw the major expected organic product (a) Redraw Compound A as seen in Viewpoint I below left as a Newman projection on the template provided in Problem 2a (below). Hint: Fill in missing Hs ar C2 and C3 to help you get started! (b) Rotate the C2 C3 bond to obtain the...
1. Name the following or Draw the Structure (2 x 3 pts each) a. N-methyl-3-phenylpentan-2-amine OH...
1. Name the following or Draw the Structure (2 x 3 pts each) a. N-methyl-3-phenylpentan-2-amine OH b. OH NH2O 2. Draw the starting materials for the following hydrolysis reactions. (3 pts each) 1. NaOH, H2O a. 3-or 2. HCI, H2O OH OH Ph 1. NaOH, H2O b. HO Н. CH3 OH HPh 2. HCI, H2O 3. Of the following, which form would actually exist at: (5 points) a) pH = 2 (acidic) b) pH = 7 (neutral) c) pH =...
Complete the following chart to predict the IR features that would indicate the presence of vario...
Complete the following chart to predict the IR features that
would indicate the presence of various specific molecular compounds
that might be present as possible impurities in your product of
isobutyl propanoate. Draw the structure of each molecular compound
(any style is okay). Then predict the IR signal(s) one would expect
to see if this were present as a contaminant. Remember, you need to
focus on how you would see each compound added to the product, so
you must not...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
Draw the structures of the two carbocation intermediates that might form during the reaction of the alkene (below) with HCI. • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • If the two carbocations differ in stability, select the reaction arrow from the dropdown menu, and draw the less stable carb • If two carbocations are energetically equivalent, separate the two structures with...
Name_ 08 (4 pts total) Explain why the formation of the carbocation that leads to the way product of this reaction is both thermodynamically and kinetically favorable con the formation of the other possible carbocation. (Hint: there are some key terms that I am looking for and none of them are "Marko Rule" -I am asking you to explain why/how Markovnikov's Rule works) нас H.SO H30 C H, H,0 Q8a (2 pts) It is thermodynamically favorable because... Q8b (2 pts)...
1. (4 pts) Rank each of the following carbocations in order of stability (1 most stable and 4 least stable). н н сH н Н,с Н,с" H сH; CH3 Hас- H 2. (6 pts total; 2 pts each) Complete the following transformations by indicating the reactant structure or the major organic product(s). Place your answer(s) in the space provided. Be certain to indicate stereochemistry where applicable. Cl2 Он cat. H2SO H-о Br Br conc. HBra) сн сна 3. (10 pts...
For each of the following pairs of organic molecules, circle the one that would react with a given nucleophile at a faster rate in the Sw1 reaction, and briefly explain your choice. нссн, vs. H₂C CH₂ CH Hoc tots vs. Ho C^ots 6. Each of the following carbocations can undergo a rearrangement to give a more stable carbocation. In each case, draw the structure of the rearranged carbocation, and show the mechanism of the 1,2 hydride shift or 1,2-alkyl shift...
I.
name the following compounds
II. write structures for each of the followong
structires
III.Arrange alkenes from most to least stable
IV. if rearrangement is expected, draw rearranged structure
for wach carbocation
V.
PLEASE HELP, ive been struggling in organic and this is the
review for our 3rd exam. if i can get help (and explanations) for
1-4 it would be a big help
CHM 2210 Examination 3 11/02/18 Directions: Please supply all answers in the spaces provided on both...
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
1. [10 pts] Consider the elimination reaction for the following alkyl halide with sodium methoxide in methanol (Na* OCH, CH,OH). CH NaOme MeOH CH Compound A Problem 2c Draw the major expected organic product (a) Redraw Compound A as seen in Viewpoint I below left as a Newman projection on the template provided in Problem 2a (below). Hint: Fill in missing Hs ar C2 and C3 to help you get started! (b) Rotate the C2 C3 bond to obtain the...
1. Name the following or Draw the Structure (2 x 3 pts each) a. N-methyl-3-phenylpentan-2-amine OH b. OH NH2O 2. Draw the starting materials for the following hydrolysis reactions. (3 pts each) 1. NaOH, H2O a. 3-or 2. HCI, H2O OH OH Ph 1. NaOH, H2O b. HO Н. CH3 OH HPh 2. HCI, H2O 3. Of the following, which form would actually exist at: (5 points) a) pH = 2 (acidic) b) pH = 7 (neutral) c) pH =...
Complete the following chart to predict the IR features that
would indicate the presence of various specific molecular compounds
that might be present as possible impurities in your product of
isobutyl propanoate. Draw the structure of each molecular compound
(any style is okay). Then predict the IR signal(s) one would expect
to see if this were present as a contaminant. Remember, you need to
focus on how you would see each compound added to the product, so
you must not...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
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