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![The for the reaction is, rate equation r = K[NO] ² [co] Rate Constant, k= 2.088104 L moltst. Initial concentration, [Ao) a 0.](http://img.homeworklib.com/questions/0c477c80-055a-11ec-ae2c-cb55f1767366.png?x-oss-process=image/resize,w_560)
hTime required in two
significant figures is given by, t=5.6
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Nitrogen dioxide reacts with carbon monoxide to produce nitric oxide as follows: NO2 (9) + CO...
carbon monoxide reacts with nitrogen dioxide to produce carbon dioxide and nitric oxide as given by...
carbon monoxide reacts with nitrogen dioxide to produce carbon dioxide and nitric oxide as given by the following reaction. CO (g) + NO2 (g) → CO2 (g) + NO (g) The reaction is zeroth order in CO and second order in NO2, and second order overall. The rate constant for this reaction at 175ºC is 7.58 × 10-4 L mol-1 s-1. If the initial concentration of NO2 was 0.565 M, what is the molar concentration of NO2 after 5.8 minutes?...
The gas phase reaction of nitric oxide, NO, with bromine, Br2, to produce nitrosyl bromide, NOBr,...
The gas phase reaction of nitric oxide, NO, with bromine, Br2,
to produce nitrosyl bromide, NOBr,
occurs according to the net reaction: A possible reaction
mechanism is:
?1
Step 1: 2 NO ⇌ N2O2
?−1
Step 2: N2O2 + Br2
2NO+Br2 → 2NOBr
2 NOBr
Neither step is faster than the other. What is the order of the
overall reaction, and what is the overall rate constant (expressed
in terms of the individual rate constants for the elementary
steps)?
9....
Nitrogen dioxide, NO2 decomposes into nitrogen monoxide (NO)
Nitrogen dioxide, NO2 decomposes into nitrogen monoxide (NO) and oxygen gas O2, according to the following reaction. 2 NO2(g) → 2NO(g) + O2(g) A sample of nitrogen dioxide in a sealed vessel, and the total pressure in the vessel was measured to be 0.0980 atm before any reaction had occurred. The total pressure in the vessel was monitored over time during the reaction at 575 K, giving the following data. (a) (20 points) Determine the rate law (in pressure) for this reaction at 575...
QUESTION 1 (10) Nitric oxide reacts with oxygen to form nitrogen dioxide: 2NO(g) + O2(g) +...
QUESTION 1 (10) Nitric oxide reacts with oxygen to form nitrogen dioxide: 2NO(g) + O2(g) + 2NO2 (g) a) What is the Kc for the reaction if the equilibrium concentration of NO is 0.300 M, O2 is 0.200 M, and NO2 is 0.530 M at 25°C? b) What is the Kp for the same reaction? c) If the equilibrium re-establishes where [NO]=0.150 M and [02]-0.225 M, what is [NO2) at this point under the same temperature? 2(12) The equilibrium constant...
10 and 11 10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows...
10 and 11
10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows second order kinetics with a rate constant of 0.020 L mol-' s at a certain temperature. 2 NOCI (g) → 2 NO(g) + Cl2(g) If the initial concentration of NOCI in a closed reaction vessel is 0.050 M, what will be the concentration be after 30 minutes? 11. The reaction 2 NO2 (g) → 2 NO(g) + O2(g), is second order with respect to...
9,10,11 9. Consider the decomposition reaction of N2Os. 2 N203(g) → 4NO2(g) + O2(g) follows the...
9,10,11
9. Consider the decomposition reaction of N2Os. 2 N203(g) → 4NO2(g) + O2(g) follows the first order kinetics with rate constant of 4.8 x 10's. (a) if the initial 165 x 10-2M what is the concentration at 825 s? (b) How long it will take for concentration is 1.65 x 10-2M what is the concentrat the concentration of N2Os to decrease to 1.00 x 10-2M? t 10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows...
9. Nitrogen dioxide (NO2) can react with water to form aqueous nitric acid according to the...
9. Nitrogen dioxide (NO2) can react with water to form aqueous nitric acid according to the following reaction. This is one way that acid rain forms in the atmosphere. Also listed are the standard free energies of formation for the species involved in the reaction. 3NO2(g) + H2O(l) → 2HNO3(aq) + NO(g) Compound AG, (kJ/mol) NO2(g) 51.3 H2O(0) -237.1 HNO3(aq) -110.9 NO(g) 87.6 a. Calculate AGºrx (6 points) b. Is the reaction spontaneous at standard conditions? Circle one and explain...
Nitrosyl bromide decomposes by the reaction 2 NOBO(g) + 2NO(9) + Brz(9). Show that the following...
