Free Radical Halogenation 2. Supply the identities of each of the following unknowns, A - F,...
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III IV 5. The product of free-radical halogenation reactions is an alkyl halide. The major amount of this halide forms during the second step of propagation. However, you should be aware that one possible termination step also forms alkyl halides. Why does the majority of the alkyl halide product come from the propagation step and not the termination step? A. At any given time during the reaction, the concentration of both the alkyl radical and the halide...
20. Which of the halogens below undergoes free radical halogenation with ethane most rapidly? a. Fluorine b. Chlorine c. lodine d. Bromine 1. List the differences between SN1 and SN2 reactions. (10 points)
Which of the following statements is (are) true about free radical halogenation of alkanes? choose only one 1) The first of the chain-propagating steps is rate-determining. 2) The reaction proceeds by way of a flat sp2 hybridized free radical. 3) The chain-initiating step involves cleavage of a carbon-hydrogen bond to afford a carbon radical and a hydrogen atom. 4) Statements (The first of the chain-propagating steps is rate-determining) and (The reaction proceeds by way of a flat sp2 hybridized free...
In which stage of free radical halogenation does the net number of radicals stay the same? Select one: O a. Termination O b. Alkylation c. Initiation O O d. Propagation
questions 14,15,and16 please
Model 8: Selectivity of the Photo-Halogenation Reaction Radical halogenation with Fis i olent and dangerous limiting the usefulness of this reaction in organic synthesis Radical halogenation with lis so slow as to be useless in organic synthesis Radical halogenation with Br, is just right! It is very useful in organic synthesis. The rate is manageable and reactions with Bry are very selective. (A selective reaction gives close to 100% of a single product. An unselective reaction gives...
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188 ChemActivity 20 Radical Halogenation of Aanes Model 8: Selectivity of the Photo-Halogenation Reaction • Radical halogenation with F, is unselective, violent and dangerous limiting the usefulness of this reaction in organic synthesis. • Radical halogenation with le is so slow as to be useless in organic synthesis • Radical halogenation with Br, is right It is very useful in organic synthesis. The rate is manageable and reactions with Br, are very...
1) Consider the free radical monochlorination of 3-methylpentane and answer the following: a) How many products (including stereoisomers) are formed? _______ b) How many are chiral? ________ c) Would the major product of free radical bromination possess a chiral carbon? Yes or No 2) Which of the following functional groups can be generated in one step via SN2 or SN1 reaction? (Enter all that apply) a) Aldehyde b) Alcohol c) Alkene d) Alkyne e) Amine f) Carboxylic Acid g) Ester...
1) Consider the free radical monochlorination of 3-methylpentane and answer the following: a) How many products (including stereoisomers) are formed? _______ b) How many are chiral? ________ c) Would the major product of free radical bromination possess a chiral carbon? Yes or No 2) Which of the following functional groups can be generated in one step via SN2 or SN1 reaction? (Enter all that apply) a) Aldehyde b) Alcohol c) Alkene d) Alkyne e) Amine f) Carboxylic Acid g) Ester...
Answer the following two questions about the following synthetic scheme. (Numbers in parentheses below the structures are for identification purposes.) CH, Cl/h CI KOH CI +K -HCI - H2O NO2 NO NO2 (1) (2) (3) CA NO2 NO2 NO2 -KCI -HCI CI (4) (5) NO, NO H/Pd/C A NH2 -NH (6) (7) NH2 Br + (9) (8) ta +NH -HCI -HCI CI HAN (10) What is the role of KOH in the conversion of 2) to (3)? Select one: O...
Consider the preparation of an addition polymer by a radical chain reaction Q. 2 (a) Give the polymers that can be formed from each of the following monomers and show the repeating unit in each case CI OMe (b) Describe the key steps in a radical chain growth polymerisation. What is "head to tail" addition and explain why it preferentially occurs (c) (d) Show the resonance stabilisation for the radical formed where possible for each of the monomers given in...