Question

Please combine the Mn electrode half reaction with the Ag electrode half reaction and write the complete redox reaction using date from table 8.1. Indicate which is the oxidizing and which is the reducing agent.

Reducing agent Half-reaction E0 (volts) -2.93 2.87 Ca Na Mg Mn Zn Fe Ni Pb Ca Ca2++2e Na → Na++e- -2.36 Mn Mn++2e Zn Zn2++2e Fe → Fe2++ 2e- NiNi2++2e- -0.76 -0.47 -0.24 -0.13 2 Cu+ Cu Cu Fe2+ H2 2H +2e Cu+ → Cu2++ e- Cu Cu++2e- Cu Cut+e Fe2 Fe3++e Ag → Ag++ e- Hg Hg2++2e- 0.00 (SHE) +0.16 +0.34 +0.52 +0.76 +0.80 +0.85 +1.36 Ag На *F-AG/n F (equation 8.22); Δ@calculated using ΔG1. 298.15 values in Robie and Hemmingway (1995) listed in Appendix 6.

b. Calculate the EMF when the reaction quotient (Q) = ]Mn2+]/[Ag+]^2 = 10^-5

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