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The Re-Cl bond distance of ReCl6 was found to be 226.3 (6) pm in single-crystal structural...

The Re-Cl bond distance of ReCl6 was found to be 226.3 (6) pm in single-crystal structural determination. However, the calculated structural parameter showed deviation from octahedral symmetry with two shorter Re-Cl bonds (230.6 pm) and four longer Re-Cl bonds (231.5 pm). Explain these results.

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