1.
SiF62-
Number of valence electrons (whole structure).
Si = 4
6F = 6×7 = 42
2 negative charge = 2
Total = (4+42+2) = 48.
Area of electron density around central atom
= 6.
Electron geometry is octahedral.
Bonding areas = 6
Nonbonding areas = 0.
Molecular geometry is octahedral
Bond angle 900
Si-F bond is polar.
But molecule is nonpolar due to symmetry in the molecule.
No pi bond is present.
2.
H2S
Number of valence electrons
S = 6
2H = 2
Total = (6+2) = 8.
Area of electron Electron density around central atom = 4
Electron geometry is tetrahedral
Bonding areas = 2
Nonbonding areas = 2
Molecular geometry is bent or angular.
Bond angle is 920 (less than idesl bond angle due to lone pair -bond pair repulsion).
S-H bond is polar.
Due to presence of two nonbonding electron pair and bent shape the molecule is polar.
No pi bond is present
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