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CH2 1. (CH2CH2hCuli 2. H30* CH3 The coniugate addition of an alkyl group to an ß-unsaturated...
1. 2. JUST DRAW ARROWS... (CH3)2Culi + CH3Cu Ph CI Ph CH3 The ketone intermediate formed...
1.
2.
JUST DRAW ARROWS...
(CH3)2Culi + CH3Cu Ph CI Ph CH3 The ketone intermediate formed in the reaction of an acid chloride with a Grignard reagent cannot be isolated because it reacts too rapidly with the second equivalent of Grignard reagent. To produce a ketone from an acid chloride, one can treat the acid chloride with a lithium dialkylcopper reagent. The reaction occurs by nucleophilic acyl substitution on the acid chloride by the dialkylcopper anion to yield an acyl...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C +...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C + CO2 + E H3C CO2Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon In progress by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN 2 reaction with a primary...
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving tw...
Organic Chemistry 2
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving two molecules of the same aldehyde or ketone, in the presence of a base, and results in the formation of a new carbon-carbon bond joining the carbonyl carbon of one molecule to the a-position of the second. In many cases - if the reaction conditions aren't sufficiently mild - the initially formed aldol product reacts further in an elimination reaction to give what is...
Can you help me identify reagent (i), Compound 8 and Compound 12 in the reaction scheme?...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Can you help me determine if I am correct and help me find the ither answers...
Can
you help me determine if I am correct and help me find the ither
answers to this functional group lab worksheet?
18 w paper 1 we by addin trecome char Discussion of Properties and Test Ora general undergo dition reactions, whereas by substitution reactions. These two types of d e beds and womate compounds we characterized described in equation form as follows: action Addition Reaction Substitution Reaction (Note: numbers in boxes to the left refer to w in the...
____ 1. The diagram below represents serine, a polar, uncharged amino acid. Which functional group gives...
____ 1. The diagram below represents serine, a polar, uncharged
amino acid. Which functional group gives serine its
distinct property?
a. H3
b. CH2OH
c. –H
d. COO–
____ 2. The monomers shown below are monomers for which of the
following natural polymers?
a. polysaccharides
b. plastics
c. DNA
d. proteins
____ 3. Which of the following processes illustrates the production
of a protein?
a. specific code for amino acids --> amino acid chain -->
gene --> DNA --> specific...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23,...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
1.
2.
JUST DRAW ARROWS...
(CH3)2Culi + CH3Cu Ph CI Ph CH3 The ketone intermediate formed in the reaction of an acid chloride with a Grignard reagent cannot be isolated because it reacts too rapidly with the second equivalent of Grignard reagent. To produce a ketone from an acid chloride, one can treat the acid chloride with a lithium dialkylcopper reagent. The reaction occurs by nucleophilic acyl substitution on the acid chloride by the dialkylcopper anion to yield an acyl...
1. NaOEt CO2Et 2. H30+ 3. heat Br. Br CORET + H3C V CO2H H₂C + CO2 + E H3C CO2Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon In progress by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN 2 reaction with a primary...
Organic Chemistry 2
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving two molecules of the same aldehyde or ketone, in the presence of a base, and results in the formation of a new carbon-carbon bond joining the carbonyl carbon of one molecule to the a-position of the second. In many cases - if the reaction conditions aren't sufficiently mild - the initially formed aldol product reacts further in an elimination reaction to give what is...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Can
you help me determine if I am correct and help me find the ither
answers to this functional group lab worksheet?
18 w paper 1 we by addin trecome char Discussion of Properties and Test Ora general undergo dition reactions, whereas by substitution reactions. These two types of d e beds and womate compounds we characterized described in equation form as follows: action Addition Reaction Substitution Reaction (Note: numbers in boxes to the left refer to w in the...
____ 1. The diagram below represents serine, a polar, uncharged
amino acid. Which functional group gives serine its
distinct property?
a. H3
b. CH2OH
c. –H
d. COO–
____ 2. The monomers shown below are monomers for which of the
following natural polymers?
a. polysaccharides
b. plastics
c. DNA
d. proteins
____ 3. Which of the following processes illustrates the production
of a protein?
a. specific code for amino acids --> amino acid chain -->
gene --> DNA --> specific...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...
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