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Practice Problemm that we've observed the qualitative relationships between AH, AS, and AG, let's calculate quantitative...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the following reaction, assuming that all gases have a pressure of 10.88 mm Hg. 2NO(g) + O2(g)—>2NO2(g) AG= kJ/mol Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) N2(g) 191.6 N(9) 472.7 455.6 153.3 NH3(9) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO(9) 90.3 86.6 210.8 NOCI(g) 51.7 66.1 261.8 NO2(9) 33.2 240.1 51.3 104.2 N2O(9) 82.1 219.9 N204(9) 9.2 97.9...
9) Using the information given calculate, AH, AS and AG at 25°C (remember, for a reaction...
9) Using the information given calculate, AH, AS and AG at 25°C (remember, for a reaction calculated using the relationship: AH = AH° reaction = nАHºf(products) - EnАHºt(reactants). PAY ATTENTION TO UNITS AND SIGN PC13(g) + Cl2 (g) → PCls(g) AHºt(kJ/mol) -287 O -374.9 (why is AHºt = 0 for Cl2?) Sºt (J/K) 311.67 223.1 364.47
please show work and maybe explanations ? Practice Problem 1 Calculate AH and AS for the...
please show work and maybe explanations ?
Practice Problem 1 Calculate AH and AS for the following reaction (the Haber process for the manufacture of ammonia) and calculate if the reaction is favorable at STP. N2(g) + 3 H2(g) 2 NH3(g) (The following information may also be obtained from Appendix C in the Jespersen text.) Compound Enthalpy (kJ/mol) Entropy (J/mol-K) N2(9) H2(g) NH3(g) 0 191.61 130.68 192.45 -46.11 Practice Problem 2 Use the values of AH and AS calculated in...
Nitrogen Ahºf (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) 191.6 N2(9) 0 0 N(g) 472.7 455.6 153.3 NH3(g) -46.1 -16.5 192.5 NH3(a...
Nitrogen Ahºf (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) 191.6 N2(9) 0 0 N(g) 472.7 455.6 153.3 NH3(g) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 90.3 86.6 210.8 NO(9) NOCI(g) 51.7 66.1 261.8 NO2(g) 33.2 51.3 240.1 N20(9) 82.1 104.2 219.9 N204(9) 9.2 97.9 304.3 N204(0) -20.0 97.0 209.0 N205(s) -42.0 134.0 178.0 N2H4(0) 50.6 149.3 121.2 N2H3CH3 () 54.0 180.0 166.0 HNO3(aq) -207.4 -111.3 146.4 HNO3(1) -174.1 -80.7 155.6 HNO3(9) -135.1 -74.7 266.4 NH4ClO4(s) -295.0...
In the Check Your Learning section how did they get that value of K? Calculating an...
In the Check Your Learning section how did they get that value
of K?
Calculating an Equilibrium Constant using Standard Free Energy Change Given that the standard free energies of formation of Ag'(aq), CI (aq), and AgCl(s) are 77.1 kJ/mol, -131.2 kJ/mol, and -109.8 kJ/mol, respectively, calculate the solubility product, Ksp, for AgCl. Solution The reaction of interest is the following: Ag (aq) +CI (aq) Ksp [Ag ICI] AgCl(s) The standard free energy change for this reaction is first computed...
ΔΗ, (at 298K AG; (at 298 K in kJ/mol) Compound Compound AH (at 298K in kJ/mol in kJ/mol) AG (at 298 K. in kJ/mol...
ΔΗ, (at 298K AG; (at 298 K in kJ/mol) Compound Compound AH (at 298K in kJ/mol in kJ/mol) AG (at 298 K. in kJ/mol 0 0 210.5 70.18 Ho (g) Hg (1) Hg,CI, (s) Ag (s) Agor(s AgCl(s) 0 265.37 106.76 -96.90 -109.80 0 -628.8 - 1582.3 -100.37 -127.01 0 -704 2 -1675.7 0 1 (g) AICI, (s) Al O (5) Ar (9) Au (s) BaSO's) 0 K(s) KBr(s) KCI (s) 0 -393.8 436.5 -567.3 -327.9 0 -1362.3 380.7 -408.5...
Using enthalpies of formation (Appendix C), calculate ΔH ° for the following reaction at 25°C. Also...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C....
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
#6-9 6. Calculate the enthalpy change for the reaction given below, using thermodynamic tables in your...
#6-9
6. Calculate the enthalpy change for the reaction given below, using thermodynamic tables in your book (Appendix 2): CH(g)+02(B) HO(g) + CO,(g) (not balanced) 7. Calcium carbonate decomposes at high temperature to form carbon dioxide and calcium oxide: CaCO3 CO2+ CaO Using data from the textbook (Apendix 2), determine the heat of reaction. 8. When potassium chloride reacts with oxygen under the right conditions, potassium chlorate is formed: 2 KCI+3 02 2KCIO3 Using data from the textbook (Appendix 2),...
