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Section 16.5: Voltaic Cells under Non-standard Conditions 16.64 The half-cells Fe2+ (aq, 0.024 mol L-'Fe(s) and...
question 16.46 UU 15 - UU UL ut tu uve- 16.46 The half-cells Fe2+ (aq)|Fe(s) and...
question 16.46
UU 15 - UU UL ut tu uve- 16.46 The half-cells Fe2+ (aq)|Fe(s) and O2(g)|H2O (in acid solution) are linked to create a voltaic cell. (a) Write equations for the oxidation and reduction half- reactions and for the overall cell reaction. (b) Which half-reaction occurs in the anode compart- ment and which occurs in the cathode compartment? (c) Complete the following sentences: Electrons in the external circuit flow from the — electrode to the electrode. Negative ions move...
79. Two half-cells, PtlFe3+(aq, 0.50 M), Fe2 +(aq, 1.0 x 10-5 M) and Hg (aq, 0.020...
79. Two half-cells, PtlFe3+(aq, 0.50 M), Fe2 +(aq, 1.0 x 10-5 M) and Hg (aq, 0.020 M)IHg, are constructed and then linked together to form a voltaic cell. Which electrode is the anode? What will be the potential of the voltaic cell at 298 K:
A voltaic cell utilizes the following reaction: 2Fe3+(aq)+H2(g)→2Fe2+(aq)+2H+(aq). emf of this cell under standard conditions E∘...
A voltaic cell utilizes the following reaction: 2Fe3+(aq)+H2(g)→2Fe2+(aq)+2H+(aq). emf of this cell under standard conditions E∘ = 0.771 V What is the emf for this cell when [Fe3+]= 3.70 M , PH2= 0.95 atm , [Fe2+]= 1.0×10−3 M , and the pH in both compartments is 3.95? Express your answer using two significant figures.
Half-Reaction Fe2+(aq) + 2e Fe(s) Hg2+ (aq) + 2e Hg() Ag+ (aq) + e + Ag(s)...
Half-Reaction Fe2+(aq) + 2e Fe(s) Hg2+ (aq) + 2e Hg() Ag+ (aq) + e + Ag(s) Cu2+ (aq) + 2e + Cu(s) Zn2+ (aq) + 2e → Zn(s) E (V) -0.44 0.86 0.80 0.34 - 0.76 Using the table, calculate Eºcell for the following electrochemical cell under standard conditions voltmeter a) 1.24 V Fe. salt bridge Ag b) -1.24 V c) 2.04 V d) - 2.04 V Ag a b С
Separate galvanic cells are made from the following half-cells: cell 1: H+(aq)/H2(g) and Pb2+(aq)/Pb(s) cell 2:...
Separate galvanic cells are made from the following half-cells: cell 1: H+(aq)/H2(g) and Pb2+(aq)/Pb(s) cell 2: Fe2+(aq)/Fe(s) and Zn2+(aq)/Zn(s) Which of the following is correct for the working cells? Standard reduction potentials, 298 K, Aqueous Solution (pH = 0): Cl2(g) + 2e --> 2C1-(aq); E° = +1.36 V Fe3+(aq) + e --> Fe2+(aq); E° = +0.77 V Cu2+(aq) + 2e --> Cu(s); E° = +0.34 V 2H+(aq) + 2e --> H2(g); E° = 0.00 V Pb2+(aq) + 2e --> Pb(s);...
18. Identify the metal if during a 1.000 hour long 2 electron electrolysis reaction 8.388 g...
18. Identify the metal if during a 1.000 hour long 2 electron electrolysis reaction 8.388 g of metal is deposited using a constant current of 4.000 A. 19. The standard cell potential (F) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +2H (aq) Zn2+(aq)+ H2(g) With PH2 1.0 atm and [Zn2]-1.0 mol L-1, the cell potential is 0.45 V. The concentration of Ht in the cathode compartment ismol L-1, Long Answer 20. A galvanic...
1. A voltaic cell is constructed that is based on the following reaction: Sn2+(aq)+Pb(s)→Sn(s)+Pb2+(aq). A. If...
1. A voltaic cell is constructed that is based on the following reaction: Sn2+(aq)+Pb(s)→Sn(s)+Pb2+(aq). A. If the concentration of Sn2+ in the cathode compartment is 1.30 M and the cell generates an emf of 0.25 V , what is the concentration of Pb2+ in the anode compartment? B. If the anode compartment contains [SO2−4]= 1.30 M in equilibrium with PbSO4(s), what is the Ksp of PbSO4? 2. A voltaic cell utilizes the following reaction: 2Fe3+(aq)+H2(g)→2Fe2+(aq)+2H+(aq). A. What is the emf...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq,...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq, 0.500 M) || Cu2+(aq, 1.00 M) Cu(s) Candidate 3: Mg(s) | Mg2+(aq, 0.500 M) | Pb2+(aq, 1.00 M)| Pb(s) (a) 6 pts) Choose one of the candidate voltaic cells #1, #2, or #3. Draw a schematic cell diagram for the candidate voltaic cell of choice. Clearly label anode, cathode, electrodes, ions and their concentrations, salt bridge, and the flow of electrons. (b) (5 pts)...
