1. a)
b)
c)
1. Provide the product and mechanism for the following reactions a) HBr 2 equiv. b) H2SO4...
1. Provide the product and mechanism for the following HBr 2 equiv. H2SO4 HgSO4 H2O *No reaction mechanism necessary 1) BH3 2) H2O2, NaOH *No reaction mechanism necessary
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr HBr (1 equivalent) (2 equivalents) Br2 Br2 (1 equivalent) CH2Cl2 (2 equivalents) CH2Cl2 HO HgSO4, H2SO4 1) disyamylborane 2) H202, NaOH, H2O
Predict the major organic product or products of each of the following reactions: Identify the mechanism taking place in each of the reactions and please provide explanation. H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
101 3. Provide the products for the following reactions below. 54K 01 OP 1) NaNH2 2) CH3BT 38 HBr (1 equiv.) ( H2. Lindlar catalyst 1) BH3. THE 2) H2O2, OH H2O, H2SO4, HgSO4 Excess Hz, Pd/C 1809 4. An unknown hydrocarbon has the molecular formula CxHjo. Upon catalytic hydrogenation over Lindlar catalyst, 1 equivalent of H2 is absorbed. On hydrogenation over a palladium catalyst, 3 equivalents of H2 are absorbed. a) How many degrees of unsaturation are present in...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
With explanation please! 10.(30 pts) Provide the major product(s) for the following reactions. (Remember: Stereochemistry and regiochemistry!). ( = H HBr (1 equiv) ROOR Bra (1 equiv) HgSO4, H20, H2SO4 1) RzBH 2) H202, NaOH 1) 03 2) H30 مجلس
Problem #4 Draw the substitution product from each of the following reactions. 1. BH3-THF 2. H2O2, NaOH ( =CH HgSO4 H2SO4 H2O Extra Credit Show how you would accomplish the following conversion. More than one step is likely necessary.
Predict the products of the following reactions 1 equivalent HBr NaNH2 Br (excess) 1. Sia BH, THE 2. H2O2, NaOH HgSO4 H2SO4 H20
2. Give the product(s) of the reactions below, then draw the mechanism. HBr B H2SO4 H2O