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(4 points). How can a 1st order (i.e. 1st derivative) thermodynamic plot be used to determine if a change in the degree of cr
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Crystallinity defines the degree of long-range order in a material, and strongly affects its properties. The more crystalline a polymer, the more regularly aligned its chains. Increasing the degree of crystallinity increases hardness and density.

Polymer crystallinity can be determined with DSC by quantifying the heat associated with melting (fusion) of the polymer. This heat is reported as Percent Crystallinity by normalizing the observed heat of fusion to that of a 100 % crystalline sample of the same polymer.

The specific enthalpy of fusion of a sample determined from the peak area is proportional to its degree of crystallinity. The proportionality factor, Δhc, is equal to the enthalpy of fusion of a 100% crystalline material. If the value is known, the degree of crystallinity can be determined from the melting curve.

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