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Hint: Ta 4+ vs. Fe 2+
22.6 Hint: TaS2 crystallizes with a layer structure related to that of Cdl2, whereas FeS2 adopts a distorted NaCl structure.
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Answer #1

The type of crystal structure one material going to have will depend upon size of both anions and cations.

If the ions of two materials are similar, they are going to have similar crystal structure.

Here both have S2- as anion.

But have different cations.

One have Fe4+ and Ta4+. Their size are not equal. So they will never have similar crystal structure.

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