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1. Provide the products, starting materials, or reagents. regioselectivity of the reactions. Use filled or dashed...
2. Provide the reagents/conditions required to accomplish each of the transformations (A-C) below. If a reaction consists of two steps, be sure to show this: 6 points. 3. Draw the starting materials (A and B) required to obtain the products shown below, using the reagents and conditions provided: 6 points. 1. HB(sia), THE 2. H2O2, NaOH, H20 produces 1.03 both products 2.(CH3)2S HgSO4 H2SO4, H20
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Q2. Provide the missing information of the following reactions. (such as reagents, starting materials, products_etc.) 21 1. CH,CH-CH=PP 1-Propanol 2-methylpentan-3-one H+, heat H2N Н. + HO- Н HO- + Y. H trace HCI H НО. OH H3C сн. H30.4 H2CH2CO OCH CH3
1. Provide the missing starting materials, reagents, or products in each of the following reactions. H+ OH CH,OH NaOH Meo NH2 room temp. HO OH Meo Me ОН Meo 2. Provide appropriate conditions to convert each of the following starting mana hexanoic acid (some transformations may require more than one step): It each of the following starting materials into OH OH ОMe "NH₂
Predict the products of the following reactions. I will rate fast. Thank you in advance! excess NaNH2 THF Br Br H 1. NaNH2 2. CH3CH2Br H2SO4, H20 v MSO. MO H2, Pd/Baso quinoline, CH3OH Na, NH3 Na, NH, 1 equivalent HBr NaNH2 Br (excess) 1. Sia BH, THF 2. H202, NaOH h. HgSO4 H2SO4 H20
Directions: Provide the missing reactants, reagents, or products. Indicate stereochemistry where it matters. 1) (Sia)2BH 2) HOOH Cl2 CCl4 (solvent) HO. CH2C Cl2 H20 OsO4 OH OH HCI
Predict the products of the following reactions 1 equivalent HBr NaNH2 Br (excess) 1. Sia BH, THE 2. H2O2, NaOH HgSO4 H2SO4 H20
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
2. (16 pts) Reactions Provide reagents, products or starting materials for the following reactions. Show stereochemistry when relevant (or loss thereof). If a reaction produces no significant products, write "NR". If you have a question about an abbreviation, just ask. NaBr OH 1. TsCI 2. Nal, DMF CI DMSO OH 1. PBrg NaCN 2. KOC(CH3)3 Ether LDA НОН THE NaH NaH PO Acetone Heat, water
1. Predict the product(s), provide the reagents, or draw the starting material used in the reactions below. Be sure to include the correct stereochemistry where needed. ooroo OH 1) Na 2) CICH CH3 H2SO4 но- HCI, ZnCl C l TMSCI, OTMS NELS