U. Soo-school-bet.cn E. 4-bromo-1-chloro-2-nitrobenzene 10 Identify the aromatic compounds AI and II B. II and 111...
Question 47 (2 points) Which one of the following compounds is aromatic? S - II IV a) III Ob) Oc) II O d) IV Question 48 (2 points) Predict the product(s) for the following reaction: NaNH2, NH3 NH2 -NH₂ que "NH2 a) I, II and III b) I and II c) III and I d) II and III
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
52. Arrange the relative pKa's of the following compounds:( P (2 pts) соон соон COOH pKa's: 53. Arrange th compounds: (2 pts) e relative reaction rates for the electrophilic aromatic substitution of the following CH3 OCHa NO2 Reaction rates: 54. Arrange the relative base strength of the following compounds: (2 pts) NHCOCH3 NH2 NH2 NH2 NH. OCH3 OCH3 Basicity 55. What is the splitting pattern for the labeled hydrogens in the following compounds? (5 pt CH CH 56. Provide one...
aromatic reaction worksheet 2. b IV. fastest > slowest 3. Under each reaction, circle the correct operating mechanism 1) NaNH, NH. --Br 2) 1,0 EAS, SNAr, or Elimination-Addition b) FeBry HC- Br? EAS, SyAr, or Elimination-Addition 1) NaOH, 70°C ON- -Br 2)H,0 EAS, SyAr, or Elimination-Addition Topose a synthesis of each of the following compounds, from the given starting material and any other needed reagents. -OH from -CH2-CH3 c= CH2 from -CH2-CH2-CH, from
11) (50 pts total) Consider the following 2 compounds: Yor You I II (a) (6 pts) Provide the IUPAC names for compounds I and II. Compound I: Compound II: (b) (10 pts) Draw the resonance contributors of compounds I and II. Which compound is more stable? Explain in 20 words or less. (c) (6 pts) Which C-N bond below is shorter, A or B ? Explain in 20 words or less. (d) (6 pts) Draw the products obtained when compound...
3. Draw the structural formulas for the following compounds. (10 points, 2 each) a. 2-propanol b. 2-methyl-5-hexene-2-ol c. 3-cyclohexenol d. 4-nitrophenol e. phenol 4. Classify the following substituents as ortho/para or meta directing and activating or deactivating (two part answer for each group) (note the line 34 indicates where the group is attached to the benzene ring. (12points, 2 each) NH2 Ooh &r HC-CH₃ No? QH
final organic product of the following reaction? j. DIBAL-H, -18°C 2 ii. H3O+ OH с. НО L. OH OH OH d. e Ho ~ i NBS, ROOR -OH ii. Mglether A Com ill. CO2 iv. H+ a) O=C(CH₂ CGHS) 6) HCOOCH Cults C) CGHSCH₂COOH d) CCH CHCOOH Cottaoh H₂O, heat a conat +EtOH ... CO2 Nat + EtoH + ELOH + CO₂ Reactant is missing in the Гtation: following reactant PGO 10 reactant NON heat NINH NINHCH NA NCH), a...
11. Identify the product(s) of the following reaction. A. I B. II C. III D. IV E. V Gom Do is a From co be on) porno porno olyan 12. What is the final product obtained when toluene is subjected to the following reaction sequence? i) Clz (large excess), heat, hv; ii) OH-/H20, heat; iii) H30+ A. I OH B. II OH COH C. III U OH D. IV E. V I II Hol YCC, III HOCCI3 C/ стон с...
1.The main product of the reaction between p-cresol and Br2 / FeBr3 is: 3-Bromo-4-methyl phenol 2-Bromo-4-methyl phenol 2-methyl-4-bromine phenol 3-methyl-4-bromine phenol 2.Which of the following compounds is the least reactive in the nucleophilic substitution with NaOH? 2,4-dinitrochlorobenzene m-nitrochlorobenzene o-nitrochlorobenzene 3,5-dinitrochlorobenzene 3.What is the mechanism (s) for the reaction of 4-bromo-1-nitrobenzene with sodium hydroxide to form 4-nitrophenol? bimolecular nucleophilic substitution (Sn2) aromatic nucleophilic substitution by addition-elimination aromatic nucleophilic substitution by elimination-addition aromatic electrophilic substitution 4.which of the following is the correct...
Multiple choice questions I. Which ONE of the following compounds is an isolated diene? a) 4-methyl-13-heptadiene b) 5-methyl-2,6-heptadiene c) 2-methyl-2.4-heptadiene d) 5-methyl-2.3-heptadiene e) 13-cyclohexadiene 2. Which ONE of the following compounds will liberate the largest heat upon hydrogenation? 3. How many of the molecules below are aromatic? Identify and count. 4. How many electrons are participating in aromaticity? :N H a) 2 b) 4 c)6 d) 8 Which of the following sets of substituents are all activating groups in electrophilic...