1. Consider the reaction below: 3Ag2S(s) +
8H+(aq) + 2NO3-(aq) ?
6Ag+(aq) + 3S(s) + 2NO(g) + 4H2O(l)
In this reaction, which species is reduced?
2. Calculate Ecell for the following
electrochemical cell which is operating under nonstandard
conditions:
Cr | Cr3+(0.010 M) ||
Ag+(0.00010 M) | Ag
The relevant standard reduction potentials are:
Cr3+(aq) + 3e- ? Cr(s) | Eº = ?0.74 V |
Ag+(aq) + e- ? Ag(s) | Eº = +0.80 V |
1. Consider the reaction below: 3Ag2S(s) + 8H+(aq) + 2NO3-(aq) ? 6Ag+(aq) + 3S(s) + 2NO(g)...
Given the following standard reduction potentials Ru2+(aq) + 2e– → Ru(s) Eº = 0.46 V Pb2+(aq) + 2e– → Pb(s) Eº = –0.13 V Fe2+(aq) + 2e– → Fe(s) Eº = –0.44 V Cr3+(aq) + 3e– → Cr(s) Eº = –0.74 V Mn2+(aq) + 2e– → Mn(s) Eº = –1.19 V Mg2+(aq) + 2e– → Mg(s) Eº = –2.36 V choose all metals that will not prevent corrosion of iron by cathodic protection. Group of answer choices only Pb only...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
Half-reaction Cr3+ (aq) + 3e- → Cr(s) Fe2+ (aq) + 2e- → Fe (s) Fe3+ (aq) + e- + Fe2+ (s) Sn4+ (aq) + 2e- + Sn2+ (aq) E° (V) -0.74 -0.440 +0.771 +0.154 3Sn** (aq) +2Cr(s) → 2Cr** (aq) +3Sn²+ (aq) 3. What is the cell potential, Ecell, for the reaction above if [Sn] = 1.00 M, [Cr3+1 = 0.0200 M and [Sn2+] = 0.0100 M?
A voltaic cell is set up with a beaker on the left containing 1.0 M AgNO 3 and a silver electrode, and a beaker on the right containing 1.0 M Cr(NO 3) 3 and a chromium electrode. Given the following standard reduction potentials, answer the 3 questions below: Eº Ag+(aq) + 1e → Ag(s) +0.80 V Cr3+(aq) + 3e → Cr(s) -0.73V Part a. Write out the half-cell reaction that occurs at the anode of the voltaic cell. Part...
Given: C+++ (aq) +3e" = Cr(s);E°=-0.74V Ag+ (aq) +e Ag(s); E° = 0.80 V What is the cell potential at 25°C for the following cell? Cr(s) | Cr3+(0.010 M) || Ag+(0.00025 M) | Ag(s) a) 1.71 V b) 1.51 V O c) 0.95 V d) 2.09 V e) 1.37 V
Consider the following cell reaction: 2Cr(s) + 6H*(aq) - 2Cr3+ (aq) + 3H2(g); Eºcell = 0.74V Under standard-state conditions, what is Eº for the following half-reaction? C++ (aq) + 3e - Cr(s) Select one: a. -0.37 V Ob. 0.74 V Oc. -0.74 V Od 0.25V o e. 0.37 v
Use the standard reduction potentials from the following table to choose the weakest reducing agent among those shown below. Ag+(aq) + - + Ag(s) E° = 0.80 V Cu2+(aq) + 2e → Cu(s) E° = 0.34 V Ni2+(aq) + 2e + Ni(s) E° = -0.26 V Cr3+(aq) + 3e- → Cr(s) E° = -0.74 V Mn2+(aq) + 2e → Mn(s) E° = -1.19 V О Ni(s) Ag(s) Cr(s) Mn(s) Cu(s)
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures. Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V) Half-reaction E∘ (V) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) −0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) −0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) −0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) −0.76 Cu2+(aq)+2e−→Cu(s) 0.34 Mn2+(aq)+2e−→Mn(s) −1.18 2H+(aq)+2e−→H2(g) 0.00 Al3+(aq)+3e−→Al(s) −1.66 Fe3+(aq)+3e−→Fe(s) −0.036 Mg2+(aq)+2e−→Mg(s) −2.37 Pb2+(aq)+2e−→Pb(s) −0.13 Na+(aq)+e−→Na(s) −2.71 Sn2+(aq)+2e−→Sn(s) −0.14 Ca2+(aq)+2e−→Ca(s) −2.76 Ni2+(aq)+2e−→Ni(s) −0.23 Ba2+(aq)+2e−→Ba(s) −2.90 Co2+(aq)+2e−→Co(s) −0.28 K+(aq)+e−→K(s) −2.92 Cd2+(aq)+2e−→Cd(s)...
Standard Electrode Potentials at 25?C Reduction Half-Reaction E?(V) F2(g)+2e? ?2F?(aq) 2.87 Au3+(aq)+3e? ?Au(s) 1.50 Cl2(g)+2e? ?2Cl?(aq) 1.36 O2(g)+4H+(aq)+4e? ?2H2O(l) 1.23 Br2(l)+2e? ?2Br?(aq) 1.09 NO3?(aq)+4H+(aq)+3e? ?NO(g)+2H2O(l) 0.96 Ag+(aq)+e? ?Ag(s) 0.80 I2(s)+2e? ?2I?(aq) 0.54 Cu2+(aq)+2e? ?Cu(s) 0.16 2H+(aq)+2e? ?H2(g) 0 Cr3+(aq)+3e? ?Cr(s) -0.73 2H2O(l)+2e? ?H2(g)+2OH?(aq) -0.83 Mn2+(aq)+2e? ?Mn(s) -1.18 How can the table be used to predict whether or not a metal will dissolve in HCl? In HNO3? Drag the terms on the left to the appropriate blanks on the right to...
For the reaction below: (5 points) 3Cu(s) + 2NO3– (aq) + 8 H+(aq) 3Cu2+(aq) + 2NO(g) + 4H2O(퓁)What is Gº at 25 ºC?(a) −361 kJ(b) 180. kJ(c) 361 kJ(d) −120 kJ(e) none of these