Homework Answers
Water is an aqueous solvent, Diethyl ether is an organic solvent. If isobutyric acid has solubility x in Diethyl ether then it's solubility in water would be X/3. In this two cases concentration of butyric acid becomes equal to their solubility. So the value of partion coefficient is 3.
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Isobutyric acid has a solubility in water (at 25 °C) about 1/3 (one-third) of its solubility...
Extractions rely on differences in solubility of the components that are being separated
Extractions rely on differences in solubility of the components that are being separated. The amount of a material that will transfer into the solvent in an extraction can be calculated using a partition coefficient. This is a ratio of the solubility of the material in each solvent that can be used to predict outcomes of extractions. A certain organic compound, Z, has the distribution coefficient (partition coefficient), Kp = 10.45 when partitioned between ether and water. Therefore, the equation used...
A monoprotic acid, HA, with a Ka of 6.67 × 105 has a partition coefficient of...
A monoprotic acid, HA, with a Ka of 6.67 × 105 has a partition coefficient of 4.0 (favoring octanol) when distributed between water and octanol. Find the formal concentration of the acid in each phase when 100 mL of 0.100 M aqueous acid is extracted with 25 mL of octanol
Exercise 2 Separation of a Mixture Based on Acid-Base Properties One purpose of this exercise is...
Exercise 2 Separation of a Mixture Based on Acid-Base Properties One purpose of this exercise is to learn how to use a separatory funnel to extract a single component away from other compounds in solution. To do so, we will apply the principles of solubility and acid-base behavior you’re seeing in class. One of the compounds is neutral in the acid-base sense. It has no ability to either donate or accept a proton from an aqueous solution, and will remain...
Acid/Base Extraction 1. Provide a flow chart detailing the acid/base extraction/separation of the compounds shown below....
Acid/Base Extraction
1. Provide a flow chart detailing the acid/base
extraction/separation of the compounds shown below. Your answer
must employ the following reagents: methylene chloride,
hydrochloric acid (1M & 6M), sodium hydroxide (1M & 6M),
10% sodium bicarbonate (aq). Clearly indicate the product(s) and
layers formed following each step of your separation scheme.
IMPORTANT: p-cresol is soluble in sodium hydroxide solution but
insoluble in neutral water or sodium bicarbonate solution. 2-
ethylbenzoic acid is soluble in both sodium hydroxide and...
You will apply what you have learned earlier in the semester when performing the Acid-Base Extraction...
You will apply what you have learned earlier in the semester when performing the Acid-Base Extraction experiment to perform a different separation: that of an organic neutral compound and organic base. You will also need to purify and characterize these compounds. You will have one lab period to execute your plan for separating the assigned mixture given below. There will be a 1:1 (by mass) mixture placed in the lab: 1,4-dichlorobenzene/ethyl 4-aminobenzoate. You will take approximately 1 g of your...
Would the methylene chloride layer be above or below the experiment? Justify your answer. 1. aqueous layer in today...
Would the methylene chloride layer be above or below the experiment? Justify your answer. 1. aqueous layer in today's ium carbonate used in the isolation of caffeine? Be specific as to the 2. Why is potass chemical species the carbonate may act on. Why was sodium sulfate used? 3. 4. After introducing 1.0 g of potassium carbonate into the centri hot water extract, it was capped, shaken, and then cooled to room temperature. Following this, roug minute. Why wasn't the...
please solve number 5 and 6 using the table. Part 1: Simple Extraction and Determination of the Distribution Coeffi...
please solve number 5 and 6 using the table.
Part 1: Simple Extraction and Determination of the Distribution Coefficient (Partition Coefficient) for Propionic Acid Between Ether and Water Table 1 (a) Preparation of Propionic Acid (PA) Solution weight PA Volume H2O (g) (e) Titration of Aqueous Propionic Solution After Ether Extraction (b) Titration of Aqueous Propionic Acid Solution Before Ether Extraction Volume PA. Volume NaOH Volume Volume PA Aliquot (mL) aliquot (mL) NaOH (mL) (mL) (mL) 17.30 mL50.00 mL 10-00...
