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Consider the following reaction that shows time-independent stoichiometry. and has an experimental rate equation of the...
I need help with question number 5. 283 14.4 Equilibria in complex reactions (5) The experimental...
I need help with question number 5.
283 14.4 Equilibria in complex reactions (5) The experimental rate law for the reaction 2NO(g)+Br2(g)→2NOBI(g) Is u= kINO)2[Br2]. Show that this rate law is consistent with the mechanism NO(g) + Br2(g NOE3r2(g) + NO(g) kI NOBT2(g) k-1 2NOBrg) → Give an equation for the experimental rate constant k in terms of the elementary rate constants ki, k-i and k2. Briefly discuss, based on your derivation of the rate equation, which elementary processes are...
Please help!!! Our experimental rate law is rate=k[H2O2][KI] which shows they are both first order. UsItion...
Please help!!! Our experimental rate law is rate=k[H2O2][KI]
which shows they are both first order.
UsItion of Hydrogen Peroxide The following reaction mechanism has been proposed focwhe the first step is the rate-limiting step. Using these elementary st the reaction you studied),where eps, show (in your report the rate law for each step. Based on these rate laws,isthe reaction mechanismbelow consisen with your experimental results? Explain. H,O, (aq) +1-(ag) → 10-(aq) +HO() HO, (aq) + IO, (a)→1. (aq) + H,0(!)...
for hhe 0Verall reaction is Rate k ICHCL,JICIJ Is the following mechanism consistent with the experimental...
for hhe 0Verall reaction is Rate k ICHCL,JICIJ Is the following mechanism consistent with the experimental results? ki 2 Cl(g) fast equilibrium k.j k2 CHCls(g)+Cl(gHCI(g)+ CCl(g) Slow k3 fast
The following mechanism has been proposed for the reaction between nitrogen monoxide and oxygen in the...
The following mechanism has been proposed for the reaction
between nitrogen monoxide and oxygen in the gas phase.
.....step
1.....fast:......2
NO --->
N2O2
.....step
2.....slow:....N2O2
+ O2 ----> 2
NO2
(1) What is the equation for the overall reaction?
Use the smallest integer coefficients possible. If a box is not
needed, leave it blank.
_______ +
________
_________ + ________
(2)
Enter the formula of any species
that acts as a reaction intermediate? If none leave box...
Question 14 Consider the following reaction AB+30 According to the experimental results, a student found that...
Question 14 Consider the following reaction AB+30 According to the experimental results, a student found that the concentration of product Bincreases with time proportionally. Which of the following statement is correct? The half-life for this reaction is independent to the initial concentration of reactant A. When the initial concentration of reactant Ais doubled, the initial reaction rate is also doubled. The production rate of product is 3 times higher than that of B. If the initial concentration of reactant A...
2. Consider the reaction below between nitric oxide and hydrogen gas: 2 NO(g) + 2 H2(g)...
2. Consider the reaction below between nitric oxide and hydrogen gas: 2 NO(g) + 2 H2(g) - N2 + 2 H2009) Upon being studied experimentally, it has been determined that the rate law expression for this reaction is first order in Hz and second order in NO(g). With this information in mind, answer the following: [Tip: You can assume that the steady-state approximation is valid for any intermediate here.) a. As written, is the reaction above a valid mechanism? In...
Question 2: Data analysis and reactor design The stoichiometry of a non-elementary liquid-phase reaction can be...
Question 2: Data analysis and reactor design The stoichiometry of a non-elementary liquid-phase reaction can be represented by the reaction: A products The following data were obtained from an experimental campaign to determine the rate equation Concentration (moles/dm) of reactant A Time seconds 1.50 1.05 10 0.80 15 sody 0.65 0.50 20 Determine the order of the reaction using polynomial method 2.1 (10) 2.2 Following from your results in question 2.1 above, show by using Integral Method that your result...
At 300 K, the following reaction is found to obey the rate law of Rate =...
At 300 K, the following reaction is found to obey the rate law of Rate = k[NOCl]^2: 2 NOCl(g) 2 NO(g) + Cl2(g) The following reaction mechanism has been proposed for the reaction above: Proposed Mechanism: NOCl(g) ->NO(g) + Cl(g) slow Cl(g) + NOCl(g) -> NOCl(g) fast NOCl2(g) -> NO(g) + Cl2(g) fast 21. The suggested rate law in the mechanism is Rate = k[NOCl]. (T) 22. The reaction mechanism is plausible. (F) 23. NOCl2 is a catalyst in...
