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For aq. solutions of salt NH4NO2, following reactions possible: NH4+ + NO2- -> NH3 + HNO2...

For aq. solutions of salt NH4NO2, following reactions possible:

NH4+ + NO2- -> NH3 + HNO2 k1?

NH4+ + H2O -> H3O+ + NH3. ka = 5.6 x 10^-10

NO2- + H2O -> HNO2 + OH- kb =2.2 x 10^-11

2H2O -> H3O+ + OH- kw = 1.0 x10^-14

Write symbolic expression for equilibrium constants for each reaction. Derive expression for k1 in terms of ka, kb, and kw; find numerical value of k1.

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Answer #1

MHyt +NO2 - NH3 + HNO2 To get this equation, Na Hut + Hao ka, thot + NMz Nož + tho Ko, HHOO + at 2H20 kw Isot tot + 1 Nitlut

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