Which of the following has a conformer with one equatorial substituent and one axial substituent? A)...
Which of the following has a conformer with one equatorial substituent and one axial substituent?
A) trans-1,4-dibromocyclohexane
B) cis-1,4-dibromocyclohexane
C) cis-1,3-dibromocyclohexane
D) trans-1,2-dibromocyclohexane
E) none of the above
Homework Answers
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Which of the following
has a conformer with one equatorial substituent and one axial
substituent?
A)...
5.5. Place the methyl groups by drawing the axial and equatorial positions on the cyclohexane structure...
5.5. Place the methyl groups by drawing the axial and equatorial positions on the cyclohexane structure in the chair conformations next to the cyclohexane derivatives named below. H H CH, H CH, CH, cis-1,2-Dimethylcyclohexane H CH, trans-1,2-Dimethylcyclohexane H CH, H CH, CH, eis-1,3-Dimethylcyclohexane CH, trans-1,3-Dimethylcyclohexane H H H CH, KO HC CH, cis-1,4-Dimethylcyclohexane н,с H trans-1,4-Dimethyleyclohexane
20. Name these compoands CHy 21. Draw chair structures for each of these compounds. Label cach...
20. Name these compoands CHy 21. Draw chair structures for each of these compounds. Label cach substituent as axial or equatorial. trans-1,2-intethylcyclohexane cis-1.2-dimetlylcyclohexane 22. Draw a chair conformation of cyclohexane with one CH,CH: gruup and ene Clls group that fits cach description. 1,1-disubstituted cyclohexane with an axial CHCH: group cis-1,2-disubstituted cyeloliexane with an axial CHs group trans-1,3-disulstituted cyclohexane wilh an equatorial Cli, group trans-1,4-disubistituted cyclohexane with an equatorial CHCiH: group
In carbon tetrachloride solution, cis-cyclohexane-1,3-diol exists mainly in the conformer with two axial OH groups, but...
In carbon tetrachloride solution, cis-cyclohexane-1,3-diol exists mainly in the conformer with two axial OH groups, but in methanol solution, the major conformer has both OH groups equatorial. Why?
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip...
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip of both *Draw the two conformation of the cis and trans cyclohexane structures above *List the number of axial and equatorial substituents for both the cis and trans *Which isomer is more stable overall, cis or trans? Why? 2. Make a model cis-1,3-dimethylcyclohexane and trans-1,3-dimethylcyclohexane. Do a ring flip *Draw the two conformation of the cis and trans cyclohexane structures above *List the number...
Help if you can, don’t worry about # 4 Questions Which of the two conformations is...
Help if you can, don’t worry about # 4
Questions Which of the two conformations is favored at equilibrium? a. trans-1,2-dimethylcyclohexane (a/aor b. cis-1,3-dimethylcyclohexane (a/a)or 1. (ele) (ele) 2. How many gauche interactions are present in the trans 1.2-dimethylcyclohexane (a/a) conformer between the methyl groups and between the methy)l groups and the a. b. 2 c. 3 d. 4 e. None 3. How many gauche interactions are present in the trans-1,2-dimethylcyclohexane (e/e) conformer between the methyl groups and between the...
Two methyl groups Distance between methyl carbons 0 1,3-diaxial 1,3-diequatorial 1,3-equatorial/axial 3.410A 5.038 A 4 569...
Two methyl groups Distance between methyl carbons 0 1,3-diaxial 1,3-diequatorial 1,3-equatorial/axial 3.410A 5.038 A 4 569 A Cis or trans? Energy Relative energy (kcal/mol) (cis) 41.96 /moll (cis) 20.72 kJ/mol ccis) 26.68 kJ/mol Complete this sentence based on your data in the table above: The_(more/fewer)_ axial methyl groups, the (greater/lesser) the energy of the molecule.
b. Which of the following alkanes has the highest bolling point? 2,3-dimethylbutane: 2-methylpentane; 3-methylpentane; hexane c....
