Kp is the equilibrium constant in terms of partial pressure of the components. Kc is the equilibrium constant in terms of molar concentration of the components.
The relation between Kp and Kc is given by the relation -
where = (number of moles of gaseous products) - (number of moles of gaseous reactants)
R = universal gas constant = 0.0821 L atm K-1 mol-1
(this value of R is taken as the concentration is taken in mol L-1)
T = temperature of the system
Part B
All the components are gaseous.
= 2-(3+1) = -2
T = 298 K
Kp = 6.2 * 105
= 3.7 * 108(rounding off to 2 significant figure)
Part C
All the components are gaseous.
= 2-(1+1) = 0
T = 298 K
Kp = 4.10 * 10-31
= 4.10 * 10-31 (rounding off to 3 significant figure) [Since a0 = 1]
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Calculate Kp for the following (R = 0.08206 L.atm/mol.K): a) N2O4(g) ->2NO2(g) Kc = 5.9 x 10 -3 (at 298 K) b) N2(g) + O2(g) -> 2NO(g) Kc = 4.10 x 10 -31 (at 298 K)
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