2. Differential method of analysis: Consider the reaction of A B, for which the rate equation...
2. Differential method of analysis: Consider the reaction of A B, for which the rate equation is of the general form TA fn (k, CA) and does not follow elementary kinetics. Based upon the time versus concentration data below from a batch reaction experiment, determine the complete kinetic rate form, that is, determine the order for CA in the rate equation and determine the value of k (kinetic rate constant) using only the differential method of analysis. This means that...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in the spherical coordinate representation is where ao-top- 0.5298 10-10rn is the Bohr radius, and μ is the electon-proton reduced mass. Here, the square of the angular momentum operator L2 in the spherical coordinate representation is given by: 2 (2.2) sin θー sin θ 00 The form of the Schrödinger equation means that all energy eigenstates separate into radial and angular motion, and we can write...
I need help with question number 5.
283 14.4 Equilibria in complex reactions (5) The experimental rate law for the reaction 2NO(g)+Br2(g)→2NOBI(g) Is u= kINO)2[Br2]. Show that this rate law is consistent with the mechanism NO(g) + Br2(g NOE3r2(g) + NO(g) kI NOBT2(g) k-1 2NOBrg) → Give an equation for the experimental rate constant k in terms of the elementary rate constants ki, k-i and k2. Briefly discuss, based on your derivation of the rate equation, which elementary processes are...
Please help!!! Our experimental rate law is rate=k[H2O2][KI]
which shows they are both first order.
UsItion of Hydrogen Peroxide The following reaction mechanism has been proposed focwhe the first step is the rate-limiting step. Using these elementary st the reaction you studied),where eps, show (in your report the rate law for each step. Based on these rate laws,isthe reaction mechanismbelow consisen with your experimental results? Explain. H,O, (aq) +1-(ag) → 10-(aq) +HO() HO, (aq) + IO, (a)→1. (aq) + H,0(!)...
for hhe 0Verall reaction is Rate k ICHCL,JICIJ Is the following mechanism consistent with the experimental results? ki 2 Cl(g) fast equilibrium k.j k2 CHCls(g)+Cl(gHCI(g)+ CCl(g) Slow k3 fast
Question 14 Consider the following reaction AB+30 According to the experimental results, a student found that the concentration of product Bincreases with time proportionally. Which of the following statement is correct? The half-life for this reaction is independent to the initial concentration of reactant A. When the initial concentration of reactant Ais doubled, the initial reaction rate is also doubled. The production rate of product is 3 times higher than that of B. If the initial concentration of reactant A...
2. Consider the reaction below between nitric oxide and hydrogen gas: 2 NO(g) + 2 H2(g) - N2 + 2 H2009) Upon being studied experimentally, it has been determined that the rate law expression for this reaction is first order in Hz and second order in NO(g). With this information in mind, answer the following: [Tip: You can assume that the steady-state approximation is valid for any intermediate here.) a. As written, is the reaction above a valid mechanism? In...
Question 2: Data analysis and reactor design The stoichiometry of a non-elementary liquid-phase reaction can be represented by the reaction: A products The following data were obtained from an experimental campaign to determine the rate equation Concentration (moles/dm) of reactant A Time seconds 1.50 1.05 10 0.80 15 sody 0.65 0.50 20 Determine the order of the reaction using polynomial method 2.1 (10) 2.2 Following from your results in question 2.1 above, show by using Integral Method that your result...
2. Differential method of analysis: Consider the reaction of A B, for which the rate equation is of the general form TA fn (k, CA) and does not follow elementary kinetics. Based upon the time versus concentration data below from a batch reaction experiment, determine the complete kinetic rate form, that is, determine the order for CA in the rate equation and determine the value of k (kinetic rate constant) using only the differential method of analysis. This means that...
2. The hydrogen atom [8 marks] The time-independent Schrödinger equation for the hydrogen atom in the spherical coordinate representation is where ao-top- 0.5298 10-10rn is the Bohr radius, and μ is the electon-proton reduced mass. Here, the square of the angular momentum operator L2 in the spherical coordinate representation is given by: 2 (2.2) sin θー sin θ 00 The form of the Schrödinger equation means that all energy eigenstates separate into radial and angular motion, and we can write...
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