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[Et4N]2[NiCl4], is deliquescent, meaning that it will absorb moisture from the air and dissolve. In this...

[Et4N]2[NiCl4], is deliquescent, meaning that it will absorb moisture from the air and dissolve. In this case, the deliquescence is accompanied by a colour change. How do you account for this observation?

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Answer #1

[Ni(H2O)6]Cl2 + 2 (Et4N)Cl (Et4N)2[NiCl4] + 6 H2O

Green. Blue

Tetrahedral complex of Ni2+ with Cl- is of blue color at room temperature with tetrethylamine cation.

While octahedral complex of Ni2+ with H2O is of green color .

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