question 7 9 10 ), where n, a, and are constant, is an eigenfunction of p....
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
Particle in a box Figure 1 is an illustration of the concept of a particle in a box. V=00 V=00 V=0 Figure 1. A representation of a particle in a box, where the potential energy, V, is zero between x = 0 and x = L and rises abruptly to infinity at the walls. The Schrödinger equation for a particle in a box reads t² d²u Y +V(x)y = Ey 2m dx2 + (1) where ħ=h/21 , y represents the...
Could you please answer this question by clear handwriting UESTION 2 A particle of mass m moves in a one- dimensional box of length Lwith boundaries at x-0 and x - L. Thus, V(x) - 0 for 0 x L and V(x) elsewhere. The normalized eigenfunctions of the Hamiltonian for the system are given by 1/2 -| sin 1-_- , with -, where the quantum number 2ml2 n can take on the values n -1, 2, 3, (i). Assuming that...
A particle of mass m is bound by the spherically-symmetric three-dimensional harmonic- oscillator potential energy , and ф are the usual spherical coordinates. (a) In the form given above, why is it clear that the potential energy function V) is (b) For this problem, it will be more convenient to express this spherically-symmetric where r , spherically symmetric? A brief answer is sufficient. potential energy in Cartesian coordinates x, y, and z as physically the same potential energy as the...
please help 1. The eigenfunctions of a particle in a square two-dimensional box with side lengths a = b = L are non, (x, y) = { sin ("T") sin (9,7%) = xn, (x)}n, (y) where n. (c) and on, (y) are one-dimensional particle-in-a-box wave functions in the x and y directions. a. Suppose we prepare the particle in such a way that it has a wave function V (2,y) given by 26,0) = Võru (s. 1) + Vedra ....
Please answer number 8 l Verizon LTE 9:53 PM 100%,--+ Close Physical Chemistry ll Spring...1 DOCX-149 KB (e) none of the above 7. A free particle is inside a one dimentional box from 0 to a/2, (a is a constant). If the particle is in the first excited states with eigenfunction, y Nsin (4px/a) (a) Determine the normalization constant. (b) Calculate the probability in between a/4 and a/2 8. What is the degree of the degeneracy if the three quantum...
Incorrect Question 9 0/1 pts The state % = to 4-1 + tzv. + tag 42 is a linear combination of three orthonormal eigenstates of the operator Ô corresponding to eigenvalues - 1, 1, and 2. What is the expectation value for Ô for this state? V o 13+2821 Which of the following is true of observable in quantum mechanics? I. They are represented by Hermitian operators. II. Multiple observables can never be simultaneously measured. III. The operators representing observables...
1) (35 points) The wave function for a particle moving along x axis between the limits 0 and L is: (x)-C sin (nx xL) where n are 1, 2, 3, A) Determine the normalization constant C B) Why can't n take the value of 0, briefly explain C) For n-3 determine the values of x (in terms of L) that correspond to a maximum or a minimum in the wave function D) For n-3 determine the values of x (in...
Question #9 all parts thanks 9. The wavefunction, p(x,t), of a particle moving along the x-axis, whose potential energy V(x) is independent of time, is described by the one-dimensional non-relativistic Schrödinger equation (where m is its mass, h is the reduced Planck constant, i is the imaginary number): 2m (a) Verify that it is a parabolic equation (page E-1-2). [It has wave-like solutions, however.] (b) Use the substitution Px,t)-Xx)Tt) to separate the equation into two ODEs. (c) Solve for T,...
Recall that an energy eigenfunction of any central potential V (r) may be writtren as ψn`m(r, θ, φ) = Rn`(r)Y`m(θ, φ). This problem explores the behavior of ψ in the vicinity of the origin r = 0. Recall that the function u(r) = rRn`(r) satisfies the equation − ~ 2 2m d 2u dr2 + ~ 2 `(` + 1) 2mr2 + V (r) u = Eu, (1) where E is the energy eigenvalue. Note that Eq. (1) has the...