Question

Chemical Formula: CgH 140 2.23 - 2.22 -2.22 1.10 -0.47 4.32 4.31 4.31 2.23 2.22 2.22 4.40 4.35 4.30 f1 (ppm) 4.25 2.30 2.25 2

100 95 90 - 86.23 85 8 0 -- 79.28 75 70 65 60 55 - 51.68 50 45 40 35 30 - 30.87 29.97 28.33 25 20 15 10

Both the above is for one question. please answer the following according to the above.

1. Assign signals of 13C and 1H spectra as well as find the structural unit and functional group.

2. Give the structure

sample answer - as follows

1H NMR: p-substituted Ar at 7.27-7.97 ppm, benzylic CH3 group at 2.42 ppm, COOH proton at 12.9 ppm

13C NMR: carbonyl C at 167.8 ppm (ester or acid), benzylic CH3 at 21.40 ppm, 4 remaining signals are Ar carbons, two of which are quaternary, typical of a p-substituted ring

and give a structure for the question.

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Answer #1

unselurahon Camlin Page Answer ① chemical Formula 8 HILO __ @ site of origarroahon . C8H18 - 18 HH H NMR 45 = 2 site of on 1

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