Homework Answers
Please answer each part with work shown. Thank you. 6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +...
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
3a. Write the overall reaction equation for the following mechanism. Identify the intermediates. fast slow fast...
3a. Write the overall reaction equation for the following mechanism. Identify the intermediates. fast slow fast 02 20 O+N2 NO N b. The rate law for the following mechanism is rate kIN2] [O]. Show how this can be determined from the mechanism. c. Draw a possible energy diagram for this reaction and show the location of the reactants, products, and intermediates. Reaction progress
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 ...
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 + O2 slow; rate determining step Step 2 NO3 + NO2 --> N2O5 fast a. What is the overall reaction? b. Identify the intermediates in the mechanism. c. Write the rate law expression for each step of the mechanism including any reversible reactions. c. What is the predicted rate law expression? Be sure to only list reactants from the overall equation and not intermediates...
Question 8 Step 1: H,02 + I +10- +H,0 Step 2: H,02 + 10 + H2O...
Question 8 Step 1: H,02 + I +10- +H,0 Step 2: H,02 + 10 + H2O + O2 +I" The mechanism for a chemical reaction is shown above. Which of the following statements about the overall reaction and rate laws of the elementary reactions is correct? The chemical equation for the overall reaction is 2 H202 + I and the rate law for elementary step 2 is rate = k[H,02][10 + 2 H2O + O2 +I , ]. + H2O...
A proposed mechanism for a reaction is as follows: NO2(g) + NO2(g) + N204(8) Fast/Equilibrium Step...
A proposed mechanism for a reaction is as follows: NO2(g) + NO2(g) + N204(8) Fast/Equilibrium Step N2048) -> NO(g) + NO3(g) Slow NO3(g) NO) + O2(g) Fast The target rate law is rate = k (NO2)2 The target reaction is 2NO2(e) 2NON + O2) A. Write the rate law expected for this mechanism: B. What is the rate-determining step? C. What is the overall balanced equation for this mechanism? D. If there is/are a reactive intermediate(s), which is/are they? E....
#13 Interpreting Mechanisms 1. Consider the following mechanism: Step 1 Br2  
#13 Interpreting Mechanisms 1. Consider the following mechanism: Step 1 Br2 2Br fast Step 2 Br + H2 H2Br fast Step 3 H2Br + Br 2HBr slow a. What is the overall equation? b. Identify the intermediate(s) if any. c. What is the molecularity and the rate law for each step including any reversible steps? d. What is the predicted rate law expression for this reaction. Be sure to only list reactants from the overall equation and...
Predict the overall reaction from the following two-step mechanism: 2 A→A 2(fast) A2+B→A2B(slow) Express your answer...
Predict the overall reaction from the following two-step mechanism: 2 A→A 2(fast) A2+B→A2B(slow) Express your answer as a chemical equation. Predict the rate law from the following two-step mechanism: 2A⇌ A2 (fast) A2+B→A2B (slow)
Hello! Can someone help me and solve these? Thank you! 4. The following mechanism has been...
Hello! Can someone help me and solve these? Thank you!
4. The following mechanism has been proposed for a reaction: Step 1 H2(g) + Step 2 O(g) + O2(g) H2(g) → O(g) H2O(g) + H2O(g) → (a) What is the equation for the overall reaction? (b) What are the expected rate laws for Step 1 and Step 2? Step 1 - Step 2 (c) What if any intermediates are there? (d) If step 1 is slow and step 2 is...
You are given the mechanism below (Part 1): (1) A = 00 fast, equilibrium (2) B...
You are given the mechanism below (Part 1): (1) A = 00 fast, equilibrium (2) B + C – D slow (3) C + D - E fast How many intermediates are present in the above proposed mechanism? O a. 1 O b.3 O c. 2 do You are given the mechanism below (Part 2): (1) A = B fast, equilibrium (2) B+C - D slow (3) C + D E fast What will the coefficient be of C in...
1. The following mechanism has been proposed for the pas-phase reaction of chloroform and chlorine Ch> 20 (fast)...
1. The following mechanism has been proposed for the pas-phase reaction of chloroform and chlorine Ch> 20 (fast) CI + CHCI, - HCI +CCI, (slow) Cl + CCI - CCI (fast) a) Identify any intermediate(s): b) Identify any catalyst(s): b) Write the balanced equation for the overall reaction: c) Molecularity of each step: step 1. step 2. step 3 d) rds (circle): 1 2 3 d) What is the observable rate law predicted by this mechanism? e) What is the...
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
3a. Write the overall reaction equation for the following mechanism. Identify the intermediates. fast slow fast 02 20 O+N2 NO N b. The rate law for the following mechanism is rate kIN2] [O]. Show how this can be determined from the mechanism. c. Draw a possible energy diagram for this reaction and show the location of the reactants, products, and intermediates. Reaction progress
Question 8 Step 1: H,02 + I +10- +H,0 Step 2: H,02 + 10 + H2O + O2 +I" The mechanism for a chemical reaction is shown above. Which of the following statements about the overall reaction and rate laws of the elementary reactions is correct? The chemical equation for the overall reaction is 2 H202 + I and the rate law for elementary step 2 is rate = k[H,02][10 + 2 H2O + O2 +I , ]. + H2O...
A proposed mechanism for a reaction is as follows: NO2(g) + NO2(g) + N204(8) Fast/Equilibrium Step N2048) -> NO(g) + NO3(g) Slow NO3(g) NO) + O2(g) Fast The target rate law is rate = k (NO2)2 The target reaction is 2NO2(e) 2NON + O2) A. Write the rate law expected for this mechanism: B. What is the rate-determining step? C. What is the overall balanced equation for this mechanism? D. If there is/are a reactive intermediate(s), which is/are they? E....
Hello! Can someone help me and solve these? Thank you!
4. The following mechanism has been proposed for a reaction: Step 1 H2(g) + Step 2 O(g) + O2(g) H2(g) → O(g) H2O(g) + H2O(g) → (a) What is the equation for the overall reaction? (b) What are the expected rate laws for Step 1 and Step 2? Step 1 - Step 2 (c) What if any intermediates are there? (d) If step 1 is slow and step 2 is...
You are given the mechanism below (Part 1): (1) A = 00 fast, equilibrium (2) B + C – D slow (3) C + D - E fast How many intermediates are present in the above proposed mechanism? O a. 1 O b.3 O c. 2 do You are given the mechanism below (Part 2): (1) A = B fast, equilibrium (2) B+C - D slow (3) C + D E fast What will the coefficient be of C in...
1. The following mechanism has been proposed for the pas-phase reaction of chloroform and chlorine Ch> 20 (fast) CI + CHCI, - HCI +CCI, (slow) Cl + CCI - CCI (fast) a) Identify any intermediate(s): b) Identify any catalyst(s): b) Write the balanced equation for the overall reaction: c) Molecularity of each step: step 1. step 2. step 3 d) rds (circle): 1 2 3 d) What is the observable rate law predicted by this mechanism? e) What is the...
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