Substance X is known to exist at 1atm in the solid, liquid, or vapor phase, depending on the temperature. Additionally, the values of these other properties of Xhave been determined.:
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You may also assume X behaves as an ideal gas in the vapor phase.
Suppose a small sample of X at −20°C is put into an evacuated flask and heated at a constant rate until 20.0/kJmol of heat has been added to the sample. Graph the temperature of the sample that would be observed during this experiment.
Substance X is known to exist at 1atm in the solid, liquid, or vapor phase, depending...
X is known to exist at 1 atm in the solid, liquid, or vapor phase, depending on the temperature. Additionally, the values of these other properties of Substance X have been determined: boiling point 35. melting point enthalpy of fusion6.00 kJ/mol enthalpy of vaporization 34.00 kJ/mol 46. J-K mol (solid) 73. JK mol (vapor 2.80 g/em (solid) 2.40 g/mL (liquid density heat capacity61.JKmol Ciquid) You may also assume X behaves as an ideal gas in the vapor phase. Suppose a...
A pure solid sample of Substance X is put into an evacuated flask. The flask is heated at a steady rate and the temperature recorded as time passes. Here is a graph of the results: 190.- TI temperature (°C) 150. 30. heat added (kJ/mol) Use this graph to answer the following questions: What is the melting point of X ? 1°C What phase (physical state) of X would you expect to find in the flask after 19 kJ/mol of heat...
For a given pure substance, vapor pressure values were determined experimentally in equilibrium with the solid and liquid phases, at different temperatures, from which the following ratios were deduced: Solid / vapor equilibrium: ln (p / mmHg) = 17.44 - 939.7 / (T / K) Liquid / vapor balance: ln (p / mmHg) = 16.02 - 820.0 / (T / K) a) Determine the coordinates (p, T) of the triple point of the substance. b) Assuming that the enthalpy values...
Naphthalene, C10H8, melts at 80.0 ˚C; the vapor pressure of the solid is 1.00 torr at 52.6 ˚C, and that of the liquid is 10.0 torr at 85.8 ˚C and 40.0 torr at 119.3 ˚C. Calculate: (a) the enthalpy of vaporization, the normal boiling point, and the entropy of vaporization at the boiling point; (b) the vapor pressure at the melting point (Hint: liquid and solid are in equilibrium there)
15. According to the Clausius-Clapeyron equation ln va R T T P"арф) refers to the vapor pressure at temperature 1, R-2 cal/mol-K, and Ah is the heat of changc associated with the process of transitioning to the vapor (cither sublimation or vaporization depending on whether the transition is from solid to vapor or liquid to vapor) i.e., дН-H vapor-H , where X is either solid or liquid and H denotes the corresponding molar enthalpy. Use the Clausius-Clapeyron equation to solve...
Heat of fusion (ΔHfus) is used for calculations involving a phase change between solid and liquid, with no temperature change. For H2O, ΔHfus=6.02 kJ/mol. Specific heat capacity (C) is used for calculations that involve a temperature change, but no phase change. For liquid water, C=4.184 J/(g⋅∘C). Heat of vaporization (ΔHvap) is used for calculations involving a phase change between liquid and gas, with no temperature change. For H2O, ΔHvap=40.7 kJ/mol. How much heat is required to boil 77.5 g of...
identifying phase transitions on a heating curve - O GASES, LIQUIDS, AND SOLIDS Identifying phase transitions on a heating curve A pure solid sample of Substance X is put into an evacuated flask. The flask is heated at a steady rate and the temperature recorded as time passes. Here is a graph of the results: temperature (°C) heat added (kJ/mol Use this graph to answer the following questions: What is the melting point of X? What phase (physical state) of...
4. The other phase change that can happen is liquid to gas. Similar to the phase change of solid to liquid, the temperature of the system does not change. All of the energy goes into the phase change. Only now instead of the latent heat of fusion, we have the latent heat of vaporization: Q = mly How much heat must be added to 3.8 kg (1 gallon) of water for half of it to be changed into gas? The...
4. The other phase change that can happen is liquid to gas. Similar to the phase change of solid to liquid, the temperature of the system does not change. All of the energy goes into the phase change. Only now instead of the latent heat of fusion, we have the latent heat of vaporization: Q = mL How much heat must be added to 3.8 kg (1 gallon) of water for half of it to be changed into gas? The...
Given the following information for an unknown chemical: Specific heat (c) of solid phase: 1.75 J/g°C Heat of fusion (ΔHfus): 32.0 kJ/mol Specific heat (c) of liquid phase: 4.50 J/g°C Heat of vaporization (ΔHvap): 400. kJ/mol Specific heat (c) of vapor phase: 1.50 J/g°C Molar mass: 72.5 g/mol Freezing point: -15.00°C Boiling point: 15.00°C 1.Calculate the total energy needed (in kJ) to convert 15.5g of this chemical from -21.5°C to room temperature (23.0°C).