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please explain 1-5
1. Hydrocodone, the synthetic opiate in Vicodin contains stereocenters. 2. The following structures...
18. Assign the absolute configuration of the two stereocenters in stereoisomer of 2-bromo-3-pentanol shown below. Br...
18. Assign the absolute configuration of the two stereocenters in stereoisomer of 2-bromo-3-pentanol shown below. Br ОН a) 2R, 3R b) 2R, 3S c) 2S, 3R d) 2S, 3S 19. The following are 5 stereorepresentations of 1,5-dimercaptopentane-1,5-diol. Taking (1) as a reference structure. Determine if each of the other stereorepresentations are conformers to (1), enantiomers to (1) and diastereomers of (1). OH OH Enantiomer Diastereomer Conformer HS SH (2) он SH Enantiomer Diastereomer Conformer OH OH HS "ОН (3) ON...
g) Which structure is Z-2-bromo-3-methyl-2-pentene? CH3 H3C CH2CH3 H C=C CH-CH,CH, CH3 CH3 Вісн. C=C CH3...
g) Which structure is Z-2-bromo-3-methyl-2-pentene? CH3 H3C CH2CH3 H C=C CH-CH,CH, CH3 CH3 Вісн. C=C CH3 Br н Br | BÁ CHẠCH, C=C CH, CHỊCH, 10) Which compounds contain stereocenters? D) 1-chloropentane II) 2-chloropentane III) 3-chloropentane IV) 1,2-dichloropentane 11) Aspartame is an artificial, non-saccharide sweetener. It is made from two amino acids phenylalanine (methyl ester) and aspartic acid. Both aminoacids have one stercocenter. Both stereocenters have S-stereoconfiguration. Which of the two structures is aspartame? H2N-C-C-N-C-0-0 CH2 CH2 c=0 HO HO...
Which of the compounds shown below are chiral? (choose all correct) ОН o ОН E Which...
Which of the compounds shown below are chiral? (choose all correct) ОН o ОН E Which of the compounds shown below is/are chiral? (choose all correct answers) O For determining whether a stereogenic center is Ror S. the substituents need to be ranked. Rank the following substituents from high to low, entering a 1,2,3, or 4 next to each structure, with 1 for highest priority ranking and 4 for lowest priority ranking. 0-6 -C-H -CH_Br -CH₂OH -c-oh Which of the...
how does the structure on thr bottom left have 2 stereocenters? I see both Carbons in the CH3 being bonded directly...
how does the structure on thr bottom left have 2 stereocenters? I
see both Carbons in the CH3 being bonded directly to a H, -CH2 and
another -CH3. i do not see how there are 4 different groups that
each chiral carbon is attached to
os structures are show cand trans molecules srent sequence of groups ul (CH3) group and les initially, a-CH- ction gives, initially, a aded to four different 1,2-Disubstituted Cyclohexanes Now consider 1,2-dimethylcyclohexane. The cis and trans...
Please write neatly. 6. Below are seven spectra: 2 x 11-NMR. 3 x 1·1x C-NMR, and 1 x MS, m hat order. At the bottom of the page there are seven structures, Match each structure with a spectrum by...
Please write neatly.
6. Below are seven spectra: 2 x 11-NMR. 3 x 1·1x C-NMR, and 1 x MS, m hat order. At the bottom of the page there are seven structures, Match each structure with a spectrum by writing the letter for the structure in the box on the correct spectrum. Fach structure and spectrum should be used only once HC-CH2-C CH3 OH 6 NH2 CH
6. Below are seven spectra: 2 x 11-NMR. 3 x 1·1x C-NMR, and...
please solve all the questions 5. Label the chiral carbon(s) in each of the following structures...
please solve all the questions
5. Label the chiral carbon(s) in each of the following structures with an asterisk (*). H OHH OH H-C-C=C – H | H H OH 6. Use your knowledge of the Cahn-Ingold-Prelog sequence rules to rank the substituents in order of priority, highest priority first: HO HO The alcohol The chlorine The ethyl group The carboxylic acid group 7. Identify the following as chiral or achiral. If chiral, identify the chiral carbon(s) with an asterik...
+ion OAL, 5) Which of the following structures contains an alkene? A)1 B) II C) III...
+ion OAL, 5) Which of the following structures contains an alkene? A)1 B) II C) III D) IV 6) Which of the following is a secondary alcohol? OH HO B) II AT D) IV C) III 7) Rank the following compounds in order of increasing strength of intermolecular forces, putting the molecule with the weakest intermolecular force first OH A) I II B) I<IIIIIC III ) II<I<III ) IIIII< I D 8) Which of the following compounds has the highest...
Name the following compounds. Don't forget to specify stercochemistry when appropriate 2. Draw the structures of...
Name the following compounds. Don't forget to specify stercochemistry when appropriate 2. Draw the structures of cis-2-ethylhexa-1,4-diene E-2,4-dimethylhexa-1,4-diene 3. Assign E or Z configuration to the following alkenes. (Circle highest priority groups) Br сн Вr сH,сн,Br NH2CH CH2CHCH CH,OH NH2 CH2CH2Br NEC Which of the following compounds that can exist as a mixture of stereoisomers? Draw each b. 1-chloro-2-methylbut-2-ene 4. a. 1-chloropropene c. 1,1-dichloroethene 5. Calculate the degree of unsaturation for codeine, CisHaiNO,. Show your work. 6. Rank the following...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
2. Name the following alcoholis. ame: Cyclpentah Structure: Name: Structure: ОН CH, CH,CH,C- OH CH Name:...
2. Name the following alcoholis. ame: Cyclpentah Structure: Name: Structure: ОН CH, CH,CH,C- OH CH Name: Name: Structure: Structure: ОН Сн, он CH, -CH-CH2-CH, CH-CH, CH3 3. Write the product of the following oxidation reactions (if no reaction, write NR). CH, OH CH3-CH-CH, CH, CH-CH, +(0) — лон +(0) - Ketone CH, OH CH3 CH, CH, CH-CH-CH-CH, +(0) -OH + (0) 11-10 Experiment 11 Alcohols and Phenols Post-Lab Questions 1. Write the structures and classifications of the following alcohols: 2-bromo-3-pentanol...
