In waters affected by acid rain the concentrations of the three carbonic acid species (H2CO3, HCO3-, CO32-) are determined by concentration of the strong acid deposited by acid rain, as well as the concentration of H2CO3 which is controlled by the solubility of carbon dioxide . Under these conditions (constant H2CO3 and relatively low pH) the only carbonic acid equilbrium of importance is the conjugate base reaction of HCO3-, which is related to, but not identical to - and not the reverse of, Equation 1 in Table 10-3. If the concentration of H2CO3 is 1.3 x 10-5 M and the pH =6.27 what is the concentration of the bicarbonate ion, HCO3-?
In waters affected by acid rain the concentrations of the three carbonic acid species (H2CO3, HCO3-,...
Calculate the pH and the concentrations of all species present (H2CO3, HCO3 – , CO3 2– , H3O + , and OH– ) in a 0.0037 M M carbonic acid solution. Ka1 = 4.3 × 10–7 ; Ka2 = 5.6 × 10–11
You create a 1 L solution of 0.1 M H2CO3. carbonic acid, H2CO3, is a diprotic acid with Ka1 = 4.5 x 10-7 and Ka2 = 4.7 x 10-11. a) What will the initial pH of the solution be? b) What volume of 0.1 M NaOH will you need to add to reach the second equivalence point( remember carbonic acid deprotonates to bicarbonate HCO3- and then can deprotonate further to CO32-? c) At the second equivalence point, what will the...
One of the most important buffering systems in the biological realm is the carbonic acid (H2CO3)/carbonate ion (HCO3- ) system that maintains the pH of blood plasma to a relatively constant value. In blood at 37°C, the Ka of carbonic acid is 8x10-8. Suppose that the concentrations of the buffer components in the blood plasma are: [HCO3-] = 0.24 M and [H2CO3] = .12 M. Calculate the pH of blood.
Carbonic acid H2CO3 is a weak acid that fully dissociates in two steps in the presence of increased concentration of base. Step 1: H2CO3 =HCO3+H* Step 2: HCO3 =20,2- + H+ What is the composition of species in solution at pH = 10.25 when the halfway point to the first equivalence point has been reached? 50 % H2CO3 and 50 % CO2- 50 % CO2- and 50 % HCO3 50 % H2CO3 and 50 % HCO3 100 % H2CO3
a) Find the concentration of H+, HCO3- and CO32-, in a 0.01M solution of carbonic acid if the pH of this is 4.18. Ka1 (H2CO3) =4.45 x 10–7 and Ka2 =4.69 x 10–11 (b) Calculate the pH at the equivalence point of the titration between 0.1M CH3COOH (25 ml) with 0.05 M NaOH. Ka (CH3COOH) = 1.8 x 10–5.
11. which of the following pairs of species is a conjugate acid-base pair? a. NaF, F b. NHs, NH c. H30+, ОН- d. H2CO3, CO32 8. which of the following salts is most likely to form an aqueous solution having the pH <7? a. NaBr b. LiNO3 c. NH4CI d. RbCN 2. which of the following pairs of species is not a conjugate acid-base pair? a. OH, H b. HOCI, OCh c. HSO4,SO42 d. H2CO3, HCO3 11. which of the...
Calculate the equilibrium concentrations of all chemical species present in a 0.10 M H2CO3(aq) solution. What is the percent ionization of the acid and resulting pH? [H2CO3] = [HCO3-] = [CO32-] = [H3O+] = % ionization = pH = Acid Acetic Ammonium Formula CH:COOH NH4+ H2BO: Boric Carbonic H2CO3 HC1O2 HCOOH Chlorous Formic Hydrocyanic Perchloric 1.8 x 105 5.6 x 10-10 5.4 x 10-10 4.5 x 10-7 4.7 x 10-11 1.1 x 10-2 1.8 x 10-4 5.2 x 10-10 Very...
21. What are the characteristics of the carbonic acid-bicarbonate buffer system (select all that apply? a CO2 is eliminated by the lungs b. Neutralizes HCl acid to yield carbonic acid and salt c. H2CO3 formed by neutralization dissociates into H2O and CO2 d. Shifts H+ in and out of cell in exchange for other cations such as potassium and sodium e. Free basic radicals dissociate into ammonia and OH-, which combines with Ho to form water 22. What are characteristics...
HELP PLEASE 5 – Calculate the concentrations of H+, HCO3- and CO32- in a 0.025 M H2CO3 solution. 6 – Classify the following as a Lewis acid, Lewis base, both or neither:CO2, H2O, I-, SO2, NH3, OH-, H+, BCl37 – 7-Calculate the pH of a solution that is 0.20 M NH3 and 0.30 M NH4Cl.8 – 8-The pH of blood plasma is 7.40. Assuming the principal buffer system is HCO3-/H2CO3, calculate the ratio [HCO3-]/[H2CO3] . 9 – A 0.2688 g...
Calculate the equilibrium concentrations of all chemical species present in a 0.10 M H CO.(aq) solution. What is the percent ionization of the acid and resulting pH? Units Units [H2CO3) = Number [HCO3) = Number [CO32) = Number [H30+) = Number Units Units % ionization = Number pH = Number Ka Acid Acetic Ammonium Formula CH3COOH NH4+ H3B03 1.8 x 10-5 5.6 x 10-10 5.4 x 10-10 Boric Carbonic H2CO3 Chlorous Formic Hydrocyanic Perchloric HCIO2 HCOOH HCN HC104 4.5 x...