Nitrosyl bromide decomposes by the reaction 2 NOBO(g) + 2NO(9) + Brz(9). Show that the following data are consistent with a second-order reaction and determine the second-order rate constant for the reaction. Students may do this by plotting the data three different ways. For each plot, time goes on the x-axis. A zero-order reaction is linear when [NOBr] on the y-axis. A first-order reaction is linear when In[NOBr) is on the y-axis. A second-order reaction is linear when 1/[NOBr) is...
The decomposition of nitrogen dioxide occurs according to the equation below: NO2 (g)------>NO( g)+1/2 O2 (g)...
The decomposition of nitrogen dioxide occurs according to the equation below: NO2 (g)------>NO( g)+1/2 O2 (g) The reaction is second order with respect to NO2. The specific rate constant for this reaction is 3.04M-1min-1. How long does it take for the concentration of NO2 to decrease from 2.00M to 1.25M?
Use the References to access important values if needed for this question. NO2 reacts with F2...
Use the References to access important values if needed for this question. NO2 reacts with F2 in the gas phase according to the following chemical equation: 2NO2(g)F2(g) 2NO Fg) It is observed that, when the concentration of F2 is reduced to 1/3 o its initial value, the rate of the reaction is also reduced to 1/3 of its nitial value. When the concentration of NO2 is multiplied by 4.48, the rate of the reaction also increases by a factor of...
The gas phase reaction of nitric oxide, NO, with bromine, Br2,
to produce nitrosyl bromide, NOBr,
occurs according to the net reaction: A possible reaction
mechanism is:
?1
Step 1: 2 NO ⇌ N2O2
?−1
Step 2: N2O2 + Br2
2NO+Br2 → 2NOBr
2 NOBr
Neither step is faster than the other. What is the order of the
overall reaction, and what is the overall rate constant (expressed
in terms of the individual rate constants for the elementary
steps)?
9....
QUESTION 1 (10) Nitric oxide reacts with oxygen to form nitrogen dioxide: 2NO(g) + O2(g) + 2NO2 (g) a) What is the Kc for the reaction if the equilibrium concentration of NO is 0.300 M, O2 is 0.200 M, and NO2 is 0.530 M at 25°C? b) What is the Kp for the same reaction? c) If the equilibrium re-establishes where [NO]=0.150 M and [02]-0.225 M, what is [NO2) at this point under the same temperature? 2(12) The equilibrium constant...
10 and 11
10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows second order kinetics with a rate constant of 0.020 L mol-' s at a certain temperature. 2 NOCI (g) → 2 NO(g) + Cl2(g) If the initial concentration of NOCI in a closed reaction vessel is 0.050 M, what will be the concentration be after 30 minutes? 11. The reaction 2 NO2 (g) → 2 NO(g) + O2(g), is second order with respect to...
9,10,11
9. Consider the decomposition reaction of N2Os. 2 N203(g) → 4NO2(g) + O2(g) follows the first order kinetics with rate constant of 4.8 x 10's. (a) if the initial 165 x 10-2M what is the concentration at 825 s? (b) How long it will take for concentration is 1.65 x 10-2M what is the concentrat the concentration of N2Os to decrease to 1.00 x 10-2M? t 10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows...
9. Nitrogen dioxide (NO2) can react with water to form aqueous nitric acid according to the following reaction. This is one way that acid rain forms in the atmosphere. Also listed are the standard free energies of formation for the species involved in the reaction. 3NO2(g) + H2O(l) → 2HNO3(aq) + NO(g) Compound AG, (kJ/mol) NO2(g) 51.3 H2O(0) -237.1 HNO3(aq) -110.9 NO(g) 87.6 a. Calculate AGºrx (6 points) b. Is the reaction spontaneous at standard conditions? Circle one and explain...
Nitrosyl bromide decomposes by the reaction 2 NOBO(g) + 2NO(9) + Brz(9). Show that the following data are consistent with a second-order reaction and determine the second-order rate constant for the reaction. Students may do this by plotting the data three different ways. For each plot, time goes on the x-axis. A zero-order reaction is linear when [NOBr] on the y-axis. A first-order reaction is linear when In[NOBr) is on the y-axis. A second-order reaction is linear when 1/[NOBr) is...
Use the References to access important values if needed for this question. NO2 reacts with F2 in the gas phase according to the following chemical equation: 2NO2(g)F2(g) 2NO Fg) It is observed that, when the concentration of F2 is reduced to 1/3 o its initial value, the rate of the reaction is also reduced to 1/3 of its nitial value. When the concentration of NO2 is multiplied by 4.48, the rate of the reaction also increases by a factor of...
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