Use standard thermodynamic data (in the Chemistry References) to calculate AG at 298.15 K for the following reaction, assuming that all gases have a pressure of 10.88 mm Hg. 2NO(g) + O2(g)—>2NO2(g) AG= kJ/mol Nitrogen AHºf (kJ/mol) AG°f (kJ/mol) sº (J/mol K) N2(g) 191.6 N(9) 472.7 455.6 153.3 NH3(9) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 NO(9) 90.3 86.6 210.8 NOCI(g) 51.7 66.1 261.8 NO2(9) 33.2 240.1 51.3 104.2 N2O(9) 82.1 219.9 N204(9) 9.2 97.9...
9) Using the information given calculate, AH, AS and AG at 25°C (remember, for a reaction calculated using the relationship: AH = AH° reaction = nАHºf(products) - EnАHºt(reactants). PAY ATTENTION TO UNITS AND SIGN PC13(g) + Cl2 (g) → PCls(g) AHºt(kJ/mol) -287 O -374.9 (why is AHºt = 0 for Cl2?) Sºt (J/K) 311.67 223.1 364.47
please show work and maybe explanations ?
Practice Problem 1 Calculate AH and AS for the following reaction (the Haber process for the manufacture of ammonia) and calculate if the reaction is favorable at STP. N2(g) + 3 H2(g) 2 NH3(g) (The following information may also be obtained from Appendix C in the Jespersen text.) Compound Enthalpy (kJ/mol) Entropy (J/mol-K) N2(9) H2(g) NH3(g) 0 191.61 130.68 192.45 -46.11 Practice Problem 2 Use the values of AH and AS calculated in...
Nitrogen Ahºf (kJ/mol) AG°f (kJ/mol) Sº (J/mol K) 191.6 N2(9) 0 0 N(g) 472.7 455.6 153.3 NH3(g) -46.1 -16.5 192.5 NH3(aq) -80.0 -27.0 111.0 NH4+ (aq) -132.0 -79.0 113.0 90.3 86.6 210.8 NO(9) NOCI(g) 51.7 66.1 261.8 NO2(g) 33.2 51.3 240.1 N20(9) 82.1 104.2 219.9 N204(9) 9.2 97.9 304.3 N204(0) -20.0 97.0 209.0 N205(s) -42.0 134.0 178.0 N2H4(0) 50.6 149.3 121.2 N2H3CH3 () 54.0 180.0 166.0 HNO3(aq) -207.4 -111.3 146.4 HNO3(1) -174.1 -80.7 155.6 HNO3(9) -135.1 -74.7 266.4 NH4ClO4(s) -295.0...
In the Check Your Learning section how did they get that value
of K?
Calculating an Equilibrium Constant using Standard Free Energy Change Given that the standard free energies of formation of Ag'(aq), CI (aq), and AgCl(s) are 77.1 kJ/mol, -131.2 kJ/mol, and -109.8 kJ/mol, respectively, calculate the solubility product, Ksp, for AgCl. Solution The reaction of interest is the following: Ag (aq) +CI (aq) Ksp [Ag ICI] AgCl(s) The standard free energy change for this reaction is first computed...
ΔΗ, (at 298K AG; (at 298 K in kJ/mol) Compound Compound AH (at 298K in kJ/mol in kJ/mol) AG (at 298 K. in kJ/mol 0 0 210.5 70.18 Ho (g) Hg (1) Hg,CI, (s) Ag (s) Agor(s AgCl(s) 0 265.37 106.76 -96.90 -109.80 0 -628.8 - 1582.3 -100.37 -127.01 0 -704 2 -1675.7 0 1 (g) AICI, (s) Al O (5) Ar (9) Au (s) BaSO's) 0 K(s) KBr(s) KCI (s) 0 -393.8 436.5 -567.3 -327.9 0 -1362.3 380.7 -408.5...
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
#6-9
6. Calculate the enthalpy change for the reaction given below, using thermodynamic tables in your book (Appendix 2): CH(g)+02(B) HO(g) + CO,(g) (not balanced) 7. Calcium carbonate decomposes at high temperature to form carbon dioxide and calcium oxide: CaCO3 CO2+ CaO Using data from the textbook (Apendix 2), determine the heat of reaction. 8. When potassium chloride reacts with oxygen under the right conditions, potassium chlorate is formed: 2 KCI+3 02 2KCIO3 Using data from the textbook (Appendix 2),...
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