Using Born-Haber cycle estimate the energy of formation for CaCl2. Estimate latice energy using kapustinskii equation...
1. Using the Born-Landé equation and the Kapustinskii equation, calculate the lattice enthalpy of cesium chloride. Cesium: 181 and Chloride: 167 2. Construct a Born-Haber cycle to calculate the first ionization energy for cesium. (should you use the results from the Born-Landé or the Kapustinskii equation). 3. 3. Calculate the lattice energy of MgF2 (Born Haber). Use the Kapustinskii Equation to calculate the radius of the Mg2+ ion. Hint – you will need to solve a quadratic (set ro =...
1. Construct a Born-Haber cycle showing all steps in the formation of LiF(s). The overall equation is given below Li(s) 1/2F:(g) LiF(s) 1. Construct a Born-Haber cycle showing all steps in the formation of LiF(s). The overall equation is given below Li(s) 1/2F:(g) LiF(s)
Discuss the relationship of calculating lattice energy and the Born-Haber cycle. Here are some suggestions of topics on which to elaborate upon in your explanations: Provide an explanation of the Born-Haber cycle. Explain the difference between ionization energy and electron affinity. Explain how the enthaply of formation is related to the Born-Haber cycle.
C) Lattice Energy Determine the standard formation energy of the following ionic compounds using the Born-Haber cycle and 4 the information from the table on the last page. a. NaBr(s) b. MgCl2(s)
The common oxidation number for an alkaline earth metal is +2. Using the Kapustinskii equation and Born-Haber cycles, show that CaCl is an exothermic compound, where CaCl may have NaCl structure. Use a suitable analogy to estimate an ionic radius for Ca. Use a radius for Ca. (rg and rca is 1.38 and 1.00 A, respectively.) suitable analogy to estimate an ionic 0.345 1.21 2 Z,n U To where En is the # of ions in the empirical formula, the...
a) Determine the lattice energy of thallium(I) iodide using a Born-Haber cycle with “experimental” thermodynamic data. Then calculate it using the Born-Mayer equation. Determine the % deviation of the calculated value from the “experimental” value. b) Explain the result from part (a), giving consideration to HSAB concept.
8. Write the equation for the steps in the Born-Haber cycle for HgF2 (i.e. the terms that add up to the heat of formation for the compound). Reminder: mercury is a liquid under standard conditions.
Question 4 4 pts Use the Born-Haber Cycle to calculate the lattice energy for the formation of X2Y. Input your answer in units of kJ/mole with the correct sign. Process Enthalpy (kJ/mol). X(s)--> X(g) 115 X(g) -->X*(8) + le 499 Y2 (8) --> 2Y (8) 264 -295 Y (8) + 1e.-->Y (8) Y (8) + 1e' --> Y2 () 115 2X(s) +% Y2 (8)--> X2Y(s) -549
Using the data given below, sketch a Born-Haber cycle for the formation of BaC2(s) and insert the various equations and energy values into the individual steps of your cycle Sublimation energy for Ba(s) +180 kJmol1 Electron affinity for Cl(g)-346 kJmol1 First ionization energy for Ba(g)-+514 kJmol1 Bond dissociation energy for Clh(g) +243 kJmol Enthalpy of formation of BaCl2: Ba(s) + Ch(g) BaCh(s)--610 kJmol Lattice energy. Ba2+(g) + 2Cl.(g) → BaCl2(s)--2075 kJmol-1 Calculate the second ionization energy for Ba+(g) → Ba2+(g)...
7. Use the Born Haber cycle and the given information to determine the net energy change (in kJ/mol) that takes place in the formation of KF(s) from the elements: Ks) + F2@KFS) Heat of sublimation of K = 89.2 kJ/mol Bond dissociation energy for F2 = 158 kJ/mol Lattice Energy of KF = 821 kJ/mol Eca for F = -328 kJ/mol E; for K = 418.8 kJ/mol