6. UV lambda-max
A. Homoannular diene = 253 nm
extended conjugation = 30
alkyl substituent = 3 x 5 = 15
lambda-max = 253 + 30 + 15 = 298 nm
B. heteroannular diene = 214 nm
extended conjugation = 30
exocyclic double bond = 5 nm
alkyl substituent = 4 x 5 = 20
lambda-max = 214 + 30 + 5 + 20 = 269 nm
C. homoannular diene = 253 nm
alkyl substiuent = 4 x 5 = 20 nm
lambda-max = 253 + 20 = 273 nm
D. alpha,beta-unsaturated ketone = 214 nm
homodiene = 39 nm
exocyclic double bond = 5 nm
ring substiuent at beta = 12 nm
ring substiuent at other = 18 nm
double bond extending conjugation = 30 nm
lambda-max = 214 + 5 + 39 + 12 + 18 + 30 = 318 nm
E. alpha,beta-unsaturated ketone = 214 nm
double bond extending conjugation = 30 nm
exocyclic double bond = 5 nm
ring substiuent at beta = 12 nm
ring substiuent at other = 2 x 18 = 36 nm
lambda-max = 214 + 30 + 12 + 36 = 292 nm
F. alpha,beta-unsaturated ketone = 214 nm
homodiene = 39 nm
ring consituent at alpha = 10 nm
ring substiuent at beta = 12 nm
ring substiuent at other = 2 x 18 = 36 nm
double bond extending conjugation = 30 nm
lambda-max = 214 + 39 + 10 + 12 + 36 + 30 = 341 nm
G. Heteroannular diene = 214 nm
OR in alpha position = 35 nm
NHR substiuent = 95 nm
extended consjugation = 30 nm
exocyclic double bond = 5 nm
alkyl substituent at beta = 12 nm
alkyl substiuent at others = 2 x 18 = 36 nm
lambda-max = 214 + 35 + 95 + 30 + 5 + 12 + 36 = 427 nm
H. 5-membered alpha,beta-unsaturated ketone = 202 nm
alkyl substiuent at beta position = 2 x 12 = 24 nm
lambda-max = 202 + 24 = 226 nm
I. alpha,beta-unsaturated ketone = 214 nm
extended conjugation = 30 nm
homodiene = 39 nm
O at alpha-position = 35 nm
lambda-max = 214 + 30 + 39 + 35 = 318 nm
6. UV: Determine the max for each of the following structures. Show your work. D. 2max...