1) Give definition of half-lifetime. How is that defined?
2) How does the half-lifetime for a zero-order reaction depend on rate constant? how does that depend on reactant initial concentration?
3) How does the half-lifetime for a first-order reaction depend on rate constant and initial reactant concentration?
4) How does the half-lifetime for second-order reaction depend on rate constant and initial reactant concentration?
5) Someone monitored a reaction by observing the time it took for the reactant concentration halve. It was observed that from the initial concentration of 0.01M to 0.005M, it took 10sec, and then from 0.005M to 0.0025M it took 20sec. What reaction order this reaction likely is? How do you make conclusion, please explain.
1) Give definition of half-lifetime. How is that defined? 2) How does the half-lifetime for a...
Someone monitored a reaction by observing the time it took for the reactant concentration halve. It was observed that from the initial concentration of 0.01M to 0.005M, it took 10sec, and then from 0.005M to 0.0025M it took 20sec. What reaction order this reaction likely is? How do you make conclusion, please explain.
Under constant conditions, the half-life of a first-order reaction ________ Select one: A. All of the options are correct B. is constant C. does not depend on the initial reactant concentration D. can be calculated from the reaction rate constant E. is the time necessary for the reactant concentration to drop to half its original value
1. A certain first order reaction has a rate constant of 0.036 min-1. How much of the reactant will remain if the reaction is run for 2.5 hours and the initial concentration of the reactant is 0.31 M? 2. A certain first order reaction has a rate constant of 0.036 min-1. How much of the reactant will remain if the reaction is run for 2.5 hours and the initial concentration of the reactant is 0.31 M? 3. The rate constant...
The half-life of a reaction, t1/2, is the time it takes for the reactant concentration [A] to decrease by half. For example, after one half-life the concentration falls from the initial concentration [A]0 to [A]0/2, after a second half-life to [A]0/4, after a third half-life to [A]0/8, and so on. on. For a first-order reaction, the half-life is constant. It depends only on the rate constant k and not on the reactant concentration. It is expressed as t1/2=0.693k For a...
+ Half-life for First and Second Order Reactions 11 of 11 The half-life of a reaction, t1/2, is the time it takes for the reactant concentration A to decrease by half. For example, after one half-Me the concentration falls from the initial concentration (Alo to A\o/2, after a second half-life to Alo/4 after a third half-life to A./8, and so on. on Review Constants Periodic Table 11/25 For a second-order reaction, the half-life depends on the rate constant and the...
Half-life equation for first-order reactions: t1/2=0.693k where t1/2 is the half-life in seconds (s), and k is the rate constant in inverse seconds (s−1). a) What is the half-life of a first-order reaction with a rate constant of 4.80×10−4 s−1? b) What is the rate constant of a first-order reaction that takes 188 seconds for the reactant concentration to drop to half of its initial value? Express your answer with the appropriate units. c)A certain first-order reaction has a rate constant...
4) Consider the schematic reaction A →P a) If the reaction is one-half order with respect to [A], what is the integrated rate law expression for this reaction? b) What plot would you construct to determine the rate constant k for the reaction? c) What would be the half-life for this reaction? Will it depend on initial concentration of the reactant'?
2. Answer the following questions by connecting the half-life of each first-order reaction to the rate constant. a. The rate constant of a first-order reaction is 2.43 × 10–2 min–1. What is the half-life of the reaction? (2 points) b. A first-order reaction has a rate constant of 0.547 min-1. How long will it take a reactant concentration 0.14 M to decrease to 0.07 M? (2 points) c. The half-life of a first-order reaction is 5.47 min. What is the...
A first-order reaction has a half-life of 20.8 s . How long does it take for the concentration of the reactant in the reaction to fall to one-fourth of its initial value?
For a first-order reaction, the half-life is constant. It depends only on the rate constant k k and not on the reactant concentration. It is expressed as t1/2=0.693k t 1 / 2 = 0.693 k For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as t1/2=1k[A]0. A certain first-order reaction (A→products A → p r o d u c t s ) has a rate constant of 9.30×10−3...