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CH NH CH3CH2 CH2CH3 3-Pentanone CH3NCHa 0 HOCH2CH20H OCH2CH3 Acid catalyst 0 Ethyl 4-oxopentanoate O CH3NH2...
Identify the best method to prepare 3-ethyl-3-heptene? CH3CH2CH2CH=PPhz + (CH3)2C=0 CH3CH2CH2CH=PPhz + (CH3CH2)2C=0 CH3CH2CH2CH=PPh3 + CH3CH2C(O)CH...
Identify the best method to prepare 3-ethyl-3-heptene? CH3CH2CH2CH=PPhz + (CH3)2C=0 CH3CH2CH2CH=PPhz + (CH3CH2)2C=0 CH3CH2CH2CH=PPh3 + CH3CH2C(O)CH CH3CH2CH=PPhz + (CH2CH2)2C=0
1. Give IUPAC names for the following compounds: O H.C =CH-C-NH2 H,00 H.CO 2. Draw structures...
1. Give IUPAC names for the following compounds: O H.C =CH-C-NH2 H,00 H.CO 2. Draw structures corresponding to each of the given names. Ethyl 4-aminobenzoate acetic formic anhydride 3. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first) H,C-4-0--CHHC-2-N(CH) Hc--OCH, (CH),CH----OCH,
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining...
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining functional group of a carboxylic acid? a) an-H attached to a carbonyl group b) an-H attached to a carbon-carbon triple bond c) an-OH attached to a carbonyl group d) an -OH group attached to a O-C double bond e) an-OH group attached to an aromatic ring To convert a carboxylic acid to an aldehyde a) convert the acid to an acid chloride, then use...
Please help! For the reaction in step 2, how do i find the theoretical yield of...
Please help! For the reaction
in step 2, how do i find the theoretical yield of the product for
this reaction? 0.07 moles of the reactant (ethyl acetoacetate
ethylene ketal) was used. What is that keto alcohol product
(circled) called? what is the molar mass of that circled product??
thank you!!
(TsOH) as catalyst. . Check your organic textbook for the mechanism- acid-catalvzed addition of alcohol to aldehydes or ketones to form acetals or ketals. The ketone carbonyl, significantly more...
CH20% O C CH 20% SOCl2, pyr (CH3CH2)2NH CH3 CH3 N,N-Diethyl-m-toluamide (DEET) 3. a. Why is...
CH20% O C CH 20% SOCl2, pyr (CH3CH2)2NH CH3 CH3 N,N-Diethyl-m-toluamide (DEET) 3. a. Why is the amine added in a solution of sodium hydroxide? b. Both the amine and hydroxide ion are good nucleophiles. Why doesn't the hydroxide attack the acid chloride in this reaction? 4. In the absence of pyridine, a prominent peak at 1780 cm appears in the IR spectrum of the product. Explain.
2) Draw the for the O + CH,NH, 0 Cl,OLCCII, (c) .NH. ? H,C NO, +...
2) Draw the for the O + CH,NH, 0 Cl,OLCCII, (c) .NH. ? H,C NO, + O,N NHNH, 2,4 dinitrophanyl- hydrazine ?? 3) Why was base required to get the reaction to go forward? In other words, why will hydroxylamine HCI and benzophenone not react on their own? 4) Ifyou camed out your reaction with phenylcyclohexyl ketone, you would have gotten the product shown below: ?? Unlike your product, this product can tautomerize (rearrange a double bond) to give an...
Please write neatly. 3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, C...
Please write neatly.
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, CH, -OCH,C 2) H2O COOMe LIAIH OH Ci 0
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI
0...
1.The main product of the reaction between p-cresol and Br2 / FeBr3 is: 3-Bromo-4-methyl phenol 2-Bromo-4-methyl...
1.The main product of the reaction between p-cresol and Br2 / FeBr3 is: 3-Bromo-4-methyl phenol 2-Bromo-4-methyl phenol 2-methyl-4-bromine phenol 3-methyl-4-bromine phenol 2.Which of the following compounds is the least reactive in the nucleophilic substitution with NaOH? 2,4-dinitrochlorobenzene m-nitrochlorobenzene o-nitrochlorobenzene 3,5-dinitrochlorobenzene 3.What is the mechanism (s) for the reaction of 4-bromo-1-nitrobenzene with sodium hydroxide to form 4-nitrophenol? bimolecular nucleophilic substitution (Sn2) aromatic nucleophilic substitution by addition-elimination aromatic nucleophilic substitution by elimination-addition aromatic electrophilic substitution 4.which of the following is the correct...
