Question

How do you know which hydrogen on Camphor belongs to which peak in H NMR

1.1 1.0 0.9 0.8 ppm 18.92 30.58 21.84 28.66


How do you know which hydrogen on Camphor belongs


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Answer #1

The most shielded peak at 0.85 ppm is by the methyl on 7th carbon which is on the side of carbonyl group.

the next peak at 0.9 ppm goes to the methyl adjacent to carbonyl carbon. and the next less shielded one can be assigned to the methyl on carbon -7 which is away from the carbonyl group.

your spectrum shows some extra peaks, there need to be three peaks only corresponding to three methyl groups in 0.8- 1.0 ppm

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