Homework Answers
The dipole moment for d6-d9 is found to be more than only spin
dipole moment value due to orbital contribution. Dipole moment for
d1-d5 is found to be almost same as only spin dipole moment. Hence
only (a) & (b) will have spin only dipole moment and (c) will
have a little orbital contribution. So (a) &(b) will have spin
only dipole moment.
Add Answer to:
20.30 For which of the following ions would you expect the spin-only formula to give reasonable...
what would you expect the spin-only magnetic susceptibility of [Fe(OH2)6]2+ to be? uld you expect the spin-only mag...
what would you expect the spin-only magnetic susceptibility of
[Fe(OH2)6]2+ to be?
uld you expect the spin-only magnetic susceptibility of [Fe(OH2)6]2+ to be? a) 5.9 B.M. b) 4.9 B.M. c) 3.9 B.M. d) 2.8 B.M. e) 1.7 B.M. 10. Which of the following statements coordination geometries is best? a) none of the below b) HS ds complexes are always octahedral as this arrangement gives them a large amount of CFSE cd3 complexes are always octahedral as this arrangement gives them...
Give the point group, LFSE, spin-only magnetic moment, Jahn-Teller activity (i.e. will the complex distort and...
Give the point group, LFSE, spin-only magnetic moment,
Jahn-Teller activity (i.e. will the complex distort and how), and
predicted stability for:
a. diaquasilver(I) (CN = 2, use Oh rules)
b. fac-[CoF3I3]3-
c. [Ru(ox)3]3-
d. Os(NH3)5 (CN = 5, use Oh
rules)
From the following list of metal ions and ligands, construct metal complexes with properties which match...
From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation. (Only one example is required for each part of the question, e.g. [Fe(H20)6]21). Metal ions Ligands (in order of increasing ligand field strength) [ < Br< <C1° <NO3 <OH <ox?- <H2O< Ti(IV), V(III), V(IV), Cr(II), Cr(III), Mn(II), NH3 <en <bpy < PPh3< CN=CO Mn(III), Mn(IV), Fe(II), Fe(III), Co(II), Co(III), en =...
Part A (2 marks) In the following pairs of complexes, which do you expect to have...
Part A (2 marks) In the following pairs of complexes, which do you expect to have a larger ligand field splitting parameter Ao? Why? Explain? i) [Fe(NH3)612+ or [Fe(NH3). 13+ ii) (Co(CN)613- or [Rh(CN)613- Part B (3 maks) In the following pairs of complexes, which do you expect to be more labile? Why? Explain? ) [Cr(NH3)613+ or [Mn(NH3)6]3+ ii) (Co(CN)613- or [Rh(CN)613- ii) [Cr(NH3).]3+ or [V(NH3).]2+
3 What spin only magnetic moment (uso) expected for each of the following complexes. (a) [MnBr.]...
3 What spin only magnetic moment (uso) expected for each of the following complexes. (a) [MnBr.] (C) [V(H2O)]2+ (b) [Ni(H20)]2+ (e) [CoBraj? (d) [FeC16] (f) Mo(CO)6
3 What spin only magnetic moment (uso) expected for each of the following complexes. (a) [MnBra]...
3 What spin only magnetic moment (uso) expected for each of the following complexes. (a) [MnBra] (d) [FeC16] 19 NICOW" (c) [V(H2O)]2+ (b) [Ni(H2O)]2+ (e) [CoBraj? TAROT (1) Mo(CO)6
With which of the following ions would you expect a color change after the addition of...
With which of the following ions would you expect a color change after the addition of acidified potassium permanaganate? Select all that apply. nitrite nitrate carbonate sulfite sulfate phosphate chromate
What type of bonding would you expect to find in the following compounds? Draw a reasonable struc...
What type of bonding would you expect to find in the following compounds? Draw a reasonable structure for each compound. Do NOT use abbreviations in your structures, i.e. show all the atoms and do not just write the functional groups. (a) (EtLi)4 (b) Pr'MgI.(OEt2)2 (c) B2Hs (e) (Et2HSİ)(Prn3Sİ)2Ge(Bu) (f) NaBu (g) GaMes (h) (3-Me-C6H4)2Sr.(tmeda)
What type of bonding would you expect to find in the following compounds? Draw a reasonable structure for each compound. Do NOT use abbreviations in your...
For which molecule in each of the following pairs would you expect hydrogen bonding, in a...
For which molecule in each of the following pairs would you expect hydrogen bonding, in a sample of the pure substance, to be more significant as a contributing factor to the attractive intermolecular interactions? a) (CH2OH)2 and CH3CH2OH (My answer: (CH2OH)2) b) CH3CHO and CH3CO2H (My answer: CH3CHO) c) H20 and NH3 (My answer: H20) d) NH3 and NH2OH (My answer: NH2OH) I've provided my original answers, which are incorrect and I'm confused as to why they're incorrect.
A37. Which one of the following coordination complexes would you expect to have the largest formation...
