You are working in a lab and need to make a buffer with a pH = 5.50. You have 5.00 M NaOH and 5.00 M HCl available. You observe that malonic acid (HO2CCH2CO2H or H2A) has pK1 = 2.847 and pK2 = 5.696. Given the mass of malonic acid needed from the last problem, how many mL of NaOH solution is needed to give a pH of 5.50 in the buffer solution? Assume that you will make 500. mL of the buffer with a total buffer concentration of 0.100 M. Mass of malonic acid = 5.2 grams
Consider a 0.0100 M solution of malonic acid (H2A) with pKa1 = 2.847 and pKa2 = 5.696 a. Calculate the pH of the solution. b. Calculate the fraction of malonic acid existing as A2-. Does the second dissociation step make a significant contribution to the H+ in solution?
3. You are asked to make a buffer solution with a pH of 3.40 by using 0.100 M HNO, and 0.100 M NaOH (aq). a. Explain why the addition of 0.100 M HNO2 to 0.100 M NaOH(aq) can result in the formation of a buffer solution. Include the net ionic equations for the reaction that occurs when you combine HNO2 (aq) and NaOH(aq). Determine the volume, in ml, of 0.100 NaOH(aq) the student should add to 100 mL of 0.100...
Calculate the grams of sodium acetate required to make 250.0 mL of a pH 5.50 buffer solution using 0.100 M acetic acid (Ka of 1.8x10-5).
To make 1.00 L of a 0.100 M H2PO4- / HPO42- buffer at pH 6.90 and you start with the NaH2PO4, A. Calculate the mass of NaH2PO4 needed to make the buffer. B. Should HCl or NaOH be added to make the final buffer? Calculate the number of moles of HCl or NaOH that needs to be added. Note: formula mass of NaH2PO4 is 120.
Calculate the pH of a buffer made from mixing 10.0 mL of 0.100 M NaC3H2O, and 10.0 mL of 0.100 M HC,H,O2 pH 4.76 Calculate the pH of the buffer when 5.00 mL of a 0.0100 M NaOH solution is added. pH Calculate the pH of the buffer when 5.00 mL of a 0.0100 M HCl solution is added.
5. You need to make 500.0 mL of a buffer with a pH of 2.20. You have the following substances to work with: 0.100 M NH3 Solid NaN3 Solid NaClO2 0.100 M HClO2 Solid NH4Cl Solid Na2SO3 0.100 M HN3 Solid NaHSO3 Ka for HClO2 = 1.1x10-2 Kb for NH3 = 1.8x10-5 Ka for HN3 = 1.9x10-5 Ka1 for H2SO3 = 1.7x10-2 Ka2 for H2SO3 = 6.4x10-8 (Assume that the addition of solid does not change the volume of the...
You are asked to prepare 500. mL 0.150 M acetate buffer at pH 5.00 using only pure acetic acid (MW = 60.05 g/mol, pKa = 4.76), 3.00 M NaOH, and water. How many grams of acetic acid will be needed to prepare the 500. mL buffer? Note that the given concentration of acetat refers to the concentration of all acetate species in solution. mass: What volume of 3.00 M NaOH, must be added to the acetic acid to achieve a...
Your lab TA asks you to prepare a buffer solution with a pH of 7.40. The following reagents are all available to you: 550 mL of 0.200 M formic acid, 450 mL of 0.200 M hypochlorous acid, solid sodium formate and solid sodium hypochlorite. a) Which 2 ingredients will you use to prepare the desired buffer? b) What is the base/acid ratio in the desired buffer? c) What mass (in g) of solid base must you dissolve in the corresponding...
how to calculate the buffer capacity and how can i solve the properties of buffer 2 solution. i already some calculations put im not sure if I'm correct КИХр. Data Sheet Moles of acetic acid contained in 50.0 mL of a 0.10 M sample solution: 0.00 Smule 50.0mL XL -> 0.05-24 0.1om Buffer pH Study 1000mL IL Buffer Sample initial pH: 4.71 buller. DH and kavalehe Sume. How mane marremalol pH after addition of 0.100 M HCI Mass of sodium...
A buffer with a pH of 3.92 contains 0.19 M of sodium benzoate and 0.36 M of benzoic acid. What is the concentration of [H3O+] in the solution after the addition of 0.054 mol HCl to a final volume of 1.7 L? Assume that any contribution of HCl to the volume is negligible. [H3O+] = M Allerede C., Calculate the change in pH when 7.00 mL of 0.100 M HCl(aq) is added to 100.0 mL of a buffer solution that...