Use the Born-Mayer equation to estimate te lattice energy for MgO given that both MgO and...
Calculate the lattice energy for PbS using electrostatic forces (assume that it is in a Rock Salt type lattice, although you should be able to determine this). Make sure you use the Born-Mayer correction. Compare the results with the Born-Haber cycle values that you calculate. (All necessary energy values can either be found in your text, at www.webelements.com, or from the following: the 2nd EA of S = 640 kJ/mol (it should be noted that the 1st EA of S...
Use the Born-Lande equation to calculate a value for the lattice energy of KBr for which r0=328pm, KBr adopts NaCl structure.
Use Born-Landéequation to determine the lattice energy of KBr, which crystallizes in NaCl lattice. The sum of ionic radii is 320 pm.
a) Determine the lattice energy of thallium(I) iodide using a Born-Haber cycle with “experimental” thermodynamic data. Then calculate it using the Born-Mayer equation. Determine the % deviation of the calculated value from the “experimental” value. b) Explain the result from part (a), giving consideration to HSAB concept.
what is Coulomb’s Law and use this to discuss lattice energy. A. In the following pairs identify the ionic compound with the greatest lattice energy. You must justify your answer A. NaCl vs NaI B. MgO vs CaO C. CaCl2 vs CaCO3 D. MgS vs NaCl
Using Born-Haber cycle estimate the energy of formation for CaCl2. Estimate latice energy using kapustinskii equation and use it for the Born-Haber cycle.
1. Using the Born-Landé equation and the Kapustinskii equation, calculate the lattice enthalpy of cesium chloride. Cesium: 181 and Chloride: 167 2. Construct a Born-Haber cycle to calculate the first ionization energy for cesium. (should you use the results from the Born-Landé or the Kapustinskii equation). 3. 3. Calculate the lattice energy of MgF2 (Born Haber). Use the Kapustinskii Equation to calculate the radius of the Mg2+ ion. Hint – you will need to solve a quadratic (set ro =...
14 (a) Give a definition of lattice energy. Does your definition mean that the associated enthalpy of reaction will be positive or negative? (b) Use the Born-Landé equation to calculate a value for the lattice energy of KBr, for which ro = 328 pm. KB adopts an NaCl structure; other data may be found in Tables 6.3 and 6.4. lattice drum Table 6.3) can be evalu where repulsion coefficient Bom exponent Values of the Bom exponent (Table from compressibility data...
Use the Born-Haber Cycle and information given below to determine the lattice energy of LiF. Li(s) → Li(g) +159.3 kJ Li(g) → Li+(g) + e– +500.9 kJ F2(g) → 2 F(g) +158.8 kJ F(g) + e– → F–(g) –332.6 kJ Li+(g) + F–(g) → LiF(s) ? --------------------------------------------------- Li(s) + ½ F2(g) → LiF(s) – 616.0 kJ Group of answer choices +209.0 kJ –1023 kJ +1023 kJ –209.0 kJ –1102.4 kJ
Estimate the lattice energy, ?U, for NaF if the ionic radii for K+ and F– are 138.0 pm and 133.0 pm, respectively. Use the Kapustinskii equation.