(a) Calculate the free energies of micellisation at each temperature, ΔG°micelle, the enthalpy of micellisation, ΔH°micelle, and the entropy of micellisation, ΔS°micelle, from the data given below.
CMC at 25°C (10–3 M) CMC at 40°C (10–3 M)
1.04 4.46
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(a) Calculate the free energies of micellisation at each temperature, ΔG°micelle, the enthalpy of micellisation, ΔH°micelle,...
Use standard free energies of formation to calculate ΔG∘ at 25∘C for each of the following reactions. How do the values of ΔG∘ calculated this way compare to those calculated from ΔH∘ and ΔS∘? Which of the two methods could be used to determine how ΔG∘ changes with temperature? Essay answers are limited to about 500 words (3800 characters maximum, including spaces).
If the reaction A + 2B ⇌ 2C has a change in enthalpy of ΔH=-8.71kJ/mol and a change in entropy of ΔS= -5.88J/mol*K and the reaction of B + D ⇌ C has a change in enthalpy of ΔH=-3.45kJ/mol and a change in entropy of ΔS= 11J/mol*K, is the reaction of A ⇌ 2D spontaneous at room temperature? Yes, ΔG > 0 Yes, ΔG < 0 No, ΔG > 0 No, ΔG < 0
Calculate the changes in free energy, enthalpy, and entropy when 1.00 mol Ar(g) at 27°C is compressed isothermally from 100.0 L to 15.0 L. ΔH = _____kJ ΔS = _____J/K ΔG = _____kJ
answer #63 by using #61 63) Use standard free energies of formation to calculate ΔG° at 25°C for each reaction in Problem 61. How do the values of AG° calcu- lated this way compare to those calculated from ΔΗ' and AS? Which of the two methods could be used to determine how ΔG changes with temperature? İN or each reaction, calculate Δ Hon, Δ-mn, and ΔGon at 25°C and state whether the reaction is spontaneous. If the reaction is not...
For reactions carried out under standard-state conditions, the equation ΔG = ΔH − TΔS becomes ΔG° = H° − TΔS°. Assuming ΔH° and ΔS° are independent of temperature, one can derive the equation: ln( K2 K1 ) = ΔH° R ( T2 − T1 T1T2 ) where K1 and K2 are the equilibrium constants at T1 and T2, respectively. Given that at 25.0°C, Kc is 4.63×10−3 for the reaction N2O4(g) longrightleftarrow 2NO2(g) ΔH° = 58.0 kJ/mol calculate the equilibrium constant...
Use the data in Appendix B in the textbook to calculate ΔH∘ and ΔS∘ for each of the following reactions. From the values of ΔH∘ and ΔS∘, calculate ΔG∘ at 25 ∘C and predict whether each reaction is spontaneous under standard-state conditions. Part A 2SO2(g)+O2(g)→2SO3(g) Express your answer using four significant figures. ΔH∘ = kJ Part B Express your answer using four significant figures. ΔS∘ = J/K Part C Express your answer using four significant figures. ΔG∘ = kJ Part...
For each of the following reactions, calculate ΔH∘rxn, ΔS∘rxn, and ΔG∘rxn at 25 ∘C.? 2CH4(g)→C2H6(g)+H2(g) Part B: Calculate ΔS∘rxn at 25 ∘C 2NH3(g)→N2H4(g)+H2(g) Part B: Calculate ΔS∘rxn at 25 ∘C.
Chemical energy is released or absorbed from reactions in various forms. The most easily measurable form of energy comes in the form of heat, or enthalpy. The enthalpy of a reaction can be calculated from the heats of formation of the substances involved in the reaction: ΔH∘rxn=ΔH∘f(products)−ΔH∘f(reactants) Entropy change, ΔS∘, is a measure of the number of energetically equivalent microstates introduced into the system during the reaction. The degree of spontaneity of a reaction is represented by the Gibbs free...
Chemical energy is released or absorbed from reactions in various forms. The most easily measurable form of energy comes in the form of heat, or enthalpy. The enthalpy of a reaction can be calculated from the heats of formation of the substances involved in the reaction: ΔH∘rxn=ΔH∘f(products)−ΔH∘f(reactants) Entropy change, ΔS∘, is a measure of the number of energetically equivalent microstates introduced into the system during the reaction. The degree of spontaneity of a reaction is represented by the Gibbs free...
For the values give for ΔH and ΔS, calculate ΔG foreach for each of the following reactions at 298 K. If the reactionis not spontaneous under standard conditions at 298 K, at whattemperature (if any) would the reaction become spontaneous? a) 2PbS(s)+3O2(g) ---> 2PbO(s)+2SO2(g) ΔH= -844kj ; ΔS = -165 J/K b)2POCl3(g)--->2PCl3(g)+O2(g) ΔH= 572kJ ; ΔS= 179 J/K