b. Which of the following alkanes has the highest bolling point? 2,3-dimethylbutane: 2-methylpentane; 3-methylpentane; hexane c. Which of the following compounds can adopt a chair conformation in which there are no axial methyl groups? 1,1-dimethylcyclohexane; cis-1,2-dimethylcyclohexane; trans-1,2-dimethylcyclohexane; trans-1,3-di methylcyclohexane d. Which of the following compounds can adopt a chair conformation which there are no axial methyl groups? cis-1,2-dimethylcyclohexane; cis-1,3-dimethylcyclohexane; trans-1,3-dimethylcyclohexane; cis-1.4-dimethylcyclohexane cis-1,2-dimethvcyclohexane (Enter the numerical value only, without any units)? e. What is the approximate di hedral angle between the...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain thes...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
34 Which of the following is the highest energy conformer of 2,3-dimethylbutane HCH, I M V...
34 Which of the following is the highest energy conformer of 2,3-dimethylbutane HCH, I M V Ho CH ) Ho Ho O Ho HC not A) 1 B) II C) III D) IV 35) - 35) Which of the following chair conformations represents trans-1,3-dimethylcyclohexane? " DIV" C) III B) II 36) Which of the following is the most stable conformation of cis-1-ethyl-3-isopropyleyclohexane? A) B) II 37) Select the most stable conformer of cis-1,3-cyclohexanediol HO dis-1,3-cyclohexanediol но Тон OH OH HO...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial inte...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
5.5. Place the methyl groups by drawing the axial and equatorial positions on the cyclohexane structure in the chair conformations next to the cyclohexane derivatives named below. H H CH, H CH, CH, cis-1,2-Dimethylcyclohexane H CH, trans-1,2-Dimethylcyclohexane H CH, H CH, CH, eis-1,3-Dimethylcyclohexane CH, trans-1,3-Dimethylcyclohexane H H H CH, KO HC CH, cis-1,4-Dimethylcyclohexane н,с H trans-1,4-Dimethyleyclohexane
20. Name these compoands CHy 21. Draw chair structures for each of these compounds. Label cach substituent as axial or equatorial. trans-1,2-intethylcyclohexane cis-1.2-dimetlylcyclohexane 22. Draw a chair conformation of cyclohexane with one CH,CH: gruup and ene Clls group that fits cach description. 1,1-disubstituted cyclohexane with an axial CHCH: group cis-1,2-disubstituted cyeloliexane with an axial CHs group trans-1,3-disulstituted cyclohexane wilh an equatorial Cli, group trans-1,4-disubistituted cyclohexane with an equatorial CHCiH: group
Help if you can, don’t worry about # 4
Questions Which of the two conformations is favored at equilibrium? a. trans-1,2-dimethylcyclohexane (a/aor b. cis-1,3-dimethylcyclohexane (a/a)or 1. (ele) (ele) 2. How many gauche interactions are present in the trans 1.2-dimethylcyclohexane (a/a) conformer between the methyl groups and between the methy)l groups and the a. b. 2 c. 3 d. 4 e. None 3. How many gauche interactions are present in the trans-1,2-dimethylcyclohexane (e/e) conformer between the methyl groups and between the...
Two methyl groups Distance between methyl carbons 0 1,3-diaxial 1,3-diequatorial 1,3-equatorial/axial 3.410A 5.038 A 4 569 A Cis or trans? Energy Relative energy (kcal/mol) (cis) 41.96 /moll (cis) 20.72 kJ/mol ccis) 26.68 kJ/mol Complete this sentence based on your data in the table above: The_(more/fewer)_ axial methyl groups, the (greater/lesser) the energy of the molecule.
b. Which of the following alkanes has the highest bolling point? 2,3-dimethylbutane: 2-methylpentane; 3-methylpentane; hexane c. Which of the following compounds can adopt a chair conformation in which there are no axial methyl groups? 1,1-dimethylcyclohexane; cis-1,2-dimethylcyclohexane; trans-1,2-dimethylcyclohexane; trans-1,3-di methylcyclohexane d. Which of the following compounds can adopt a chair conformation which there are no axial methyl groups? cis-1,2-dimethylcyclohexane; cis-1,3-dimethylcyclohexane; trans-1,3-dimethylcyclohexane; cis-1.4-dimethylcyclohexane cis-1,2-dimethvcyclohexane (Enter the numerical value only, without any units)? e. What is the approximate di hedral angle between the...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
34 Which of the following is the highest energy conformer of 2,3-dimethylbutane HCH, I M V Ho CH ) Ho Ho O Ho HC not A) 1 B) II C) III D) IV 35) - 35) Which of the following chair conformations represents trans-1,3-dimethylcyclohexane? " DIV" C) III B) II 36) Which of the following is the most stable conformation of cis-1-ethyl-3-isopropyleyclohexane? A) B) II 37) Select the most stable conformer of cis-1,3-cyclohexanediol HO dis-1,3-cyclohexanediol но Тон OH OH HO...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
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