B part is the resonance structure which explains ortho orientation for incoming electrophile
2 When an aromatic ring with an -OR group is halogenated, which of the following resonance...
(V) 10pts. When aniline (C6H3-NH2) reacts with bromonium ion (NO2. the nitro group can become bonded to a carbon at one of the three possible positions: ortho, meta, and para to the -NH2 group in the benzene ring. Consider meta and ortho attack and draw RESONANCE STRUCTURES for the carbocations that result when NO2 undergoes electrophilic aromatic substitution to aniline. Then, on the basis of these resonance structures, explain whether the --NH2, group.is meta director, or ortho/para director. Show which...
7. Using resonance structures show how the amino group would effect the electron density on the ring carbons of the following compound. Would you expect an electrophile to attack this molecule at the ortho, meta or para position(s)? 8. Draw the structure of (3R, 4R)-3-(3-fluorophenyl)-4-formylhexan-2-one ing resonance structures, show how the amino group would effect the electron density on the ring carbons of the following compound. Would you expect an electrophile to attack this molecule at the ortho, meta or...
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? Select one: -CIN 0 -NH₂ O NO₂ O-CO₂H
When there is an electron-withdrawing group on a benzene ring (eg. compounds such as nitrobenzenebenzoic acid, acetophenone, etc, resonance structures can be drawn that indicate the positions on the benzene ring that are least nucleophilic (because they have a positive charge on the carbon at that position). Because these positions are much less nucleophilic, the substitution reaction will not occur here; instead, substitution will occur at the other position(s) on the ring. As a result, which position(s) are most nucleophilic...
During electrophilic aromatic substitution, a resonance-stabilized cation intermediate is formed. Groups, already present on the benzene ring, that direct ortho/para further stabilize this intermediate by participating in the resonance delocalization of the positive charge. Assume that the following group is present on a benzene ring at position 1 and that you are brominating the ring at positon 4. In the box below draw the structure of the resonance contributor that shows this group actively participating in the charge delocalization. -OCH3...
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring ?deactivating اختر أحد الخيارات CI- CO2H- NO - O NH2- OH-
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, on last year's quiz), substituents on the aromatic ring can further modify the reactivity. First, we will consider a phenyl amide with a para-acetyl substituent: CH, (a) What is the n-effect (resonance) of the para-acetyl substituent? How will that affect the reactivity of the other (amide) carbonyl in the molecule below (increase or decrease, compared to the same amide but with no p-...
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? of Select one: O -NH2 O-SO3H O-1 0 -CN O-OCH3
4. Answer the following questions based on the electrophilic aromatic substitution reaction shown below. door a. (2.5pts) Based on the identity of the substituent on the starting material and its interaction with the aromatic ring, is this substituent an activator or deactivator? Briefly explain your answer and support your answer with structures b. (5.5pts) Draw all of the resonance contributors of the o-complexes that lead to each of the three possible products. c. (0.5p) Based on the structures drawn in...
Question 15 (2 points) Which of the following substituents will not direct the incoming group to the ortho/para position during electrophilic aromatic substitution? Oa) -CH2CH3 Ob) -OCOCH3 OC) -COOCH3 Od) -N(CH3)2 Question 16 (2 points) Which of the following compounds will undergo the fastest SN 1 reaction? Br Br Br Br IV a) 1 Ob) III OC) IV Od) 11