18. Assign the absolute configuration of the two stereocenters in stereoisomer of 2-bromo-3-pentanol shown below. Br ОН a) 2R, 3R b) 2R, 3S c) 2S, 3R d) 2S, 3S 19. The following are 5 stereorepresentations of 1,5-dimercaptopentane-1,5-diol. Taking (1) as a reference structure. Determine if each of the other stereorepresentations are conformers to (1), enantiomers to (1) and diastereomers of (1). OH OH Enantiomer Diastereomer Conformer HS SH (2) он SH Enantiomer Diastereomer Conformer OH OH HS "ОН (3) ON...
g) Which structure is Z-2-bromo-3-methyl-2-pentene? CH3 H3C CH2CH3 H C=C CH-CH,CH, CH3 CH3 Вісн. C=C CH3 Br н Br | BÁ CHẠCH, C=C CH, CHỊCH, 10) Which compounds contain stereocenters? D) 1-chloropentane II) 2-chloropentane III) 3-chloropentane IV) 1,2-dichloropentane 11) Aspartame is an artificial, non-saccharide sweetener. It is made from two amino acids phenylalanine (methyl ester) and aspartic acid. Both aminoacids have one stercocenter. Both stereocenters have S-stereoconfiguration. Which of the two structures is aspartame? H2N-C-C-N-C-0-0 CH2 CH2 c=0 HO HO...
Which of the compounds shown below are chiral? (choose all correct) ОН o ОН E Which of the compounds shown below is/are chiral? (choose all correct answers) O For determining whether a stereogenic center is Ror S. the substituents need to be ranked. Rank the following substituents from high to low, entering a 1,2,3, or 4 next to each structure, with 1 for highest priority ranking and 4 for lowest priority ranking. 0-6 -C-H -CH_Br -CH₂OH -c-oh Which of the...
how does the structure on thr bottom left have 2 stereocenters? I
see both Carbons in the CH3 being bonded directly to a H, -CH2 and
another -CH3. i do not see how there are 4 different groups that
each chiral carbon is attached to
os structures are show cand trans molecules srent sequence of groups ul (CH3) group and les initially, a-CH- ction gives, initially, a aded to four different 1,2-Disubstituted Cyclohexanes Now consider 1,2-dimethylcyclohexane. The cis and trans...
Please write neatly.
6. Below are seven spectra: 2 x 11-NMR. 3 x 1·1x C-NMR, and 1 x MS, m hat order. At the bottom of the page there are seven structures, Match each structure with a spectrum by writing the letter for the structure in the box on the correct spectrum. Fach structure and spectrum should be used only once HC-CH2-C CH3 OH 6 NH2 CH
6. Below are seven spectra: 2 x 11-NMR. 3 x 1·1x C-NMR, and...
please solve all the questions
5. Label the chiral carbon(s) in each of the following structures with an asterisk (*). H OHH OH H-C-C=C – H | H H OH 6. Use your knowledge of the Cahn-Ingold-Prelog sequence rules to rank the substituents in order of priority, highest priority first: HO HO The alcohol The chlorine The ethyl group The carboxylic acid group 7. Identify the following as chiral or achiral. If chiral, identify the chiral carbon(s) with an asterik...
+ion OAL, 5) Which of the following structures contains an alkene? A)1 B) II C) III D) IV 6) Which of the following is a secondary alcohol? OH HO B) II AT D) IV C) III 7) Rank the following compounds in order of increasing strength of intermolecular forces, putting the molecule with the weakest intermolecular force first OH A) I II B) I<IIIIIC III ) II<I<III ) IIIII< I D 8) Which of the following compounds has the highest...
Name the following compounds. Don't forget to specify stercochemistry when appropriate 2. Draw the structures of cis-2-ethylhexa-1,4-diene E-2,4-dimethylhexa-1,4-diene 3. Assign E or Z configuration to the following alkenes. (Circle highest priority groups) Br сн Вr сH,сн,Br NH2CH CH2CHCH CH,OH NH2 CH2CH2Br NEC Which of the following compounds that can exist as a mixture of stereoisomers? Draw each b. 1-chloro-2-methylbut-2-ene 4. a. 1-chloropropene c. 1,1-dichloroethene 5. Calculate the degree of unsaturation for codeine, CisHaiNO,. Show your work. 6. Rank the following...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
2. Name the following alcoholis. ame: Cyclpentah Structure: Name: Structure: ОН CH, CH,CH,C- OH CH Name: Name: Structure: Structure: ОН Сн, он CH, -CH-CH2-CH, CH-CH, CH3 3. Write the product of the following oxidation reactions (if no reaction, write NR). CH, OH CH3-CH-CH, CH, CH-CH, +(0) — лон +(0) - Ketone CH, OH CH3 CH, CH, CH-CH-CH-CH, +(0) -OH + (0) 11-10 Experiment 11 Alcohols and Phenols Post-Lab Questions 1. Write the structures and classifications of the following alcohols: 2-bromo-3-pentanol...
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