Question

CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g) Calculate ΔH for the reaction using the...

CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g)

Calculate ΔH for the reaction using the bond enthalpies given.

C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g)

Calculate the overall enthalpy change for this reaction using the bond enthalpies given.

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Answer #1

CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g)

ΔH =ΔH0fproducts –ΔH0freactants

ΔH = [(ΔH0fCO2(g) )+ (2 x ΔH0fH2O (g) )]- [( ΔH0fCH4(g) )+ (2 x ΔH0fO2 (g) )]

     = [ −393.5 +(2x( −241.8 ))]-[ −74.8 +(2x(0.0))]

     = -802.3 kJ/mol-K

C3H8(g) + 5 O2(g) → 3 CO2(g) + 4 H2O(g)

ΔH =ΔH0fproducts –ΔH0freactants

ΔH = [(3xΔH0fCO2(g) )+ (4 x ΔH0fH2O (g) )]- [( ΔH0fC3H8(g) )+ (5 x ΔH0fO2 (g) )]

     = [ (3x(−393.5)) +(4x( −241.8 ))]-[ −103.8 +(5x(0.0))]

     = -2043.9 kJ/mol-K

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