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1. Provide the product and mechanism for the following HBr 2 equiv. H2SO4 HgSO4 H2O *No...
1. Provide the product and mechanism for the following reactions a) HBr 2 equiv. b) H2SO4...
1. Provide the product and mechanism for the following reactions a) HBr 2 equiv. b) H2SO4 HgSO4 HO *No reaction mechanism necessary 1) BH3 2) H2O2, NaOH
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr HBr (1 equivalent)...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr HBr (1 equivalent) (2 equivalents) Br2 Br2 (1 equivalent) CH2Cl2 (2 equivalents) CH2Cl2 HO HgSO4, H2SO4 1) disyamylborane 2) H202, NaOH, H2O
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
101 3. Provide the products for the following reactions below. 54K 01 OP 1) NaNH2 2) CH3BT 38 HBr (1 equiv.) ( H2. L...
101 3. Provide the products for the following reactions below. 54K 01 OP 1) NaNH2 2) CH3BT 38 HBr (1 equiv.) ( H2. Lindlar catalyst 1) BH3. THE 2) H2O2, OH H2O, H2SO4, HgSO4 Excess Hz, Pd/C 1809 4. An unknown hydrocarbon has the molecular formula CxHjo. Upon catalytic hydrogenation over Lindlar catalyst, 1 equivalent of H2 is absorbed. On hydrogenation over a palladium catalyst, 3 equivalents of H2 are absorbed. a) How many degrees of unsaturation are present in...
Predict the major organic product or products of each of the following reactions: Identify the mechanism...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
4. Complete the mechanism for the following reactions. (8pt) HgSO4 H2O, H2So4 а. 1. Sia2BH b....
4. Complete the mechanism for the following reactions. (8pt) HgSO4 H2O, H2So4 а. 1. Sia2BH b. 2. H202, NaOH No need to show the C-B to C-OH step. ons. M
Draw the substitution product for the following reaction. HgSO4 H2SO4 H2O
Draw the substitution product for the following
reaction.
HgSO4 H2SO4 H2O
Problem #4 Draw the substitution product from each of the following reactions. 1. BH3-THF 2. H2O2,...
Problem #4 Draw the substitution product from each of the following reactions. 1. BH3-THF 2. H2O2, NaOH ( =CH HgSO4 H2SO4 H2O Extra Credit Show how you would accomplish the following conversion. More than one step is likely necessary.
In each reaction box, place the best reagent and conditions from the list below. OOY NaBHA CH3CH2Br 2 equiv. NaNH2 Brz...
In each reaction box, place the best reagent and conditions from the list below. OOY NaBHA CH3CH2Br 2 equiv. NaNH2 Brz BHY/THF H2O2. NaOH, H20 SOCI HBR H2. Lindlar catalyst H20, H2SO4, HgSO4 bromocyclohexane excess NaNH2, then H2O CH3Br
1. Provide the product and mechanism for the following reactions a) HBr 2 equiv. b) H2SO4 HgSO4 HO *No reaction mechanism necessary 1) BH3 2) H2O2, NaOH
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr HBr (1 equivalent) (2 equivalents) Br2 Br2 (1 equivalent) CH2Cl2 (2 equivalents) CH2Cl2 HO HgSO4, H2SO4 1) disyamylborane 2) H202, NaOH, H2O
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
101 3. Provide the products for the following reactions below. 54K 01 OP 1) NaNH2 2) CH3BT 38 HBr (1 equiv.) ( H2. Lindlar catalyst 1) BH3. THE 2) H2O2, OH H2O, H2SO4, HgSO4 Excess Hz, Pd/C 1809 4. An unknown hydrocarbon has the molecular formula CxHjo. Upon catalytic hydrogenation over Lindlar catalyst, 1 equivalent of H2 is absorbed. On hydrogenation over a palladium catalyst, 3 equivalents of H2 are absorbed. a) How many degrees of unsaturation are present in...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
4. Complete the mechanism for the following reactions. (8pt) HgSO4 H2O, H2So4 а. 1. Sia2BH b. 2. H202, NaOH No need to show the C-B to C-OH step. ons. M
Draw the substitution product for the following
reaction.
HgSO4 H2SO4 H2O
Problem #4 Draw the substitution product from each of the following reactions. 1. BH3-THF 2. H2O2, NaOH ( =CH HgSO4 H2SO4 H2O Extra Credit Show how you would accomplish the following conversion. More than one step is likely necessary.
In each reaction box, place the best reagent and conditions from the list below. OOY NaBHA CH3CH2Br 2 equiv. NaNH2 Brz BHY/THF H2O2. NaOH, H20 SOCI HBR H2. Lindlar catalyst H20, H2SO4, HgSO4 bromocyclohexane excess NaNH2, then H2O CH3Br
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