in the solvent-free synthesis of chalcones, Discuss the key aspects of the mechanism and why the equilibrium favors product.
in the solvent-free synthesis of chalcones, Discuss the key aspects of the mechanism and why the...
This is a Solvent-Free Synthesis of Chalcones: Claisen-Schmidt
Condensation
The Chalcone starting materials are:
p-bromoscetophenone (solid)
p-chlorobenzaldehyde (solid)
11. [3 points) Draw the curved-arrow mechanism for your chalcone from the starting materials that you used. Explain why this reaction produces only one chalcone and not a mixture.
This is a Solvent-Free Synthesis of Chalcones: Claisen-Schmidt
Condensation
The Chalcone starting materials are:
p-bromoscetophenone (solid)
p-chlorobenzaldehyde (solid)
6. [1pt] When you treated the reaction TLC with 2,4-dinitrophenylhydrazine solution, you must have observed that the starting materials show up as bright orange spots instantaneously, whereas the product either shows no change or appears as a faint spot. Explain this observation. 8. [1 pt] 4-chlorobenzaldehyde and 4-bromoacetophenone are both solid starting materials for the synthesis of substituted chalcone. When both of...
*Synthesis of Biodiesel
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1. The potassium methoxide solution used in this experiment was generated by reaction of KOH with methanol. Give the curved arrow mechanism for the reaction, then briefly explain why the equilibrium largely favors the potassium methoxide. KOH + CH3OH = K + OCH3 + H20
Why can 95% ethanol be used as a solvent in the synthesis of 2-butoxynaphthalene? I thought that for an Sn2 mechanism only aprotic solvents can be used for the synthesis?
7. [3 points] Discuss a) why is dimethylaniline chosen for this experiment (methyl orange synthesis) instead of aniline? (Keywords = Activating/Electron Donating Groups) NH b) Draw a potential by-product of using aniline in this reaction. (Hint = It occurs before the EAS mechanism). Describe it using few sentences.
there are fairness aspects on how e-commerce should be taxed.A discuss why states would pass a legislation to make one overall tax level important
Identify and briefly discuss each mechanism ensuring against simultaneous fatty acid synthesis and oxidation in the same cell. Match the words in the left column to the appropriate blanks in the sentences on the right. hydrolase acetyl-CoAs synthesis activates citrate pyruvate inhibits synthetase oxidation malonyl-CoA fatty acyl-CoAs carboxylase glucagon insulin A key intermediate in fatty acid synthesis,____, ______ carnitine acyltransferase I, thereby blocking the entry of fatty acyl units into the mitochondrion for oxidation. The substrates for fatty acid oxidation,...
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3. Why are alcohols or water an inappropriate solvent for dissolving sodium hydride or potassium amide? Write a detailed mechanism to justify your answer. 5. Starting with acetylene, should reagents that could be used to prepare each of the following: a. 1-butyne b. 2-butyne C. 3-hexyne d. 2-hexyne e. 2-heptyne f. 3-heptyne g. 2-octyne h. 2-pentyne i. 1-hexyne 6. Propose a synthesis for affording the transformation below. 7. Show how one could synthesize each of the following from...
QUESTION REVIEW Question 6 Status: Not yet answered I Points possible: 1.00 Aspirin synthesis involves the addition of an acetyl group to salicylic acid in a condensation reaction with an alcohol. The acety group could be added with a carboxylic acid but the preferred procedure is to use the acid anhydride. Why is preferable to use an acid anhydride for ester formation with an alcohol rather than a carboxylic acid? Select one: ОО Acid anhydrides are less stable than esters...
Multistep Synthesis: Synthesis of Amine (Organic Chemistry
Lab)
Question
1. Explain each step of reaction mechanism. (How does it
work?)
2. Discuss reason for reaction sequence. (Why must one reaction
occur before another?)
3. Explain how IR supports the major product.
Experiment Procedure
Imine Formation:
Weigh a 20 mL beaker and then add 380 mg of ortho-vanillin and
268 mg of para-toluidine. Care should be taken to add equivalent
molar amounts of the two reactants.
Observe the mixture and record...