X is known to exist at 1 atm in the solid, liquid, or vapor phase, depending...
Substance X is known to exist at 1atm in the solid, liquid, or vapor phase, depending on the temperature. Additionally, the values of these other properties of Xhave been determined.: melting point 15.°C enthalpy of fusion 8.00/kJmol density 2.00/gcm3 (solid) 1.60/gmL (liquid) boiling point 60.°C enthalpy of vaporization 31.00/kJmol heat capacity 36.·J·K−1mol−1 (solid) 29.·J·K−1mol−1 (liquid) 55.·J·K−1mol−1 (vapor) You may also assume X behaves as an ideal gas in the vapor phase. Suppose a small sample of X at −20°C is...
Calculate the amount of heat needed to transform, under standard conditions, 1.0 mol of liquid methanol at 273 K to 1.0 mol of methanol vapor at 373 K. Assume that Cp,m for liquid methanol and for methanol vapor are independent of temperature. (Enthalpy of vaporization of methanol 35.3 KJ/mol-1, Cp,m of methanol 81.6 JK-1/mol)
Heat of fusion (ΔHfus) is used for calculations involving a phase change between solid and liquid, with no temperature change. For H2O, ΔHfus=6.02 kJ/mol. Specific heat capacity (C) is used for calculations that involve a temperature change, but no phase change. For liquid water, C=4.184 J/(g⋅∘C). Heat of vaporization (ΔHvap) is used for calculations involving a phase change between liquid and gas, with no temperature change. For H2O, ΔHvap=40.7 kJ/mol. How much heat is required to boil 77.5 g of...
A pure solid sample of Substance X is put into an evacuated flask. The flask is heated at a steady rate and the temperature recorded as time passes. Here is a graph of the results: 190.- TI temperature (°C) 150. 30. heat added (kJ/mol) Use this graph to answer the following questions: What is the melting point of X ? 1°C What phase (physical state) of X would you expect to find in the flask after 19 kJ/mol of heat...
The vapor pressure of liquid C4H10 is 324.1 mmHg at a temperature of 251.0 K. The enthalpy of vaporization, ΔHvap, for this liquid is 22.4 kJ/mol. What is the vapor pressure of C4H10 at a temperature of 269.2 K, in mmHg?
1) The vapor pressure of liquid antimony is 400 mm Hg at 1.84×103 K. Assuming that its molar heat of vaporization is constant at 115 kJ/mol, the vapor pressure of liquid Sb is _____ mm Hg at a temperature of 1.81×103 K. 2) The normal boiling point of liquid acetone is 329 K. Assuming that its molar heat of vaporization is constant at 29.0 kJ/mol, the boiling point of CH3COCH3 when the external pressure is 1.21 atm is ______ K.
5. Calculate the heat (in kJ) required to transform 70.80 g of bromine from a solid at a temperature of -7.2 °C to a gas at 92 °C. Report your answer to one decimal place. Data: Molar mass of bromine, Br 2 = 159.808 g/mol Melting point = -7.2 °C Boiling point = 59°C. Enthalpy of fus ion = 10.57 kJ/mol Enthalpy of vaporization = 29.96 kJ/mol. Molar heat capacity of the liquid phase = 75.7 J/mol • K Molar...
identifying phase transitions on a heating curve - O GASES, LIQUIDS, AND SOLIDS Identifying phase transitions on a heating curve A pure solid sample of Substance X is put into an evacuated flask. The flask is heated at a steady rate and the temperature recorded as time passes. Here is a graph of the results: temperature (°C) heat added (kJ/mol Use this graph to answer the following questions: What is the melting point of X? What phase (physical state) of...
Given the following information for an unknown chemical: Specific heat (c) of solid phase: 1.75 J/g°C Heat of fusion (ΔHfus): 32.0 kJ/mol Specific heat (c) of liquid phase: 4.50 J/g°C Heat of vaporization (ΔHvap): 400. kJ/mol Specific heat (c) of vapor phase: 1.50 J/g°C Molar mass: 72.5 g/mol Freezing point: -15.00°C Boiling point: 15.00°C 1.Calculate the total energy needed (in kJ) to convert 15.5g of this chemical from -21.5°C to room temperature (23.0°C).
The vapor pressure of Y is 4.590 atm at 330K and 9.180 atm at 380K. What are the standard free energies of vaporization at the two temperatures? Hint: vaporization reaction is Y(I) = Y(g). AG330º = kJ/mol AG380º = kJ/mol Assume that the standard entropy and enthalpy of vaporization of Y are independent of temperature and determine their values ASO = J/(mol-K) AH = kJ/mol What is the normal boiling point of Y in degrees Celcius? t = Ос What...