Using the specified starting material and any other reagents, show how each of the following compounds can be
prepared:
a) CH3-CH2-CH2-OH ---------> H3C-CC-H
B)CHCH------> CH3-CH3-C-(Cl)2-CH3
c) HCCH --------> CH2-CH2-CH(Br)-CH3
Using the specified starting material and any other reagents, show how each of the following compounds...
iven starting material, any necessary inorganic reagents and catalysts, and any carton -conmaining compoundsh Using caos l. ndicate how each of the following compounds can be prepared: CH CH2OH Br d. e. CH3 CH3 lithium divinvlcuprate [(CH-CH)2Culi) for the synthesis ofeach of the following compounds?
show how to carry out the following synthetic transformations using any compounds with one or two carbon atoms, any necessary solvents, and any Inorganic reagents. Clearly indicate reaction conditions. More than one synthetic step will be required (work backwards!) 1-Bromopentane- 2-Chloropenia H-C=C-H H₃C Br H-C=C-H - Br CH3 CHO H-C=c-H HO HIC TOH meso H-C=C-H c=CH₂ H3C CH(CH2).CHCI - CH(CH2),CHCHCI Наснас н H3CH2CCECH 4 CH₂CH₃ H3CH2CCECCH2CH3 Br Br CH,CH,CHCHCH.CH meso trans Ph trans OH show in most stable chair conformation)...
Propose syntheses of each of the following compounds, from the given starting material and any other needed reagents. » O- CH2OH from O con b) CH3CCHz from CH3CH=CH2 ОН • OCHGHs from O-Br
Starting from benzene and using any other necessary reagents of your choice, design a synthesis for each of the following compounds. Some problems have more than one plausible 1 answer (a) Cl. .NO2 (b) НAN. (c) H2N (d) (e) Br СООН СООН Br (g)* in this example, what can be done to minimise the amount of the meta/para isomes. NO2 (h) Br H2N Br Cl -NH2 Cl (k) Br
Part C 20.50 Starting with benzene and using any other reagents of your choice, show how you would prepare each of the following compounds: of OH N (b) (a) HO (d) (c) I-N
Devise a synthesis of the following compounds from the given starting material and any other required reagents several steps OH yan several steps Br several steps ore
2. Is it possible to distinguish the molecules given below from each other by using 'H NMR spectroscopy? Explain your answer in detail. H3C CH3 and H3c1 CH2CH3 3. How many peaks will the following compounds have in its 'H NMR spectrum? Show each Hatom. a HC H b) 4. What is the multiplicity (splitting) expected in the 'H NMR spectrum for all the hydrogen atoms in the following 3 compounds? Hz OH CHCH H 11 CH3-C-CH2-CH3 here are so...
Starting with benzene and using any other neccessary reagents of your choice, design a synthesis for each of the following: OMe COOH Br Br NO NO (b) COOH NH Cl Cl NO2 COOH NO2 Cl NO Cl Br OEt NO2 Cl (h) C (g) NO2 Br O2N
Practice Problem 23.50 Starting with cyclopentene and using any other reagents of your choice, show how you would make each of the following compounds: (a) (b) (c) HO OH Choose from the following list of reagents: c b d Pd[OAC)2, PPhy, BN NaOH, H20, heat H,0NaOH (xs) CH2CH2 f g e BHy-THF (xs) CHşlyZn-Cu. Et, BCOM) h Grubbs catalyst i k - BE Be Using the reagents above, list in order (by letter, no period) those necessary to provide each...
Propose a synthesis of the following derivative of diethyl malonate using reagents from the choices provided below. (From the choices provided, list the reagent(s) in order that will accomplish this transformation. No more than 4 steps are required. List your answer as a single letter (single-step transformation) or a series of letters (multi-step transformation) with no commas separating them.) Reagents available a. Eto Na g. CH2=CHCH=CHCH,Br b. CH3 CH2Br c. CH3 CH, CH, CH(CH3)Br d. (CH3)2 CHCH, CH,Br e. CH3...