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In waters affected by acid rain the concentrations of the three carbonic acid species (H2CO3, HCO3-,...

In waters affected by acid rain the concentrations of the three carbonic acid species (H2CO3, HCO3-, CO32-) are determined by concentration of the strong acid deposited by acid rain, as well as the concentration of H2CO3 which is controlled by the solubility of carbon dioxide . Under these conditions (constant H2CO3 and relatively low pH) the only carbonic acid equilbrium of importance is the conjugate base reaction of HCO3-, which is related to, but not identical to - and not the reverse of, Equation 1 in Table 10-3. If the concentration of H2CO3 is 1.3 x 10-5 M and the pH =6.27 what is the concentration of the bicarbonate ion, HCO3-?

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