Question

3,4,5,6

QUESTIONS 1. Considering that the Cr in CrO, and Cr,0- is in the 6+ oxidation state and that each step in the se- quence CH4 → CH3OH → CH- O → HCOOH → CO2 corresponds to a two-electron change, com- plete and balance the following reactions: +HC,O, CH,CH.COCH, +CO2 +Cr 2. Write a balanced equation for the oxidation of cyclohexanone to adipic acid, and calculate the theo- 3. In an oxidation of cyclohexanol in which the temperature was allowed to rise above 50°C, the yield c. CH CH CH, retical amount of permanganate needed for this procedure. 4. 5. 6. What organic product would you expect from NaBH reduction of the following ketones: of cyclohexanone was low, and an acid by-product, with a melting point of 153 to 154°C, was isolated. Suggest the structure of this product. In basic solution, sodium bisulfite solution the product is What organic product would you expect from the permanganate oxidation of the following ketones: ion (Mn+2). Write balanced equations for these reactions b. 2-pentanone, b. 2-pentanone, c. 1-phenyl-2-propanone? c. 1-phenyl-2- a. acetophenone,

Answer 1