1. Read about electrophilic aromatic substitutions reactions in general. You need to be familiar with the...
1. Read about electrophilic aromatic substitutions reactions in general. You need to be familiar with the mechanism. Louden text (if using) Chapter 16 sections 16.4 and 16.5. Ask your lecture professor which chapters this correlates to if you are using a different text. 2. Write the structure, hazards, and molecular weight for all the reactants and products. Table 1. Chemical Information for Reactants and Products. Compound MW (g/mol) Density (g/mL) Hazrads nitric acid 63.01 1.513 corrosive, oxidizer Sulfuric acid 98.075...
In need of help 1 – List four factors that affect the strength of an acid....
In need of help 1 – List four factors that affect the strength of an acid. All four may not apply to every acid. 2 – Calculate [OH-] for a 1.4 x 10-3 M HCl solution. 3 – Calculate the pH of an aqueous solution at 25 ̊C at is 0.34 M in phenol (Ka = 1.3 x 10-10) .4 – Calculate the concentration at which a monoprotic acid with Ka = 4.5 x 10-5 will be 2.5% ionized. (The...
1. The solubility of a gaseous solute in water is by an increase in pressure. Increased...
1. The solubility of a gaseous solute in water is by an increase in pressure. Increased decreased not affected 2. A supersaturated solution may be prepared by slowly cooling down a solution saturated at an elevated temperature. TRUE FALSE 3. A dilution is a solution made by adding a solvent to a supersaturated solution. TRUE FALSE 4. When sugar & water are mixed, a clear liquid results. In this scenario, the sugar is considered a Solute Solution Solvent All of...
A monoprotic acid, HA, with a Ka of 6.67 × 105 has a partition coefficient of 4.0 (favoring octanol) when distributed between water and octanol. Find the formal concentration of the acid in each phase when 100 mL of 0.100 M aqueous acid is extracted with 25 mL of octanol
Acid/Base Extraction
1. Provide a flow chart detailing the acid/base
extraction/separation of the compounds shown below. Your answer
must employ the following reagents: methylene chloride,
hydrochloric acid (1M & 6M), sodium hydroxide (1M & 6M),
10% sodium bicarbonate (aq). Clearly indicate the product(s) and
layers formed following each step of your separation scheme.
IMPORTANT: p-cresol is soluble in sodium hydroxide solution but
insoluble in neutral water or sodium bicarbonate solution. 2-
ethylbenzoic acid is soluble in both sodium hydroxide and...
Would the methylene chloride layer be above or below the experiment? Justify your answer. 1. aqueous layer in today's ium carbonate used in the isolation of caffeine? Be specific as to the 2. Why is potass chemical species the carbonate may act on. Why was sodium sulfate used? 3. 4. After introducing 1.0 g of potassium carbonate into the centri hot water extract, it was capped, shaken, and then cooled to room temperature. Following this, roug minute. Why wasn't the...
please solve number 5 and 6 using the table.
Part 1: Simple Extraction and Determination of the Distribution Coefficient (Partition Coefficient) for Propionic Acid Between Ether and Water Table 1 (a) Preparation of Propionic Acid (PA) Solution weight PA Volume H2O (g) (e) Titration of Aqueous Propionic Solution After Ether Extraction (b) Titration of Aqueous Propionic Acid Solution Before Ether Extraction Volume PA. Volume NaOH Volume Volume PA Aliquot (mL) aliquot (mL) NaOH (mL) (mL) (mL) 17.30 mL50.00 mL 10-00...
1. The solubility of a gaseous solute in water is by an increase in pressure. Increased decreased not affected 2. A supersaturated solution may be prepared by slowly cooling down a solution saturated at an elevated temperature. TRUE FALSE 3. A dilution is a solution made by adding a solvent to a supersaturated solution. TRUE FALSE 4. When sugar & water are mixed, a clear liquid results. In this scenario, the sugar is considered a Solute Solution Solvent All of...
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