QUESTIONS 1. What is the purpose of the sulfuric acid (yes, it's a catalyst, but why...
QUESTIONS 1. What is the purpose of the sulfuric acid (yes, it's a catalyst, but why is it a catalyst? What is it doing that makes the reaction possible? Would the reaction just go slower without it, or would the reaction not go at all? Why?) 2. If isobutyl alcohol (2 methyl propanol) is used instead of tert butyl alcohol, a mixture of products is obtained. One the products is the same as the product obtained with the tert butyl...
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, o...
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, on last year's quiz), substituents on the aromatic ring can further modify the reactivity. First, we will consider a phenyl amide with a para-acetyl substituent: CH, (a) What is the n-effect (resonance) of the para-acetyl substituent? How will that affect the reactivity of the other (amide) carbonyl in the molecule below (increase or decrease, compared to the same amide but with no p-...
Identify the best method to prepare 3-ethyl-3-heptene? CH3CH2CH2CH=PPhz + (CH3)2C=0 CH3CH2CH2CH=PPhz + (CH3CH2)2C=0 CH3CH2CH2CH=PPh3 + CH3CH2C(O)CH CH3CH2CH=PPhz + (CH2CH2)2C=0
1. Give IUPAC names for the following compounds: O H.C =CH-C-NH2 H,00 H.CO 2. Draw structures corresponding to each of the given names. Ethyl 4-aminobenzoate acetic formic anhydride 3. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first) H,C-4-0--CHHC-2-N(CH) Hc--OCH, (CH),CH----OCH,
What is the correct name for the following compound? d) 5-oxo-3-octenoic acid What is the defining functional group of a carboxylic acid? a) an-H attached to a carbonyl group b) an-H attached to a carbon-carbon triple bond c) an-OH attached to a carbonyl group d) an -OH group attached to a O-C double bond e) an-OH group attached to an aromatic ring To convert a carboxylic acid to an aldehyde a) convert the acid to an acid chloride, then use...
Please help! For the reaction
in step 2, how do i find the theoretical yield of the product for
this reaction? 0.07 moles of the reactant (ethyl acetoacetate
ethylene ketal) was used. What is that keto alcohol product
(circled) called? what is the molar mass of that circled product??
thank you!!
(TsOH) as catalyst. . Check your organic textbook for the mechanism- acid-catalvzed addition of alcohol to aldehydes or ketones to form acetals or ketals. The ketone carbonyl, significantly more...
CH20% O C CH 20% SOCl2, pyr (CH3CH2)2NH CH3 CH3 N,N-Diethyl-m-toluamide (DEET) 3. a. Why is the amine added in a solution of sodium hydroxide? b. Both the amine and hydroxide ion are good nucleophiles. Why doesn't the hydroxide attack the acid chloride in this reaction? 4. In the absence of pyridine, a prominent peak at 1780 cm appears in the IR spectrum of the product. Explain.
2) Draw the for the O + CH,NH, 0 Cl,OLCCII, (c) .NH. ? H,C NO, + O,N NHNH, 2,4 dinitrophanyl- hydrazine ?? 3) Why was base required to get the reaction to go forward? In other words, why will hydroxylamine HCI and benzophenone not react on their own? 4) Ifyou camed out your reaction with phenylcyclohexyl ketone, you would have gotten the product shown below: ?? Unlike your product, this product can tautomerize (rearrange a double bond) to give an...
Please write neatly.
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI 0 SOCl OH heat NH 1) CH3MgBr excess CH, CH, -OCH,C 2) H2O COOMe LIAIH OH Ci 0
3. Show the products formed in the tollowing reactions draw two enols 1) Mg. Et O 2) CO2 3) H:O NHz Jo .OTo. 쁘. pyridne CI NH Ci CI
0...
QUESTIONS 1. What is the purpose of the sulfuric acid (yes, it's a catalyst, but why is it a catalyst? What is it doing that makes the reaction possible? Would the reaction just go slower without it, or would the reaction not go at all? Why?) 2. If isobutyl alcohol (2 methyl propanol) is used instead of tert butyl alcohol, a mixture of products is obtained. One the products is the same as the product obtained with the tert butyl...
2. Not only does an aromatic ring itself affect the reactivity of an acid derivative (an ester, on last year's quiz), substituents on the aromatic ring can further modify the reactivity. First, we will consider a phenyl amide with a para-acetyl substituent: CH, (a) What is the n-effect (resonance) of the para-acetyl substituent? How will that affect the reactivity of the other (amide) carbonyl in the molecule below (increase or decrease, compared to the same amide but with no p-...
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