A37. Which one of the following coordination complexes would you expect to have the largest formation constant? (en is the bidentate ligand ethane-1,2- diamine, H2NCH2CH2NH2) 3+ (A) ICo(eno (B) ICo(en)o2 (C) [Co(NH3)6 (D) [Co(NH3)6l2+ (E) [Co(NH3)4] + 3+ Questions continue on next page
what would you expect the spin-only magnetic susceptibility of
[Fe(OH2)6]2+ to be?
uld you expect the spin-only magnetic susceptibility of [Fe(OH2)6]2+ to be? a) 5.9 B.M. b) 4.9 B.M. c) 3.9 B.M. d) 2.8 B.M. e) 1.7 B.M. 10. Which of the following statements coordination geometries is best? a) none of the below b) HS ds complexes are always octahedral as this arrangement gives them a large amount of CFSE cd3 complexes are always octahedral as this arrangement gives them...
Give the point group, LFSE, spin-only magnetic moment,
Jahn-Teller activity (i.e. will the complex distort and how), and
predicted stability for:
a. diaquasilver(I) (CN = 2, use Oh rules)
b. fac-[CoF3I3]3-
c. [Ru(ox)3]3-
d. Os(NH3)5 (CN = 5, use Oh
rules)
From the following list of metal ions and ligands, construct metal complexes with properties which match that described in each part of the question and provide a brief explanation. (Only one example is required for each part of the question, e.g. [Fe(H20)6]21). Metal ions Ligands (in order of increasing ligand field strength) [ < Br< <C1° <NO3 <OH <ox?- <H2O< Ti(IV), V(III), V(IV), Cr(II), Cr(III), Mn(II), NH3 <en <bpy < PPh3< CN=CO Mn(III), Mn(IV), Fe(II), Fe(III), Co(II), Co(III), en =...
Part A (2 marks) In the following pairs of complexes, which do you expect to have a larger ligand field splitting parameter Ao? Why? Explain? i) [Fe(NH3)612+ or [Fe(NH3). 13+ ii) (Co(CN)613- or [Rh(CN)613- Part B (3 maks) In the following pairs of complexes, which do you expect to be more labile? Why? Explain? ) [Cr(NH3)613+ or [Mn(NH3)6]3+ ii) (Co(CN)613- or [Rh(CN)613- ii) [Cr(NH3).]3+ or [V(NH3).]2+
3 What spin only magnetic moment (uso) expected for each of the following complexes. (a) [MnBr.] (C) [V(H2O)]2+ (b) [Ni(H20)]2+ (e) [CoBraj? (d) [FeC16] (f) Mo(CO)6
3 What spin only magnetic moment (uso) expected for each of the following complexes. (a) [MnBra] (d) [FeC16] 19 NICOW" (c) [V(H2O)]2+ (b) [Ni(H2O)]2+ (e) [CoBraj? TAROT (1) Mo(CO)6
What type of bonding would you expect to find in the following compounds? Draw a reasonable structure for each compound. Do NOT use abbreviations in your structures, i.e. show all the atoms and do not just write the functional groups. (a) (EtLi)4 (b) Pr'MgI.(OEt2)2 (c) B2Hs (e) (Et2HSİ)(Prn3Sİ)2Ge(Bu) (f) NaBu (g) GaMes (h) (3-Me-C6H4)2Sr.(tmeda)
What type of bonding would you expect to find in the following compounds? Draw a reasonable structure for each compound. Do NOT use abbreviations in your...
A37. Which one of the following coordination complexes would you expect to have the largest formation constant? (en is the bidentate ligand ethane-1,2- diamine, H2NCH2CH2NH2) 3+ (A) ICo(eno (B) ICo(en)o2 (C) [Co(NH3)6 (D) [Co(NH3)6l2+ (E) [Co(NH3)4] + 3+ Questions continue on next page
Most questions answered within 3 hours.
-
Based on the range, which of the following sets of scores has
the greatest variability? 3,...
asked 2 minutes ago -
The extent to which assets are financed by borrowed funds and
other liabilities is indicated by:...
asked 1 hour ago -
Explain in detail
Germany is the fifth largest economy
explain what goods and services Germany specializes...
asked 1 hour ago -
The density of platinum is 21.45 g/mL. If a cube of platinum
with a mass of...
asked 1 hour ago -
Accounts Receivable
Sales
A/R Posting
Extended Sales Invoice
Packing Slip
Compare invoice to packing slip 2...
asked 1 hour ago -
Michaella, age 23, is a full-time law student and is claimed by
her parents as a...
asked 1 hour ago -
Why are polymers not typically casted into products?
asked 1 hour ago -
When rolling a die 129 times, what is the probability of rolling
a 6 no more...
asked 1 hour ago -
4. A call option currently sells for $7.75. It has a strike
price of $85 and...
asked 1 hour ago -
1.
You need to prepare 10.0 liters of an acid aqueous solution with a
pH of...
asked 1 hour ago -
Along an aggregate supply curve, if the level of output is less
than the natural level...
asked 1 hour ago -
By 2025, annual consumption in emerging markets will total $30
trillion and contribute more than ________...
asked 1 hour ago