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1. Consider a free particle in one-dimensional space of dimension L. If the momentum eigenstates (0p(x))...
quantum mechanics
Consider a particle confined in two-dimensional box with infinite walls at x 0, L;y 0, L. the doubly degenerate eigenstates are: Ιψη, p (x,y))-2sinnLx sinpry for 0 < x, y < L elsewhere and their eigenenergies are: n + p, n, p where n, p-1,2, 3,.... Calculate the energy of the first excited state up to the first order in perturbation theory due to the addition of: 2 2
Consider a particle confined in two-dimensional box with infinite...
3. Consider a free particle on a circle. That is, consider V(z) = 0 and wave functions Ψ(z, t) which are periodic functions of z: Ψ(z,t) = Ψ(z + L, t). a) Solve the Time-Independent Schroedinger equation. For each allowed energy, En, you will find two solutions, (s). Why does this not contradict the theorem that we proved in class about the non-degeneracy of the solutions to the TISE in one dimension? b) Start with the initial condition Ψ(z,0) sin2(nz/L)....
Problem 3: A free particle of mass m in one dimension is in the state Hbr Ψ(z, t = 0) = Ae-ar with A, a and b real positive constants. a) Calculate A by normalizing v. b) Calculate the expectation values of position and momentum of the particle at t 0 c) Calculate the uncertainties ΔΧ and Δ1) for the position and momentum at t 0, Do they satisfy the Heisenberg relation? d) Find the wavefunction Ψ(x, t) at a...
Consider a potential well defined as \(U(x)=\infty\) for \(x<0, U(x)=0\)for \(0<x<L,\)and \(U(x)=U_{0}>0\) for \(x>L\) (see the following figure). Consider a particle with mass \(m\) and kinetic energy \(E<U_{0}\)that is trapped in the well. (a) The boundary condition at the infinite wall ( \(x=\)0) is \(\psi(x)=0\). What must the form of the function \(\psi(x)\) for \(0<x<L\)be in order to satisfy both the Schrödinger equation and this boundary condition? (b) The wave function must remain finite as \(x \rightarrow \infty\). What must...
1. (50 points) Consider the particle in a one-dimensional box (0 s x S L). Assume a term is added to the Hamiltonian of the form: πχ V(x)g sin Sketch the potential and the expected eigenfunction (small g). In the limit of small g, find the second order correction to the ground state energy 2. (50 points) For a diatomic molecule rotating in free space, the Hamiltonian may be written: 12 21 Where L is the total angular momentum operator,...
Consider a particle confined to one dimension and positive r with the wave function 0, z<0 where N is a real normalization constant and o is a real positive constant with units of (length)-1. For the following, express your answers in terms of a: a) Calculate the momentum space wave function. b) Verify that the momentum space wave function is normalized such that (2.4) c) Use the momentum space wave function to calculate the expectation value (p) via (2.5)
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Consider a particle in a one-dimensional box, where the potential the potential V(x) = 0 for 0 < x <a and V(x) = 20 outside the box. On the system acts a perturbation Ĥ' of the form: 2a ad αδα 3 Approximation: Although the Hilbert space for this problem has infinite dimensions, you are allowed (and advised) to limit your calculations to a subspace of the lowest six states (n = 6), for the questions of...
Consider a particle of mass m under the action of the one-dimensional harmonic oscillator potential. The Hamiltonian is given by Knowing that the ground state of the particle at a certain instant is described by the wave function mw 1/4 _mw2 Th / calculate (for the ground state): a) The mean value of the position <x> (2 marks) b) The mean value of the position squared < x2 > (2 marks) c) the mean value of the momentum <p> (2...
Consider a one-dimensional well with one impenetrable wall. The potential energy is given by 0 x < 0 V(x) = { -V. 0 < x < a 10 x > a We showed in the homework that the allowed energies for the eigenstates of a bound particle (E < 0) in this potential well satisfy the transcendental function -cotĚ = 16 - 52 $2 where 5 = koa, and ko = V2m(Vo + E)/ħ, and 5o = av2mV /ħ (a)...
The eigenfunctions for a particle in a one-dimensional box of length L, and the corresponding energy eigenvalues are given below. What is the variance of measurements for the linear momentum, i.e., Op = v<p? > - <p>2? Øn (x) = ( )" sin nga, n= 1, 2,.. En = n2h2 8m12 Note the Hamiltonian operator to give the energy is H = = - 42 8n72 dx2 nh 2L oo O nềh2 412 Uncertain since x is known. Following Question...