NO−3(aq)+4H+(aq)+3e−→NO(g)+2H2O(l) E∘=0.96V ClO2(g)+e−→ClO−2(aq) E∘=0.95V Cu2+(aq)+2e−→Cu(s) E∘=0.34V 2H+(aq)+2e−→H2(g) E∘=0.00V Pb2+(aq)+2e−→Pb(s) E∘=−0.13V Fe2+(aq)+2e−→Fe(s) E∘=−0.45V You may want to...
NO−3(aq)+4H+(aq)+3e−→NO(g)+2H2O(l) E∘=0.96V ClO2(g)+e−→ClO−2(aq) E∘=0.95V Cu2+(aq)+2e−→Cu(s) E∘=0.34V 2H+(aq)+2e−→H2(g) E∘=0.00V Pb2+(aq)+2e−→Pb(s) E∘=−0.13V Fe2+(aq)+2e−→Fe(s) E∘=−0.45V You may want to reference (Pages 898 - 902) Section 19.4 while completing this problem. Part A Use data from the table above to calculate E∘cell for the reaction. Fe(s)+2H+(aq)→Fe2+(aq)+H2(g) Express your answer using two decimal places.
all questions pleasee 2. Which of the following reactions will have the larger emfnder s ave the larger emf under standard conditions? Why? CuSO (aq)+Pb(s)PbsO ()+Cu(s) Cu(NO, ag)+P)P(NO,)a)+Cu) 3...
all questions pleasee
2. Which of the following reactions will have the larger emfnder s ave the larger emf under standard conditions? Why? CuSO (aq)+Pb(s)PbsO ()+Cu(s) Cu(NO, ag)+P)P(NO,)a)+Cu) 3. Calculate AG for the reaction in Example 17.3. 4. Voltages listed in textbooks and handbooks are given as standard cell potentials volitas What is ceWere the cells constructed in this experiment standard cells? Why or why not? . As a standard voltaic cell runs, it "discharges" and the cell potential decreases...
question 16.46
UU 15 - UU UL ut tu uve- 16.46 The half-cells Fe2+ (aq)|Fe(s) and O2(g)|H2O (in acid solution) are linked to create a voltaic cell. (a) Write equations for the oxidation and reduction half- reactions and for the overall cell reaction. (b) Which half-reaction occurs in the anode compart- ment and which occurs in the cathode compartment? (c) Complete the following sentences: Electrons in the external circuit flow from the — electrode to the electrode. Negative ions move...
79. Two half-cells, PtlFe3+(aq, 0.50 M), Fe2 +(aq, 1.0 x 10-5 M) and Hg (aq, 0.020 M)IHg, are constructed and then linked together to form a voltaic cell. Which electrode is the anode? What will be the potential of the voltaic cell at 298 K:
Half-Reaction Fe2+(aq) + 2e Fe(s) Hg2+ (aq) + 2e Hg() Ag+ (aq) + e + Ag(s) Cu2+ (aq) + 2e + Cu(s) Zn2+ (aq) + 2e → Zn(s) E (V) -0.44 0.86 0.80 0.34 - 0.76 Using the table, calculate Eºcell for the following electrochemical cell under standard conditions voltmeter a) 1.24 V Fe. salt bridge Ag b) -1.24 V c) 2.04 V d) - 2.04 V Ag a b С
Separate galvanic cells are made from the following half-cells: cell 1: H+(aq)/H2(g) and Pb2+(aq)/Pb(s) cell 2: Fe2+(aq)/Fe(s) and Zn2+(aq)/Zn(s) Which of the following is correct for the working cells? Standard reduction potentials, 298 K, Aqueous Solution (pH = 0): Cl2(g) + 2e --> 2C1-(aq); E° = +1.36 V Fe3+(aq) + e --> Fe2+(aq); E° = +0.77 V Cu2+(aq) + 2e --> Cu(s); E° = +0.34 V 2H+(aq) + 2e --> H2(g); E° = 0.00 V Pb2+(aq) + 2e --> Pb(s);...
18. Identify the metal if during a 1.000 hour long 2 electron electrolysis reaction 8.388 g of metal is deposited using a constant current of 4.000 A. 19. The standard cell potential (F) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn(s) +2H (aq) Zn2+(aq)+ H2(g) With PH2 1.0 atm and [Zn2]-1.0 mol L-1, the cell potential is 0.45 V. The concentration of Ht in the cathode compartment ismol L-1, Long Answer 20. A galvanic...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq, 0.500 M) || Cu2+(aq, 1.00 M) Cu(s) Candidate 3: Mg(s) | Mg2+(aq, 0.500 M) | Pb2+(aq, 1.00 M)| Pb(s) (a) 6 pts) Choose one of the candidate voltaic cells #1, #2, or #3. Draw a schematic cell diagram for the candidate voltaic cell of choice. Clearly label anode, cathode, electrodes, ions and their concentrations, salt bridge, and the flow of electrons. (b) (5 pts)...
all questions pleasee
2. Which of the following reactions will have the larger emfnder s ave the larger emf under standard conditions? Why? CuSO (aq)+Pb(s)PbsO ()+Cu(s) Cu(NO, ag)+P)P(NO,)a)+Cu) 3. Calculate AG for the reaction in Example 17.3. 4. Voltages listed in textbooks and handbooks are given as standard cell potentials volitas What is ceWere the cells constructed in this experiment standard cells? Why or why not? . As a standard voltaic cell runs, it "discharges" and the cell potential decreases...
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